Mixed Valence Compounds
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Mixed Valence Compounds
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Author : D.B. Brown
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Mixed Valence Compounds written by D.B. Brown and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
It has been a decade since two seminal reviews demonstrated that mixed-valence compounds share many unique and fascinating features. The insight pro vided by those early works has promoted a great deal of both experimental and theoretical study. As a result of extensive efforts, our understanding of the bonding and properties of mixed-valence compounds has advanced substantially. There has been no compre hensive treatment of mixed-valence compounds since 1967, and the meeting convened at Oxford in September, 1979, provided a unique opportunity to examine the subject and its many ramifications. Mixed-valence compounds play an important role in many fields. Although the major impact of the subject has been in chemistry, its importance has become increasingly clear in solid state physics, geology, and biology. Extensive interest and effort in the field of molecular metals has demonstrated that mixed-valency is a prerequisite for high elec trical conductivity. The intense colors of many minerals have been shown to be due to mixed-valency, and the electron-transfer properties of certain mixed-valence metalloproteins are important in biological processes. Experts from all of these areas participated in this meeting, and the truly interdisciplinary nature of the subject made it a unique learning experience for all in attendance.
Mixed Valence Systems
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Author : Yu-Wu Zhong
language : en
Publisher: John Wiley & Sons
Release Date : 2023-03-09
Mixed Valence Systems written by Yu-Wu Zhong and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-03-09 with Science categories.
Mixed-Valence Systems Comprehensive overview on the advanced development of mixed-valence chemistry Mixed-Valence Systems: Fundamentals, Synthesis, Electron Transfer, and Applications covers all topics related to the theory and experimental results of mixed-valence systems, including the design, synthesis, and applications of mixed-valence compounds containing inorganic, organometallic and organic redox-active centers. The text also covers the recent advances in mixed-valence chemistry, including the development of new mixed-valence systems, transition of mixed valency, better understanding of the spectral characteristics of intervalence charge transfer, and controllable electron transfer related to molecular electronics. In Mixed-Valence Systems, readers can expect to find detailed information on sample topics such as: Characterization and evaluation of mixed-valence systems, electron paramagnetic resonance spectroscopy, and electrochemical methods Optical analysis, important issues in mixed-valence chemistry, transition of mixed valency from localized to delocalized, and solvent control of electron transfer Theoretical background, potential energy surfaces from classical two-state model, and quantum description of the potential energy surfaces Reorganization energies, electronic coupling matrix element and the transition moments, generalized Mulliken–Hush theory, and analysis of the band shape of intervalence charge transfer Strengthening the relationship of mixed-valence electron transfer and molecular electronics, Mixed-Valence Systems is of immense value to researchers and professionals working in the field of electron transfer, molecular electronics, and optoelectronics.
Mixed Valence Compounds
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Author : D. B. Brown
language : en
Publisher:
Release Date : 2014-01-15
Mixed Valence Compounds written by D. B. Brown and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-01-15 with categories.
Mixed Valency Systems Applications In Chemistry Physics And Biology
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Author : K. Prassides
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Mixed Valency Systems Applications In Chemistry Physics And Biology written by K. Prassides and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Mixed valency is one of various names used to describe compounds which contain ions of the same element in two different formal states of oxidation. The existence of mixed valency systems goes far back into the geological evolutionary history of the earth and other planets, while a plethora of mixed valency minerals has attracted attention since antiquity. Indeed, control of the oxidation states of Fe in its oxides (FeO, Fe304' Fe203) was elegantly used in vase painting by the ancient Greeks to produce the characteristic black and red Attic ceramics (Z. Goffer, "Archaeological Chemistry", Wiley, New York, 1980). It was, however, only 25 years ago that two reviews of mixed valency appeared in the literature almost simultaneously, signalling the first attempt to treat mixed valency systems as a separate class of compounds whose properties can be correlated with the molecular and the electronic structure of their members. Then mixed valency phenomena attracted the interest of disparate classes of scientists, ranging from synthetic chemists to solid state physicists and from biologists to geologists. This activity culminated with the NATO ASI meeting in Oxford in 1979. The 1980's saw again a continuing upsurge of interest in mixed valency. Its presence is a necessary factor in the search for highly conducting materials, including molecular metals and superconductors. The highly celebrated high T c ceramic superconducting oxides are indeed mixed valency compounds.
Inorganic Chemistry
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Author : Gary Wulfsberg
language : en
Publisher: University Science Books
Release Date : 2000-03-16
Inorganic Chemistry written by Gary Wulfsberg and has been published by University Science Books this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-03-16 with Science categories.
This is a textbook for advanced undergraduate inorganic chemistry courses, covering elementary inorganic reaction chemistry through to more advanced inorganic theories and topics. The approach integrates bioinorganic, environmental, geological and medicinal material into each chapter, and there is a refreshing empirical approach to problems in which the text emphasizes observations before moving onto theoretical models. There are worked examples and solutions in each chapter combined with chapter-ending study objectives, 40-70 exercises per chapter and experiments for discovery-based learning.
Chemistry Of Mixed Valence Binuclear And Polynuclear Ruthenium Complexes
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Author : Glenn McPherson Tom
language : en
Publisher:
Release Date : 1975
Chemistry Of Mixed Valence Binuclear And Polynuclear Ruthenium Complexes written by Glenn McPherson Tom and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1975 with Complex compounds categories.
Electronic Structure And Magnetism Of Inorganic Compounds
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Author : P Day
language : en
Publisher: Royal Society of Chemistry
Release Date : 2007-10-31
Electronic Structure And Magnetism Of Inorganic Compounds written by P Day and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-10-31 with Science categories.
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
New Directions In Solid State Chemistry
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Author : C. N. R. Rao
language : en
Publisher: Cambridge University Press
Release Date : 1997-02-28
New Directions In Solid State Chemistry written by C. N. R. Rao and has been published by Cambridge University Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1997-02-28 with Science categories.
In the new edition of this widely praised textbook, all the chapters have been revised and the authors have brought the work completely up to date by the addition of new material on numerous topics. In recent years, solid state chemistry has emerged as a very important element of mainstream chemistry and materials science. Students, teachers and researchers need to understand the chemistry of solids because of the crucial role this plays in determining the properties of materials. An understanding of solid state chemistry is also essential in materials design, and many fascinating relationships between the structure and properties of solids have been discovered by chemists. This text requires only an understanding of basic physics, chemistry and crystallography, and is enhanced with the most recent examples, case studies and references. It will be of value to advanced students and researchers studying solid state chemistry and materials science as a text and reference work.
Comprehensive Coordination Chemistry Ii
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Author : J. A. McCleverty
language : en
Publisher: Newnes
Release Date : 2003-12-03
Comprehensive Coordination Chemistry Ii written by J. A. McCleverty and has been published by Newnes this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-12-03 with Science categories.
Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Valence Instabilities And Related Narrow Band Phenomena
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Author : R. Parks
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Valence Instabilities And Related Narrow Band Phenomena written by R. Parks and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Those well-intending workers, especially theorists, who have viewed hungrily the mixed valence problem, but have not yet made the bold leap, might be comforted to learn that the Rochester conference left the virginal state of that problem essentially intact. That is not to say that the event was prosaic. Indeed, the conferees exhibited a level of effervescence appropriate to the freshness and challenge of the problem at hand. If the meeting failed to solve major questions, it at least established several guidelines. One is that future experimental efforts, at least on a short time scale, might be spent most profitably on those substances which exhibit consistent, and hence probably intrinsic, behavior from laboratory to laboratory. A recurring message, not always subtle, to the·theorists was that piecemeal approaches to the mixed valence problem, characteristic of much of the work to date, are of limited usefulness. For at the core of the problem one has a melange of boot-strapping interac tions which must be sorted out and dealt with properly. Para phrasing Phil Anderson (see Epilogue), the mixed valence problem is in the same category of problems which are failing to be done in field theory these days.