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Mechanisms Of Catalysis


Mechanisms Of Catalysis
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Organometallic Mechanisms And Catalysis


Organometallic Mechanisms And Catalysis
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Author : Jay Kochi
language : en
Publisher: Elsevier
Release Date : 2012-12-02

Organometallic Mechanisms And Catalysis written by Jay Kochi and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.


Organometallic Mechanisms and Catalysis: The Role of Reactive Intermediates in Organic Processes covers the mechanistic delineation of organometallic chemistry and catalysis. This book is organized into three parts encompassing 18 chapters. The first part describes first the oxidation-reduction process of organometals, followed by discussions on the catalytic reactions of peroxides, metal-catalyzed addition to olefins, and reduction of organic halides. This part also explores other reactions involving transition metal carbonyls and metal-catalyzed reactions of aromatic diazonium salts. The second part deals with some chemical aspects of organometals, such as their stability, thermochemistry, decomposition, hemolytic pathways, and the formation of carbon-carbon bonds. The third part examines the charge transfer processes and interactions of organometals with electron acceptors. This part further looks into the cleavage and insertion reactions of organometals with electrophiles, as well as the electrophilic and electron transfer mechanisms of organometals. Organic and inorganic chemists, teachers, and students will greatly benefit from this book.



Homogeneous Catalysis With Metal Complexes


Homogeneous Catalysis With Metal Complexes
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Author : Oleg N. Temkin
language : en
Publisher: John Wiley & Sons
Release Date : 2012-02-08

Homogeneous Catalysis With Metal Complexes written by Oleg N. Temkin and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-02-08 with Science categories.


Homogeneous catalysis by soluble metal complexes has gained considerable attention due to its unique applications and features such as high activity and selectivity. Catalysis of this type has demonstrated impressive achievements in synthetic organic chemistry and commercial chemical technology. Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms presents a comprehensive summary of the results obtained over the last sixty years in the field of the kinetics and mechanisms of organic and inorganic reactions catalyzed with metal complexes. Topics covered include: Specific features of catalytic reaction kinetics in the presence of various mono- and polynuclear metal complexes and nanoclusters Multi-route mechanisms and the methods of their identification, as well as approaches to the kinetics of polyfunctional catalytic systems Principles and features of the dynamic behavior of nonlinear kinetic models The potential, achievements, and limitations of applying the kinetic approach to the identification of complex reaction mechanisms The development of a rational strategy for designing kinetic models The kinetic models and mechanisms of many homogeneous catalytic processes employed in synthetic and commercial chemistry Written for specialists in the field of kinetics and catalysis, this book is also relevant for post-graduates engaged in the study



Enzyme Catalysis And Regulation


Enzyme Catalysis And Regulation
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Author : Gorden Hammes
language : en
Publisher: Elsevier
Release Date : 2012-12-02

Enzyme Catalysis And Regulation written by Gorden Hammes and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.


Enzyme Catalysis and Regulation is an introduction to enzyme catalysis and regulation and covers topics ranging from protein structure and dynamics to steady-state enzyme kinetics, multienzyme complexes, and membrane-bound enzymes. Case studies of selected enzyme mechanisms are also presented. This book consists of 11 chapters and begins with a brief overview of enzyme structure, followed by a discussion on methods of probing enzyme structure such as X-ray crystallography and optical spectroscopy. Kinetic methods are then described, with emphasis on the general principles of steady-state and transient kinetics. The chemical principles involved in enzyme catalysis are also discussed, and case studies of a few well-documented enzymes are presented. The regulation of enzyme activity is analyzed from a nongenetic viewpoint, with particular reference to binding isotherms and models for allosterism. Two particular enzymes, aspartate transcarbamoylase and phosphofructokinase, are used as examples of well-studied regulatory enzymes. The last two chapters focus on multienzyme complexes and membrane-bound enzymes. This monograph is intended for graduate students, advanced undergraduates, and research workers in molecular biology and biochemistry.



Organic Chemistry Of Enzyme Catalyzed Reactions Revised Edition


Organic Chemistry Of Enzyme Catalyzed Reactions Revised Edition
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Author : Richard B. Silverman
language : en
Publisher: Elsevier
Release Date : 2002-03-07

Organic Chemistry Of Enzyme Catalyzed Reactions Revised Edition written by Richard B. Silverman and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002-03-07 with Technology & Engineering categories.


The Organic Chemistry of Enzyme-Catalyzed Reactions is not a book on enzymes, but rather a book on the general mechanisms involved in chemical reactions involving enzymes. An enzyme is a protein molecule in a plant or animal that causes specific reactions without itself being permanently altered or destroyed. This is a revised edition of a very successful book, which appeals to both academic and industrial markets. - Illustrates the organic mechanism associated with each enzyme-catalyzed reaction - Makes the connection between organic reaction mechanisms and enzyme mechanisms - Compiles the latest information about molecular mechanisms of enzyme reactions - Accompanied by clearly drawn structures, schemes, and figures - Includes an extensive bibliography on enzyme mechanisms covering the last 30 years - Explains how enzymes can accelerate the rates of chemical reactions with high specificity - Provides approaches to the design of inhibitors of enzyme-catalyzed reactions - Categorizes the cofactors that are appropriate for catalyzing different classes of reactions - Shows how chemical enzyme models are used for mechanistic studies - Describes catalytic antibody design and mechanism - Includes problem sets and solutions for each chapter - Written in an informal and didactic style



Mechanisms Of Catalysis


Mechanisms Of Catalysis
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Author :
language : en
Publisher: Academic Press
Release Date : 1991-01-28

Mechanisms Of Catalysis written by and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1991-01-28 with Technology & Engineering categories.


The remarkable expansion of information leading to a deeper understanding of enzymes on the molecular level necessitated the development of this volume which not only introduces new topics to The Enzymes series but presents new information on some covered in Volume I and II of this edition.



Ammonia Synthesis Catalysts


Ammonia Synthesis Catalysts
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Author : Huazhang Liu
language : en
Publisher: World Scientific
Release Date : 2013

Ammonia Synthesis Catalysts written by Huazhang Liu and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013 with Science categories.


This book provides a review of worldwide developments in ammonia synthesis catalysts over the last 30 years. It focuses on the new generation of Fe1-xO based catalysts and ruthenium catalysts - both are major breakthroughs for fused iron catalysts. The basic theory for ammonia synthesis is systematically explained, covering topics such as the chemical components, crystal structure, preparation, reduction, performance evaluation, characterization of the catalysts, the mechanism and kinetics of ammonia synthesis reaction. Both theory and practice are combined in this presentation, with emphasis on the research methods, application and exploitation of catalysts. The comprehensive volume includes an assessment of the economic and engineering aspects of ammonia plants based on the performance of catalysts. Recent developments in photo-catalysis, electro-catalysis, biocatalysis and new uses of ammonia are also introduced in this book. The author, Professor Huazhang Liu, has been engaged in research and practice for more than 50 years in this field and was the inventor of the first Fe1-xO based catalysts in the world. He has done a lot of research on Fe3O4 based- and ruthenium based-catalysts, and has published more than 300 papers and obtained 21 patents during his career.



Catalysis In Chemistry And Enzymology


Catalysis In Chemistry And Enzymology
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Author : William P. Jencks
language : en
Publisher: Courier Corporation
Release Date : 1987-01-01

Catalysis In Chemistry And Enzymology written by William P. Jencks and has been published by Courier Corporation this book supported file pdf, txt, epub, kindle and other format this book has been release on 1987-01-01 with Science categories.


Exceptionally clear coverage of mechanisms for catalysis, forces in aqueous solution, carbonyl- and acyl-group reactions, practical kinetics, more.



Contemporary Catalysis


Contemporary Catalysis
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Author : Paul C J Kamer
language : en
Publisher: Royal Society of Chemistry
Release Date : 2017-07-05

Contemporary Catalysis written by Paul C J Kamer and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-07-05 with Science categories.


Encompassing an integrated approach to the various aspects of catalysis, covering heterogeneous, homogeneous, organo-, bio-, and computational catalysis, as well as reaction and reactor engineering on an advanced level, this textbook is ideal for graduate students with diverse backgrounds, including catalysis, engineering, and organic synthesis. The basic principles of the various fields of catalysis are introduced in a concise way, preparing the reader for the more advanced chapters. Organometallic chemistry, surface science, biochemistry, nanoscience, transport phenomena and kinetics, reactor and reaction engineering are presented, spanning from the underlying science to industrial applications. Several important case studies on industrial applications are given. It includes catalyst preparation and characterisation and explores recent developments in the understanding of catalytic mechanisms, exploring advanced techniques such as operando spectroscopy.



Plasma Catalysis


Plasma Catalysis
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Author : Annemie Bogaerts
language : en
Publisher: MDPI
Release Date : 2019-04-02

Plasma Catalysis written by Annemie Bogaerts and has been published by MDPI this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-04-02 with Technology & Engineering categories.


Plasma catalysis is gaining increasing interest for various gas conversion applications, such as CO2 conversion into value-added chemicals and fuels, N2 fixation for the synthesis of NH3 or NOx, methane conversion into higher hydrocarbons or oxygenates. It is also widely used for air pollution control (e.g., VOC remediation). Plasma catalysis allows thermodynamically difficult reactions to proceed at ambient pressure and temperature, due to activation of the gas molecules by energetic electrons created in the plasma. However, plasma is very reactive but not selective, and thus a catalyst is needed to improve the selectivity. In spite of the growing interest in plasma catalysis, the underlying mechanisms of the (possible) synergy between plasma and catalyst are not yet fully understood. Indeed, plasma catalysis is quite complicated, as the plasma will affect the catalyst and vice versa. Moreover, due to the reactive plasma environment, the most suitable catalysts will probably be different from thermal catalysts. More research is needed to better understand the plasma–catalyst interactions, in order to further improve the applications.



Oxygen In Catalysis


Oxygen In Catalysis
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Author : Adam Bielanski
language : en
Publisher: CRC Press
Release Date : 1990-11-29

Oxygen In Catalysis written by Adam Bielanski and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990-11-29 with Science categories.


A description of catalytic systems commonly used as model systems in the laboratory and as industrial catalysts in large-scale operations, and a discussion of the mechanisms operating in these reactions. Attempts to describe the elementary steps by quantum chemical methods are also shown, as are rec