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Molecular Orbitals Of Transition Metal Complexes


Molecular Orbitals Of Transition Metal Complexes
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Molecular Orbitals Of Transition Metal Complexes


Molecular Orbitals Of Transition Metal Complexes
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Author : Yves Jean
language : en
Publisher: OUP Oxford
Release Date : 2005-03-24

Molecular Orbitals Of Transition Metal Complexes written by Yves Jean and has been published by OUP Oxford this book supported file pdf, txt, epub, kindle and other format this book has been release on 2005-03-24 with Science categories.


This book starts with the most elementary ideas of molecular orbital theory and leads the reader to an understanding of the electronic structure, geometry and reactivity of transition metal complexes. The pedagogical aim is to give the student a theoretical method of analysis which relies on some simple ideas (symmetry and overlap), applicable to problems of varying complexity.



Molecular Orbitals Of Transition Metal Complexes


Molecular Orbitals Of Transition Metal Complexes
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Author : Yves Jean
language : en
Publisher: OUP Oxford
Release Date : 2005-03-24

Molecular Orbitals Of Transition Metal Complexes written by Yves Jean and has been published by OUP Oxford this book supported file pdf, txt, epub, kindle and other format this book has been release on 2005-03-24 with Science categories.


This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions such as symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter and the structure of the "d block" is used to trace the relationships between the electronic structure and the geometry of the complexes. The third chapter studies the change in analysis when the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (e.g. structure and reactivity). The fifth chapter deals with the "isolobal analogy" which points out the resemblance between the molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some of the complexes studied in the earlier chapters.



An Introduction To Molecular Orbitals


An Introduction To Molecular Orbitals
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Author : Yves Jean
language : en
Publisher: Oxford University Press on Demand
Release Date : 1993

An Introduction To Molecular Orbitals written by Yves Jean and has been published by Oxford University Press on Demand this book supported file pdf, txt, epub, kindle and other format this book has been release on 1993 with Science categories.


This text for advanced undergraduate and graduate students guides the reader through a smooth progression from the most elementary ideas of molecular orbital theory to an understanding of the electronic structure, geometry, and reactivity of large molecules. It starts with simple molecules and proceeds to relatively large organometallic complexes. The slant is theoretical, but in the last chapter the authors strengthen the link between theory and experiment. Focusing on basic concepts, the authors take a qualitative approach, which enables this text to fill a void in the undergraduate curriculum. The book is intended as a core or supplementary text in an advanced chemistry course.



Metal Ligand Bonding


Metal Ligand Bonding
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Author : Rob Janes
language : en
Publisher: Royal Society of Chemistry
Release Date : 2004

Metal Ligand Bonding written by Rob Janes and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004 with Education categories.


The material addressed in this book forms the foundation of undergraduate lecture courses on d-block chemistry and facilitates learning through various key features.



Orbital Interactions In Chemistry


Orbital Interactions In Chemistry
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Author : Thomas A. Albright
language : en
Publisher: John Wiley & Sons
Release Date : 2013-03-28

Orbital Interactions In Chemistry written by Thomas A. Albright and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-03-28 with Science categories.


Explains the underlying structure that unites all disciplinesin chemistry Now in its second edition, this book explores organic,organometallic, inorganic, solid state, and materials chemistry,demonstrating how common molecular orbital situations arisethroughout the whole chemical spectrum. The authors explore therelationships that enable readers to grasp the theory thatunderlies and connects traditional fields of study withinchemistry, thereby providing a conceptual framework with which tothink about chemical structure and reactivity problems. Orbital Interactions in Chemistry begins by developingmodels and reviewing molecular orbital theory. Next, the bookexplores orbitals in the organic-main group as well as in solids.Lastly, the book examines orbital interaction patterns that occurin inorganic-organometallic fields as well as clusterchemistry, surface chemistry, and magnetism in solids. This Second Edition has been thoroughly revised andupdated with new discoveries and computational tools since thepublication of the first edition more than twenty-five years ago.Among the new content, readers will find: * Two new chapters dedicated to surface science and magneticproperties * Additional examples of quantum calculations, focusing oninorganic and organometallic chemistry * Expanded treatment of group theory * New results from photoelectron spectroscopy Each section ends with a set of problems, enabling readers totest their grasp of new concepts as they progress through the text.Solutions are available on the book's ftp site. Orbital Interactions in Chemistry is written for bothresearchers and students in organic, inorganic, solid state,materials, and computational chemistry. All readers will discoverthe underlying structure that unites all disciplines inchemistry.



Transition Metal Compounds


Transition Metal Compounds
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Author : Daniel Khomskii
language : en
Publisher: Cambridge University Press
Release Date : 2014-10-23

Transition Metal Compounds written by Daniel Khomskii and has been published by Cambridge University Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-10-23 with Science categories.


This book describes all aspects of the physics of transition metal compounds, providing a comprehensive overview of this diverse class of solids. Set within a modern conceptual framework, this is an invaluable, up-to-date resource for graduate students, researchers and industrial practitioners in solid-state physics and chemistry, materials science, and inorganic chemistry.



Comprehensive Coordination Chemistry Ii


Comprehensive Coordination Chemistry Ii
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Author : J. A. McCleverty
language : en
Publisher: Newnes
Release Date : 2003-12-03

Comprehensive Coordination Chemistry Ii written by J. A. McCleverty and has been published by Newnes this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-12-03 with Science categories.


Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.



The Organometallic Chemistry Of The Transition Metals


The Organometallic Chemistry Of The Transition Metals
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Author : Robert H. Crabtree
language : en
Publisher: John Wiley & Sons
Release Date : 2011-09-20

The Organometallic Chemistry Of The Transition Metals written by Robert H. Crabtree and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-09-20 with Science categories.


"One impressive and compressive book. . . . This review would have to be book size to do full justice to all the insights in this volume." —Journal of Metals Online Fully updated and expanded to reflect recent advances, this Fifth Edition of the classic text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. With increased focus on organic synthesis applications, nanoparticle science, and green chemistry, the Fifth Edition brings this vital resource up to date. New to the Fifth Edition: Chapters have been updated with relevant examples in the field, modern trends, and new applications; the organic applications chapter has been completely rewritten New end-of-chapter problems, along with their solutions Coverage enhanced with developments in nanoparticle science Increased focus on green chemistry An unparalleled pedagogic resource as well as a valuable working reference for professional chemists, with comprehensive coverage and up-to-date information, students and researchers in organic and organometallic chemistry will turn to The Organometallic Chemistry of the Transition Metals, Fifth Edition for the critical information they need on organometallic compounds, their preparation, and their use in synthesis.



Organometallic Chemistry And Catalysis


Organometallic Chemistry And Catalysis
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Author : Didier Astruc
language : en
Publisher: Springer Science & Business Media
Release Date : 2007-08-02

Organometallic Chemistry And Catalysis written by Didier Astruc and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-08-02 with Science categories.


This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.



Ligand Design In Metal Chemistry


Ligand Design In Metal Chemistry
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Author : Mark Stradiotto
language : en
Publisher: John Wiley & Sons
Release Date : 2016-10-17

Ligand Design In Metal Chemistry written by Mark Stradiotto and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-10-17 with Science categories.


The design of ancillary ligands used to modify the structural and reactivity properties of metal complexes has evolved into a rapidly expanding sub-discipline in inorganic and organometallic chemistry. Ancillary ligand design has figured directly in the discovery of new bonding motifs and stoichiometric reactivity, as well as in the development of new catalytic protocols that have had widespread positive impact on chemical synthesis on benchtop and industrial scales. Ligand Design in Metal Chemistry presents a collection of cutting-edge contributions from leaders in the field of ligand design, encompassing a broad spectrum of ancillary ligand classes and reactivity applications. Topics covered include: Key concepts in ligand design Redox non-innocent ligands Ligands for selective alkene metathesis Ligands in cross-coupling Ligand design in polymerization Ligand design in modern lanthanide chemistry Cooperative metal-ligand reactivity P,N Ligands for enantioselective hydrogenation Spiro-cyclic ligands in asymmetric catalysis This book will be a valuable reference for academic researchers and industry practitioners working in the field of ligand design, as well as those who work in the many areas in which the impact of ancillary ligand design has proven significant, for example synthetic organic chemistry, catalysis, medicinal chemistry, polymer science and materials chemistry.