Molecular Metal Metal Bonds
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Molecular Metal Metal Bonds
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Author : Stephen T. Liddle
language : en
Publisher: John Wiley & Sons
Release Date : 2016-03-16
Molecular Metal Metal Bonds written by Stephen T. Liddle and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-03-16 with Science categories.
Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.
Metal Metal Bonds And Clusters In Chemistry And Catalysis
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Author : John P. Fackler Jr.
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-11-22
Metal Metal Bonds And Clusters In Chemistry And Catalysis written by John P. Fackler Jr. and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-22 with Science categories.
This book contains a series of papers and abstracts from the 7th Industry-University Cooperative Chemistry Program symposium held in the spring of 1989 at Texas A&M University. The symposium was larger than previous IUCCP symposia since it also celebrated the 25 years that had elapsed since the initial discovery by F. A. Cotton and his co-workers of the existence of metal-metal quadruple bonds. Cotton's discovery demonstrated that multiple bonding in inorganic systems is not governed by the same constraints observed in organic chemistry regarding s and p orbital involvement. The d orbitals are involved in the multiple bonding description. The quadruple bond involves considerable d orbital overlap between adjacent metal centers. Part I of this series of papers focuses upon the impact of this discovery and describes further contributions to the development of the field. Multiple metal-metal bonding now is known to permeate broad areas of transition metal chemistry. The understanding of metal-metal bonding that developed as a result of the discovery of multiple metal-metal bonding awakened a new chemistry involving metal clusters. Clusters were defined by Cotton to be species containing metal-metal bonding. Clusters in catalysis therefore seemed a logical grouping of papers in this symposium. Clusters play an every increasing role in the control of chemical reactions. Part II of this book describes some of the interesting new developments in this field. In Part III the papers examine the role clusters play in describing and understanding solid state materials.
Metal Metal Bonding
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Author : Gerard Parkin
language : en
Publisher: Springer
Release Date : 2010-03-10
Metal Metal Bonding written by Gerard Parkin and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010-03-10 with Science categories.
John Berry: Metal-Metal Bonds in Chains of Three or More Metal Atoms: From Homometallic to Heterometallic Chains.- Malcolm Chisholm: Electronically Coupled MM Quadruple Bonded Complexes of Molybdenum and Tungsten.- Philip Power: Transition Metal Complexes Stabilized by Bulky Terphenyl Ligands: Applications to Metal–Metal Bonded Compounds.- Gerard Parkin: Metal–Metal Bonding in Bridging Hydride and Alkyl Compounds.- Roland Fischer and Gernot Frenking: Structure and Bonding of Metal Rich Coordination Compounds Containing Low Valent Ga(I) and Zn(I) Ligands.- Mike Hill: Homocatenation of Metal and Metalloid Main Group Elements.- Constandinos A. Tsipis: Aromaticity/Antiaromaticity in "Bare" and ‘‘Ligand-Stabilized’’ Rings of Metal Atoms.- Alexander Boldyrev: All-Transition Metal Aromaticity and Antiaromaticity.
Multiple Bonds Between Metal Atoms
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Author : F. Albert Cotton
language : en
Publisher: Springer Science & Business Media
Release Date : 2006-07-31
Multiple Bonds Between Metal Atoms written by F. Albert Cotton and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-07-31 with Science categories.
Provides historical perspective as well as current data Abundantly illustrated with figures redrawn from literature data Covers all pertinent theory and physical chemistry Catalytic and chemotherapeutic applications are included
Compounds Of The Transition Elements Involving Metal Metal Bonds
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Author : D. L. Kepert
language : en
Publisher: Elsevier
Release Date : 2016-06-06
Compounds Of The Transition Elements Involving Metal Metal Bonds written by D. L. Kepert and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-06-06 with Science categories.
Compounds of the Transition Elements Involving Metal-Metal Bonds focuses on compounds of the transition elements involving metal-metal bonds. Emphasis is on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. Factors that influence the formation, stability, and properties of such compounds, as well as their application in various fields of chemistry and physics, are discussed. This book is divided into four sections and begins with a classification of metal-metal bonds and some of the physical and chemical methods used to study them, including X-ray crystallography, magnetic susceptibility and electron spin resonance, nuclear spin resonance, Mössbauer measurements, infrared and Raman spectroscopy, visible and ultraviolet spectroscopy, mass spectrometry, electrical conductivity, electrochemistry, and chemical reactivity. Factors influencing the strength of metal-metal bonds in metals and compounds are also examined. The remaining sections deal with metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. This monograph will be a useful resource for inorganic chemists.
Reactivity Of Metal Metal Bonds
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Author : Malcolm H. Chisholm
language : en
Publisher:
Release Date : 1981
Reactivity Of Metal Metal Bonds written by Malcolm H. Chisholm and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1981 with Science categories.
The Metallic Bond And The Structure Of Metals
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Author : Vsevolod Konstantinovich Grigorovich
language : en
Publisher:
Release Date : 1989
The Metallic Bond And The Structure Of Metals written by Vsevolod Konstantinovich Grigorovich and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1989 with Science categories.
Very Good,No Highlights or Markup,all pages are intact.
Metal To Metal Bonded States Of The Main Group Elements
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Author : Michael James Taylor
language : en
Publisher:
Release Date : 1975
Metal To Metal Bonded States Of The Main Group Elements written by Michael James Taylor and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1975 with Science categories.
Chemical Bonds Outside Metal Surfaces
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Author : Norman H. March
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Chemical Bonds Outside Metal Surfaces written by Norman H. March and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
The problem of molecules interacting with metal surfaces has for a very long time been recognized to be of considerable technological as well as fundamental importance. Thus in the former category, a substantial number of important synthetic reactions for industrial purposes make use of metal surfaces as catalysts. Or again, problems of corrosion of metals are of great practical importance, such as in nuclear-reactor technology [see, for instance, my earlier articles, in: Physics Bulletin, Volume 25, p. 582, Institute of Physics, UK (1974); and in: Physics and Contemporqry Needs (Riazuddin, ed. ), Vol. 1, p. 53, Plenum Press, New York (1977)]. It is therefore of significance to strive to gain a more fundamental understand ing of the atomic, and ultimately the electronic, processes that occur when a molecule is brought into the proximity of a metal surface. The present volume focuses mainly on the theory and concepts involved; however, it is intended for readers in chemistry, physics, and materials science who are not specialists in theory but nevertheless wish to learn more about this truly interdisciplinary area of theoretical science. The aim of the book is to present the way in which valence theory can be synthesized with the understanding of metals that has been gained over the last half century or so. While advanced theory has at times been necessary, is largely presented in an extensive set of Appendixes.
Physics And Chemistry Of Metal Cluster Compounds
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Author : L.J. de Jongh
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-03-09
Physics And Chemistry Of Metal Cluster Compounds written by L.J. de Jongh and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-03-09 with Science categories.
On Friday, February 20, 1980, I had the pleasure to be present at the inaugural lecture of my colleague Jan Reedijk, who had just been named at the Chair of Inorganic Chemistry of Leiden University. According to tradition, the ceremony took place in the impressive Hall of the old University Academy Building. In the course of his lecture, Jan mentioned a number of recent developments in chemistry which had struck him as particularly important or interesting. Among those was the synthesis of large metal cluster compounds, and, to my luck, he showed a slide ofthe molecular structure of [PtI9(C)b]4-. (To my luck, since at traditional Leiden University it is quite unusual to show slides at such ceremonies.) This constituted my first acquaintance with this exciting new class of materials. I became immediately fascinated by this molecule, partly because of the esthetic beauty of its fivefold symmetry, partly because as a physicist it struck me that it could be visualized as an "embryonically small" metal particle, embedded in a shell of CO ligands.