Metal Catalysed Reactions Of Hydrocarbons
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Metal Catalysed Reactions Of Hydrocarbons
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Author : Geoffrey C. Bond
language : en
Publisher: Springer Science & Business Media
Release Date : 2006-10-03
Metal Catalysed Reactions Of Hydrocarbons written by Geoffrey C. Bond and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-10-03 with Science categories.
This unique book, drawing on the author’s lifetime experience, critically evaluates the extensive literature on the field of Metal-Catalysed Reactions of Hydrocarbons. Emphasis is placed on reaction mechanisms involving hydrogenation, hydrogenolysis, skeletal and positional isomerisation, and exchange reactions. The motivation for fundamental research in heterogeneous catalysis is to identify the physicochemical characteristics of active centres for the reaction being studied, to learn how these may be modified or manipulated to improve the desired behavior of the catalyst, and to recognize and control those aspects of the catalyst's structure that limit its overall performance. By restricting the subject of the book to hydrocarbons, Bond has progressively developed the subject matter to include areas of importance both to researchers and to those working in the industry.
Metal Catalysed Reactions Of Hydrocarbons
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Author : Geoffrey C. Bond
language : en
Publisher: Springer
Release Date : 2008-11-01
Metal Catalysed Reactions Of Hydrocarbons written by Geoffrey C. Bond and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-11-01 with Science categories.
This unique book, drawing on the author’s lifetime experience, critically evaluates the extensive literature on the field of Metal-Catalysed Reactions of Hydrocarbons. Emphasis is placed on reaction mechanisms involving hydrogenation, hydrogenolysis, skeletal and positional isomerisation, and exchange reactions. The motivation for fundamental research in heterogeneous catalysis is to identify the physicochemical characteristics of active centres for the reaction being studied, to learn how these may be modified or manipulated to improve the desired behavior of the catalyst, and to recognize and control those aspects of the catalyst's structure that limit its overall performance. By restricting the subject of the book to hydrocarbons, Bond has progressively developed the subject matter to include areas of importance both to researchers and to those working in the industry.
Base Catalyzed Reactions Of Hydrocarbons And Related Compounds
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Author : Herman Pines
language : en
Publisher: Elsevier
Release Date : 2012-12-02
Base Catalyzed Reactions Of Hydrocarbons And Related Compounds written by Herman Pines and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
Base-Catalyzed Reactions of Hydrocarbons and Related Compounds focuses on the use of bases as catalysts for the conversion of hydrocarbons and related compounds. In order to emphasize the broad scope of base-catalyzed reactions, examples dealing with the conversion of non-hydrocarbons are given. Comprised of 14 chapters, this book begins with a historical overview of base-catalyzed conversions of hydrocarbons, followed by a discussion on the isomerization of olefins, acetylenes, and allenes, as well as the dimerization and oligomerization of hydrocarbons. The reader is then introduced to a variety of reactions, including those between aromatic hydrocarbons and olefins and between alkylpyridines and alkenylpyridines; homogeneous carbon-carbon addition reactions; and reactions of aprotic solvents with olefins. Subsequent chapters explore carbon-carbon addition of olefins with miscellaneous compounds; addition of ammonia, amines, and anilines to olefinic hydrocarbons; hydrogenation and oxygenation; dehydrogenation, aromatization, and hydrogen transfer; and dehydration of alcohols. This monograph will be of interest to chemists.
Activation And Catalytic Reactions Of Saturated Hydrocarbons In The Presence Of Metal Complexes
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Author : A.E. Shilov
language : en
Publisher: Springer Science & Business Media
Release Date : 2001-11-30
Activation And Catalytic Reactions Of Saturated Hydrocarbons In The Presence Of Metal Complexes written by A.E. Shilov and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001-11-30 with Science categories.
hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the “noble gases of organic chemistry” and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint.
Palladium Catalyzed Oxidation Of Hydrocarbons
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Author : P. Henry
language : en
Publisher: Springer Science & Business Media
Release Date : 1979-12-31
Palladium Catalyzed Oxidation Of Hydrocarbons written by P. Henry and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 1979-12-31 with Science categories.
The field of organometallic chemistry has emerged over the last twenty-five years or so to become one of the most important areas of chemistry, and there are no signs of abatement in the intense current interest in the subject, particularly in terms of its proven and potential application in catalytic reactions involving hydrocarbons. The development of the organometallic/ catalysis area has resulted in no small way from many contributions from researchers investigating palladium systems. Even to the well-initiated, there seems a bewildering and diverse variety of organic reactions that are promoted by palladium(II) salts and complexes. Such homogeneous reactions include oxidative and nonoxidative coupling of substrates such as olefins, dienes, acetylenes, and aromatics; and various isomerization, disproportionation, hydrogenation, dehydrogenation, car bonylation and decarbonylation reactions, as well as reactions involving formation of bonds between carbon and halogen, nitrogen, sulfur, and silicon. The books by Peter M. Maitlis - The Organic Chemistry of Palladium, Volumes I, II, Academic Press, 1971 - serve to classify and identify the wide variety of reactions, and access to the vast literature is available through these volumes and more recent reviews, including those of J. Tsuji [Accounts Chem. Res. , 6, 8 (1973); Adv. in Organometal. , 17, 141 (1979)], R. F. Heck [Adv. in Catat. , 26, 323 (1977)], and ones by Henry [Accounts Chem. Res. , 6, 16 (1973); Adv. in Organometal. , 13, 363 (1975)]. F. R. Hartley's book - The Chemistry of Platinum and Palladium, App!. Sci. Pub!.
Transition Metal Catalysed Reactions
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Author : International Union of Pure and Applied Chemistry
language : en
Publisher:
Release Date : 1999
Transition Metal Catalysed Reactions written by International Union of Pure and Applied Chemistry and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999 with Science categories.
The Chemistry Of Catalytic Hydrocarbon Conversions
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Author : Herman Pines
language : en
Publisher: Elsevier
Release Date : 2012-12-02
The Chemistry Of Catalytic Hydrocarbon Conversions written by Herman Pines and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
The Chemistry of Catalytic Hydrocarbon Conversions covers the various chemical aspects of catalytic conversions of hydrocarbons. This book is composed of eight chapters that include catalytic synthesis of hydrocarbons from carbon monoxide, hydrogen, and methanol. The opening chapters examine various acid- and base-catalyzed reactions, such as isomerization, polymerization, oligomerization, alkylation, catalytic cracking, reforming, hydrocracking, and hydrogenation. The subsequent chapters are devoted to specific catalytic reactions, including heterogeneous hydrogenation, dehydrogenation, aromatization, and oxidation. Other chapters describe the homogeneous catalysis by transition metal organometallic catalysts and the metathesis of unsaturated hydrocarbons. The concluding chapter deals with the synthesis of liquid hydrocarbon fuels from carbon monoxide, hydrogen, methanol, and dimethyl ether. This book is of great benefit to petroleum chemists, engineers, and researchers.
Transition Metal Graphite Catalysts For Production Of Light Hydrocarbons From Synthesis Gas
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Author : Texas A & M University. Department of Chemistry
language : en
Publisher:
Release Date : 1976
Transition Metal Graphite Catalysts For Production Of Light Hydrocarbons From Synthesis Gas written by Texas A & M University. Department of Chemistry and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1976 with categories.
Homogeneous Transition Metal Catalysis
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Author : Christopher Masters
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Homogeneous Transition Metal Catalysis written by Christopher Masters and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Soluble catalysts are used extensively in many branches of chemistry and are indeed a vital constituent of many natural processes. They find wide application throughout the chemical industry where they assist in the production of several million tonnes of chemicals each year. Since homogeneous systems, especially those incorporating transition metals, often function effectively under milder conditions than their heterogeneous counterparts, they are becoming increasingly important at a time when the chemical industry in particular, and society in general, is seeking ways of conserving energy and of making the best possible use of available resources. My principal objective in- writing this book is to engender sufficient enthusiasm for, and knowledge of, the subject in the reader that he or she will be encouraged to begin, or continue, to make their own contribution to advancing our knowledge of homogeneous catalysis. After attempting to acquaint the reader with some of the ground rules I have tried to describe the present scope, and the future potential, of this fascinating field of chemistry by drawing both on academic and on industrial data sources. This approach stems from a personal conviction that future progress could be considerably hastened by a more meaningful dialogue between chemists working both in industrial and in academic research institutions. Wherever possible, examples of the commercial application of homogeneous catalyst systems have been included and no attempt has been made in any way to disguise the many unresolved questions and exciting challenges which still pervade this rapidly developing area.
Metal Catalysed Reactions In Ionic Liquids
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Author : Paul J. Dyson
language : en
Publisher: Springer
Release Date : 2005
Metal Catalysed Reactions In Ionic Liquids written by Paul J. Dyson and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2005 with Science categories.
Metal Catalysed Reactions in Ionic Liquids by Paul J. Dyson and Tilmann J. Geldbach Metal Catalysed Reactions in Ionic Liquids is the first non-edited book on the subject of metal catalysed reactions in ionic liquids and covers the literature from its origins until early 2005. The book begins with a general introduction to the field of biphasic/multiphasic catalysis and describes the synthesis, functionalisation and fundamental properties of ionic liquids relevant to catalysis. In the following chapters catalysed reactions are discussed according to their type, including: hydrogenation hydroformylation oxidation C-C coupling reactions metathesis dimerisation polymerisation Trends, generalisations, advantages and disadvantages of ionic liquids for specific reaction types are discussed. In addition, specific processes such as supported ionic liquid phase catalysis, continuous processes using CO2 extraction and nanoparticle catalysis are covered. This book is an invaluable resource for all those working in catalysis, green chemistry, and advanced synthetic methods, especially advanced level undergraduate and graduate students and those researching or contemplating research in biphasic or multiphasic catalysis using ionic liquids.