Molecular Clusters Of The Main Group Elements
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Molecular Clusters Of The Main Group Elements
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Author : Matthias Driess
language : en
Publisher: John Wiley & Sons
Release Date : 2008-11-21
Molecular Clusters Of The Main Group Elements written by Matthias Driess and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-11-21 with Science categories.
With more than 20 contributions from leading research groups, this book provides essential information for chemists and materials scientists working with molecular clusters. It treats both homonuclear and heteronuclear clusters, including: the theory and concepts in main-group cluster chemistry, * novel boranes and heteroboranes, * silicon/germanium/tin clusters, * alkali metal suboxides, * clusters in alloys with mercury, * chalkogen clusters * and numerous other compound classes. The whole is illustrated by examples of the great potential for technical applications such as electron storage, cancer therapy and in optoelectronic devices. Its systematic coverage of all relevant main group elements makes this the prime reference source in the field.
Cluster Chemistry
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Author : Guillermo Gonzalez-Moraga
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-11-09
Cluster Chemistry written by Guillermo Gonzalez-Moraga and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-09 with Science categories.
Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.
Cluster Molecules Of The P Block Elements
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Author : Catherine E. Housecroft
language : en
Publisher: Oxford University Press, USA
Release Date : 1994
Cluster Molecules Of The P Block Elements written by Catherine E. Housecroft and has been published by Oxford University Press, USA this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994 with Chemical elements categories.
Provides a comprehensive survey of the structures, bonding, synthesis, and reactivity of the title molecules. The text includes clusters found in the elemental state as well as compounds. Terms commonly encountered in cluster chemistry are defined and polyhedral frameworks are described.
Atomic And Molecular Clusters
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Author : Elliot R. Bernstein
language : en
Publisher: Elsevier Publishing Company
Release Date : 1990
Atomic And Molecular Clusters written by Elliot R. Bernstein and has been published by Elsevier Publishing Company this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990 with Science categories.
The last fifteen years have seen a veritable explosion of clusters research brought about by two relatively new experimental advances - supersonic jet expansions creating cold high density atomic and molecular beams, and laser (mass and optical) spectroscopy. The success and power of these two techniques, taken together and applied to the study of atomic and molecular clusters, are described in this volume. The field of cluster study is a very broad one, propelled by both the potential application of cluster results to many bulk systems and interest in clusters as systems in their own right. The eclectic nature of the collection of chapters in this book reflects well the diverse nature of this area of chemical physics. The book begins with one of the most suprising and controversial of recent cluster studies - those for the carbon system. As with bulk and molecular carbon chemistry, the chemistry of carbon clusters seems to be unique. Nonmetallic main group clusters also form a very interesting set of systems and their structure and chemistry are as fascinating as they are varied. Diatomic/atomic clusters and small polyatomic clusters demonstrate an incredible amount of spectroscopic detail and thus structure, dynamics and, in some instances, chemistry can be characterized for them. Clusters of larger molecules also yield information on structure, dynamics and chemistry but can in addition give information on changes in molecular structure with degree of solvation. As clusters become larger they begin to assume the properties of bulk systems. Finally, some chapters discuss the nucleation and growth of clusters, each from its own unique perspective and point of view. Current efforts involve following these processes from the formation of a two-molecule cluster to liquid drop. Atomic and Molecular Clusters provides the researcher with a survey of the current status of the field and will also be of interest to the student who may discover a new and exciting area of investigation.
Rings Clusters And Polymers Of Main Group And Transition Elements
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Author : H. W. Roesky
language : en
Publisher: Elsevier Publishing Company
Release Date : 1989
Rings Clusters And Polymers Of Main Group And Transition Elements written by H. W. Roesky and has been published by Elsevier Publishing Company this book supported file pdf, txt, epub, kindle and other format this book has been release on 1989 with Science categories.
The chemistry of rings, clusters and polymers is becoming an important branch of inorganic and organometallic chemistry. Although inorganic rings have been known for more than 150 years, they have only been structurally characterized within the last fifty years. Inorganic and organometallic clusters and polymers have recently become the subject of intense interest and study because of their unusual properties and their potential for applications in the areas of catalysis, electronics and ceramics. Transition metal clusters have been examined as models for heterogeneous catalysts. Both rings and clusters might function as potential building blocks for extended solid state systems. In comparison with organic polymers, however, general and versatile methods for the synthesis of inorganic and organometallic polymers are not readily available. In particular, the preparation of polymers containing transition metal atoms in the polymer backbone is a challenge to inorganic chemistry. This book describes the rapid development which has taken place in this field.
Clusters And Colloids
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Author : Günter Schmid
language : en
Publisher: Wiley-VCH Verlag GmbH
Release Date : 1994
Clusters And Colloids written by Günter Schmid and has been published by Wiley-VCH Verlag GmbH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994 with Science categories.
This book offers a comprehensive overview of the rapidly developing field of cluster science. In an interdisciplinary approach, basic concepts as well as recent developments in research and practical applications are authoritatively discussed by leading authors. Topics covered include 'naked' metal clusters, clusters stabilized by ligands, clusters in solids, and colloids. The reader will find answers to questions like: * How many metal atoms must a particle have to exhibit metallic properties? * How can the large specific surface of clusters and colloids be employed in catalysts? * How can metal clusters be introduced into solid hosts? * Which effects are responsible for the transition from isolated to condensed clusters? The editor has succeeded in bringing the contributions of various authors together into a homogeneous, readable book, which will be useful for the academic and industrial reader alike.
Structural Chemistry Across The Periodic Table
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Author : Emeritus Professor and Wei Lun Research Professor Thomas Cw Mak
language : en
Publisher: Oxford University Press
Release Date : 2023-10-12
Structural Chemistry Across The Periodic Table written by Emeritus Professor and Wei Lun Research Professor Thomas Cw Mak and has been published by Oxford University Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-10-12 with Chemistry, Inorganic categories.
This book is an expanded and updated version of Part III of the authors' previous work, Advanced Structural Inorganic Chemistry (OUP 2008). The original part deals with main-group elements, the rare-earth elements, transition-metal clusters, and supramolecular systems. In this new book, selected material from significant advances in the past decade has been added, with particular emphasis on compounds that exemplify new types of bonds such as sigma-hole, triel bond, tetrel bond, pnictogen bond, chalcogen bond, halogen bond, halogen-halogen interaction, aerogen bond, as well as quintuple and sextuple metal-metal bonds. Other new topics include actinide compounds, metallophilicity, heterometallic macrocycles and cages, com- and dis-proportionation reactions, hydrogen-bonded organic frameworks (HOFs), halogen-bonded organic frameworks, halogen-halogen interactions in supramolecular frameworks, covalent organic frameworks (COFs), and metal-organic frameworks (MOFs).
Inorganic Chemistry In Focus Iii
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Author : Gerd Meyer
language : en
Publisher: John Wiley & Sons
Release Date : 2006-12-13
Inorganic Chemistry In Focus Iii written by Gerd Meyer and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-12-13 with Science categories.
Metal clusters are on the brink between molecules and nanoparticles in size. With molecular, nano-scale, metallic as well as non-metallic aspects, metal clusters are a growing, interdisciplinary field with numerous potential applications in chemistry, catalysis, materials and nanotechnology. This third volume in the series of hot topics from inorganic chemistry covers all recent developments in the field of metal clusters, with some 20 contributions providing an in-depth view. The result is a unique perspective, illustrating all facets of this interdisciplinary area: * Inter-electron Repulsion and Irregularities in the Chemistry of Transition Series * Stereochemical Activity of Lone Pairs in Heavier Main Group Element Compounds * How Close to Close Packing? * Forty-Five Years of Praseodymium Diiodide * Centered Zirconium Clusters * Titanium Niobium Oxychlorides * Trinuclear Molybdenum and Tungsten Cluster Chalcogenides * Current State of (B,C,N)-Compounds of Calcium and Lanthanum * Ternary Phases of Lithium with Main-Group and Late-Transition Metals * Polar Intermetallics and Zintl Phases along the Zintl Border * Rare Earth Zintl Phases * Structure-Property Relationships in Intermetallics * Ternary and Quaternary Niobium Arsenide Zintl Phases * The Building Block Approach to Understanding Main-Group-Metal Complex Structures * Cation-Deficient Quaternary Thiospinels * A New Class of Hybrid Materials via Salt Inclusion Synthesis * Layered Perrhenate and Vanadate Hybrid Solids * Hydrogen Bonding in Metal Halides * Syntheses and Catalytic Properties of Titanium Nitride Nanoparticles * Solventless Thermolysis * New Potential Scintillation Materials in Borophosphate Systems. With its didactical emphasis, this volume addresses a wide readership, such that both students and specialists will profit from the expert contributions.
Rings Clusters And Polymers Of The Main Group Elements
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Author : Alan H. Cowley
language : en
Publisher:
Release Date : 1983
Rings Clusters And Polymers Of The Main Group Elements written by Alan H. Cowley and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1983 with Science categories.
Molecular Geometry
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Author : Alison Rodger
language : en
Publisher: Butterworth-Heinemann
Release Date : 2014-05-16
Molecular Geometry written by Alison Rodger and has been published by Butterworth-Heinemann this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-05-16 with Science categories.
Molecular Geometry discusses topics relevant to the arrangement of atoms. The book is comprised of seven chapters that tackle several areas of molecular geometry. Chapter 1 reviews the definition and determination of molecular geometry, while Chapter 2 discusses the unified view of stereochemistry and stereochemical changes. Chapter 3 covers the geometry of molecules of second row atoms, and Chapter 4 deals with the main group elements beyond the second row. The book also talks about the complexes of transition metals and f-block elements, and then covers the organometallic compounds and transition metal clusters. The last chapter tackles the consequences of small, local variations in geometry. The text will be of great use to chemists who primarily deal with the properties of molecules and atoms.