Metal Fluorocarbon Based Energetic Materials
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Metal Fluorocarbon Based Energetic Materials
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Author : Ernst-Christian Koch
language : en
Publisher: John Wiley & Sons
Release Date : 2012-03-26
Metal Fluorocarbon Based Energetic Materials written by Ernst-Christian Koch and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-03-26 with Science categories.
Metal-Fluorocarbon Based Energetic Materials This exciting new book details all aspects of a major class of pyrolants and elucidates the progress that has been made in the field, covering both the chemistry and applications of these compounds. Written by a pre-eminent authority on the subject from the NATO Munitions Safety Information Analysis Center (MSIAC), it begins with a historical overview of the development of these materials, followed by a thorough discussion of their ignition, combustion and radiative properties. The next section explores the multiple facets of their military and civilian applications, as well as industrial synthetic techniques. The critical importance of the associated hazards, namely sensitivity, stability and aging, are discussed in detail, and the book is rounded off by an examination of the future of this vital and expanding field. The result is a complete guide to the chemistry, manufacture, applications and required safety precautions of pyrolants for both the military and chemical industries. From the preface: “... This book fills a void in the collection of pyrotechnic literature... it will make an excellent reference book that all researchers of pyrolants and energetics must have...” Dr. Bernard E. Douda, Dr. Sara Pliskin, NAVSEA Crane, IN, USA
Metal Fluorocarbon Based Energetic Materials
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Author : Ernst-Christian Koch
language : en
Publisher: John Wiley & Sons
Release Date : 2012-04-06
Metal Fluorocarbon Based Energetic Materials written by Ernst-Christian Koch and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-04-06 with Science categories.
Metal-Fluorocarbon Based Energetic Materials This exciting new book details all aspects of a major class of pyrolants and elucidates the progress that has been made in the field, covering both the chemistry and applications of these compounds. Written by a pre-eminent authority on the subject from the NATO Munitions Safety Information Analysis Center (MSIAC), it begins with a historical overview of the development of these materials, followed by a thorough discussion of their ignition, combustion and radiative properties. The next section explores the multiple facets of their military and civilian applications, as well as industrial synthetic techniques. The critical importance of the associated hazards, namely sensitivity, stability and aging, are discussed in detail, and the book is rounded off by an examination of the future of this vital and expanding field. The result is a complete guide to the chemistry, manufacture, applications and required safety precautions of pyrolants for both the military and chemical industries. From the preface: “... This book fills a void in the collection of pyrotechnic literature... it will make an excellent reference book that all researchers of pyrolants and energetics must have...” Dr. Bernard E. Douda, Dr. Sara Pliskin, NAVSEA Crane, IN, USA
Energetic Materials And Munitions
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Author : Adam Stewart Cumming
language : en
Publisher: John Wiley & Sons
Release Date : 2019-02-20
Energetic Materials And Munitions written by Adam Stewart Cumming and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-02-20 with Science categories.
Provides a hands-on approach to demilitarization and environmental aspects of energetic materials and munitions This book gives an overview of the environmental impact of the production, use, and cleanup of energetic materials and munitions. It provides scientists, engineers, environmental specialists, and users with the understanding of environmental issues for munitions and of the ways to improve design and manage potential risks. It covers the various aspects of how chemical properties influence fate, transport, and toxicity of new formulations and prescribes tools for reducing or alleviating environmental risks. In addition, it discusses pyrotechnics and the problem of dealing with munitions underwater. Chapters in Energetic Materials and Munitions: Life Cycle Management, Environmental Impact and Demilitarization look at demilitarization in general, as well as in the future. Topics covered include logistics, costs, and management; life cycle analysis and management; and greener munitions. Another introduces readers to the "One Health" approach in the design of sustainable munition compounds. Following that, readers are taught about land assessment for munitions-related contamination in military live-fire training. The book also examines the development and integration of environmental, safety, and occupational health information. -Brings together in one source expertise and in-depth information on the current and future state of how we handle the production, use, and demilitarization of explosives and weaponry -A handy reference for experienced practitioners, as well as for training young professionals in the field -Every chapter contains real-life examples and proposes future directions for the field Energetic Materials and Munitions: Life Cycle Management, Environmental Impact and Demilitarization is an important book for explosives specialists, pyrotechnicians, materials scientists, military authorities, safety officers, health officers, and chemical engineers.
Nanoengineering And Synthesis Of Metal Based Materials For Enhanced Energetic Performance
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Author : Prawal Agarwal
language : en
Publisher:
Release Date : 2023
Nanoengineering And Synthesis Of Metal Based Materials For Enhanced Energetic Performance written by Prawal Agarwal and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023 with categories.
Metal-based energetic materials are a pathway for clean and sustainable energy applications because of their high energy densities and ability to oxidize readily and release large amounts of heat. They are sustainable sources of green combustion and can easily be stored and transported because they are chemically stable solids compared to hydrocarbon fuels. These merits lead to their applications in volume-limited propulsion, solid fuels, explosives, space exploration, self-destructing energetic chips, electrochemical energy storage, and hydrogen generation/storage. To be used effectively in these applications, nanometer-sized particles are beneficial because of the fast ignition, more complete combustion, and enhanced heat transfer and reaction rates due to the larger specific surface area available for the reaction. However, some roadblocks exist in harnessing the benefits of metal nanoparticles (NPs). The surfaces of the metal NPs are highly reactive. Hence, there is a formation of a native oxide layer on their surface. This native oxide occupies a significant fraction of mass in the sample that does not contribute to the oxidative heat release of the sample and also acts as a diffusion barrier on the metal NP surface that delays the contact of oxidizer with metal in the core and thus restricts the combustion process. Various methods are available in the literature to minimize the inhibiting effects of the native oxide layer on oxidative heat release. These methods are based on surface functionalization using solution-based approaches, reactive milling, coating reactive metals on other metals, and high-temperature sintering to synthesize metal borides. These methods helped us to determine how to approach solving the problem of the native oxide layer and investigating possible routes to improve the oxidative energy release from metal-based nanomaterials. We can either reduce native oxide or convert them into a reactive component such that they contribute to the oxidative heat release. In our work, we used nonthermal plasma processing and intermetallic chemistry based on self-propagating high-temperature synthesis (SHS) reactions. Nonthermal plasma is a low-temperature operation that triggers selective and rapid reactions on the surface. Due to low-temperature operation, this process uses energy efficiently. We used hydrogen plasma to generate reactive hydrogen species that can reduce native oxides of metal at room temperature. We also used plasma-enhanced chemical vapor deposition (PECVD) through argon plasma to deposit reactive nanofilms on the metal NPs surfaces to enhance the energy performance during oxidation and to passivate their surfaces to inhibit oxide growth in extreme temperature and humid conditions during storage. Using SHS, we synthesize solid solutions of metals with long storage life because of their thermal stability and with enhanced oxidative heat release due to the reduction of less reactive metal oxide with a more reactive metal. The process temperature is selected so that there is no sintering and agglomeration of NPs during the process. Both the above processes are dry-phase process and reduces the contamination of metals. Using nonthermal plasma processing, we enhanced the oxidative heat release from boron (B) NPs by developing an in-situ process in which hydrogen plasma reduces B oxide and PECVD coats the surface with a thin fluorocarbon film to stop reoxidation when NPs are exposed to the environment. PECVD is used to deposit reactive nanofilms of perfluorodecalin and oleic acid on the surface of aluminum (Al) NPs, which lead to superior energy performance of Al NPs. The plasma-based oleic acid nanofilms performed better than graphene oxide. Hydrogen plasma doped the Al NPs with hydrides such that during oxidation, channels are formed on the surface due to gas transport, leading to better oxidation of metal in the core. Boron is a desirable candidate for energetic applications with the highest gravimetric and volumetric energy density of 58 kJ/g and 140 kJ/mL. The energy from B can be exploited by the addition of reactive metals with reasonable gravimetric energy density, such as Al and magnesium (Mg), in the form of a mechanical mixture or solid solutions, which can undergo an exothermic redox reaction to reduce native oxide and enrich metallic B. We used SHS and mechanical mixing to form Mg/B solid solutions and energy-optimized Al/B systems to synthesize energetic materials. We also combined plasma chemistry and intermetallic chemistry to investigate the integrated effects of these processes on B energetics. Hence, we reduced native oxides and/or converted them into energetic components via nanoengineering by fabricating core-shell architectures and synthesizing energetic nanomaterials with enhanced energy performance and extended storage stability.
Metal Nanopowders
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Author : Alexander A. Gromov
language : en
Publisher: John Wiley & Sons
Release Date : 2014-05-19
Metal Nanopowders written by Alexander A. Gromov and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-05-19 with Science categories.
Written with both postgraduate students and researchers in academia and industry in mind, this reference covers the chemistry behind metal nanopowders, including production, characterization, oxidation and combustion. The contributions from renowned international scientists working in the field detail applications in technologies, scale-up processes and safety aspects surrounding their handling and storage.
Chemistry Of High Energy Materials
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Author : Thomas M. Klapötke
language : en
Publisher: Walter de Gruyter GmbH & Co KG
Release Date : 2022-08-01
Chemistry Of High Energy Materials written by Thomas M. Klapötke and has been published by Walter de Gruyter GmbH & Co KG this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-08-01 with Technology & Engineering categories.
Chemistry of High-Energy Materials continues in this new and revised 6th edition to provide fundamental scientifi c insights into primary and secondary explosives, propellants, rocket fuels and pyrotechnics. It expands with new research developments, including new melt casts, reactive structure materials, a computational study on the detonation velocity of mixtures of solid explosives with non-explosive liquids, calculation of craters after explosions. This work is of interest to advanced students in chemistry, materials science and engineering, as well as to all those working in military and defense technology.
High Explosives Propellants Pyrotechnics
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Author : Ernst-Christian Koch
language : en
Publisher: Walter de Gruyter GmbH & Co KG
Release Date : 2021-01-18
High Explosives Propellants Pyrotechnics written by Ernst-Christian Koch and has been published by Walter de Gruyter GmbH & Co KG this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-01-18 with Technology & Engineering categories.
This dictionary contains 739 entries with about 1400 references to the primary literature. Details on the composition, performance, sensitivity and other pertinent properties of Energetic Materials such as High Explosives, Propellants, Pyrotechnics, as well as important ingredients such as Oxidizers, Fuels, Binders, and Modifiers are given and presented partly in over 180 tables with more than 240 structural formulas . In detail the dictionary gives elaborate descriptions of 460 Chemical Substances 170 Pyrotechnic Compositions 360 High Explosive and Propellant Formulations In addition, the basic physical and thermochemical properties of 435 pure substances (elements & compounds) typically occuring as ingredients or reaction products are given too. 150 Figures, schemes and diagrams explain Applications, Test methods, Scientific facilities, and finally Individuals closely tied with the development and investigation of Energetic Materials. The book is intended for readers with a technical or scientific background, active in governmental agencies, research institutes, trade and industry, concerned with the procurement, development, manufacture, investigation and use of Energetic Materials, such as High Explosives, Propellants, Pyrotechnics, Fireworks and Ammunition. The book serves both as a daily reference for the experienced as well as an introduction for the newcomer to the field.
Advanced Energetic Materials
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Author : National Research Council
language : en
Publisher: National Academies Press
Release Date : 2004-01-30
Advanced Energetic Materials written by National Research Council and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-01-30 with Technology & Engineering categories.
Advanced energetic materialsâ€"explosive fill and propellantsâ€"are a critical technology for national security. While several new promising concepts and formulations have emerged in recent years, the Department of Defense is concerned about the nation's ability to maintain and improve the knowledge base in this area. To assist in addressing these concerns, two offices within DOD asked the NRC to investigate and assess the scope and health of the U.S. R&D efforts in energetic materials. This report provides that assessment. It presents several findings about the current R&D effort and recommendations aimed at improving U.S. capabilities in developing new energetic materials technology. This study reviewed U.S. research and development in advanced energetics being conducted by DoD, the DoE national laboratories, industries, and academia, from a list provided by the sponsors. It also: (a) reviewed papers and technology assessments of non-U.S. work in advanced energetics, assessed important parameters, such as validity, viability, and the likelihood that each of these materials can be produced in quantity; (b) identified barriers to scale-up and production, and suggested technical approaches for addressing potential problems; and (c) suggested specific opportunities, strategies, and priorities for government sponsorship of technologies and manufacturing process development.
Ballistics 2014
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Author : Richard G. Ames
language : en
Publisher: DEStech Publications, Inc
Release Date : 2014-10-01
Ballistics 2014 written by Richard G. Ames and has been published by DEStech Publications, Inc this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-10-01 with Technology & Engineering categories.
Original research from around the world on weapons-grade projectiles, warheads, missiles, guns and their effects on target materialsNew information on shaped charges, fire, control strategies, simulation, blast resistance, non-lethal systems and more190 original presentations in two printed volumes, plus searchable CD The first part of this 2-volume set, part of an ongoing series, presents previously unpublished research on the design and modeling of ballistic devices ranging from shells to missiles, including explosives, propellants and internal components. The second part investigates the effects of ballistic penetrants on a variety of targets, including human models, as well as hard targets and diverse armors made from engineered fibers, ceramics, metal alloys and concrete. Data is included on the modeling and testing of novel devices, explosives and shielding strategies. Papers in this text were presented at a symposium organized by the National Defense Industrial Association with the International Ballistics Society. The CD-ROM displays figures and illustrations in articles in full color along with a title screen and main menu screen. Each user can link to all papers from the Table of Contents and Author Index and also link to papers and front matter by using the global bookmarks which allow navigation of the entire CD-ROM from every article. Search features on the CD-ROM can be by full text including all key words, article title, author name, and session title. The CD-ROM has Autorun feature for Windows 2000 with Service Pack 4 or higher products along with the program for Adobe Acrobat Reader with Search 11.0. One year of technical support is included with your purchase of this product.
Explosives
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Author : Rudolf Meyer
language : en
Publisher: John Wiley & Sons
Release Date : 2016-03-18
Explosives written by Rudolf Meyer and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-03-18 with Science categories.
The unrivaled, definitive reference for almost 40 years, this classic work on explosives is now in its seventh, completely revised and updated edition. Some 500 monographic entries, arranged alphabetically, consider the physicochemical properties, production methods, and safe applications of over 120 explosive chemicals. In addition, 70 fuels, additives, and oxidizing agents are discussed as well as the corresponding test methods. Trade, company, and military short names are provided for many of the materials listed, while further key features include a combined index and glossary with terms and abbreviations in English, French, and German, as well as conversion tables and many literature references. Finally, this indispensable source also contains safety data and transport regulations.