Mxenes


Mxenes
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Mxenes Next Generation 2d Materials


Mxenes Next Generation 2d Materials
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Author : Jay Singh
language : en
Publisher: John Wiley & Sons
Release Date : 2024-03-25

Mxenes Next Generation 2d Materials written by Jay Singh and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-03-25 with Technology & Engineering categories.


MXenes One-stop reference explaining the manufacturing, design, and many applications of MXenes in an easy-to-understand linear format MXenes is a one-stop reference on MXenes, a promising new class of 2D materials, discussing the routes of functionalization and modifications towards high performance materials and providing broad coverage of lab synthesis methods. To aid in reader comprehension, this text presents the topic in a linear fashion, starting with an introduction to MXenes and ending with a comparison of MXenes to other similar 2D materials, discussing limitations, advantages, future perspectives, and challenges of both MXenes and MXene-based materials. The text covers up-to-date research in the field with a strong focus on novel findings in various devices along with core technological advancements that have been made in recent years. MXenes discusses sample topics such as: Properties of MXenes, including strong hydrophilicity, exceptional conductivity, high elastic mechanical strength, large surface-to-volume ratio, and chemical stability Applications of MXenes in energy storage, optoelectronics, spintronics, biomedicine, electro-catalysis, photocatalysis, membrane separation, supercapacitors, and batteries Performance factors that can hinder the efficacy of MXenes, including aggregation, difficulty obtaining a single layer, restacking, and oxidation of MXene nanosheets State-of-the-art progress in the field of gas sensors and electrochemical biosensors for the detection of various biomolecules, pharmaceutical drugs, and environmental pollutants Containing everything readers need to know about this exciting new class of 2D materials, MXenes is an essential reference for professionals working in advanced materials science, flexible electronics, nanoelectronics, and the energy industry, along with chemists, material scientists, and engineers in nanoscience and nanotechnology.



Transition Metal Carbides And Nitrides Mxenes Handbook


Transition Metal Carbides And Nitrides Mxenes Handbook
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Author : Chuanfang Zhang
language : en
Publisher: John Wiley & Sons
Release Date : 2024-07-23

Transition Metal Carbides And Nitrides Mxenes Handbook written by Chuanfang Zhang and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-07-23 with Technology & Engineering categories.


A comprehensive overview of the synthesis of high-quality MXenes In Transition Metal Carbides and Nitrides (MXenes) Handbook: Synthesis, Processing, Properties and Applications, a team of esteemed researchers provides an expert review encompassing the fundamentals of precursor selection, MXene synthesis, characterizations, properties, processing, and applications. You’ll find detailed discussions of the selection of MXene members for specific applications, as along with summaries of the physical and chemical properties of MXenes, including electrical, mechanical, optical, electromechanical, electrochemical, and electromagnetic properties. The authors delve into both successful and unsuccessful synthesis examples, offering detailed explanations of various failures to facilitates a comprehensive understanding of the reasons behind unsuccessful syntheses. Additionally, they provide detailed examinations on the characterizations of MXenes, empowering readers to develop a sophisticated understanding of how to achieve optimal quality, flake size, oxidation states, and more. You’ll also find: A thorough review of common applications of MXenes, including electrochemical applications, electromagnetic interference shielding, communications devices, and more Comprehensive explorations of solution and non-solution processing of MXenes Practical discussions of the synthesis of high-quality MXene powders, colloidal solutions and flakes, including information about MXene precursors Fulsome treatments of MXene precursor selection and their impact on MXene quality Tailored to meet the needs of graduate students, researchers, and scientists in the areas of materials science, inorganic chemistry, and physical chemistry, the Transition Metal Carbides and Nitrides (MXenes) Handbook will also benefit biochemists and professionals working in drug delivery.



Mxenes And Their Composites


Mxenes And Their Composites
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Author : Kishor Kumar Sadasivuni
language : en
Publisher: Elsevier
Release Date : 2021-10-07

Mxenes And Their Composites written by Kishor Kumar Sadasivuni and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-10-07 with Technology & Engineering categories.


MXenes and their Composites: Synthesis, Properties and Potential Applications presents a state of the art overview of the recent developments on the synthesis, functionalization, properties and emerging applications of two-dimensional (2D) MXenes and their composites.The book systematically describes the state-of-the-art knowledge and fundamentals of MXene synthesis, structure, surface chemistry and functionalization. The book also discusses the unique electronic, optical, mechanical and topological properties of MXenes. Besides, this book covers the various emerging applications of MXenes and their composites across different fields such as energy storage and conversion, gas sensing and biosensing, rechargeable lithium and sodium-ion batteries, lithium-sulphur and multivalent batteries, electromagnetic interference shielding, hybrid capacitors and supercapacitors, hydrogen storage, catalysis and photoelectrocatalysis, gas separation and water desalination, environmental remediation and medical and biomedical applications. All these applications have been efficiently discussed in the specific chapters and in each case, the processing of MXene composites has also been discussed.This book will be an excellent reference for scientists and engineers across various disciplines and industries working in the field of highly promising 2D MXenes and their composites. The book will also act as a guide for academic researchers, material scientists, and advanced students in investigating the new applications of 2D MXenes based materials. Covers fundamentals of technologically important MAX phases, MXene derivatives, MXene synthesis methods, intercalation and delamination strategies, surface functionalization, fundamental characteristics and properties Demonstrates major application areas of MXenes, including catalytic, energy storage and energy generation, flexible electronics, EMI shielding, sensors and biosensors, medical and biomedical, gas separation and water desalination Presents a detailed discussion on the processing and performance of various MXenes towards different applications



Mxenes


Mxenes
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Author : Yury Gogotsi
language : en
Publisher: CRC Press
Release Date : 2023-08-24

Mxenes written by Yury Gogotsi and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-08-24 with Technology & Engineering categories.


Since their discovery in 2011, MXenes (2D carbides, nitrides, and carbonitrides of early transition metals) have developed into one of the largest and most intensively studied families of 2D materials. They offer unique properties and are being explored in a large variety of applications. This book compiles the most important research from a pioneer of the field, Professor Yury Gogotsi, and his interdisciplinary research team, as well as numerous collaborators worldwide. It reports on the discovery and rise of MXenes and describes their synthesis and processing, properties, and incorporation into polymer, ceramic, and metal matrices to produce composites. It also discusses the potential of MXenes for use in energy storage, optics, electronics, and sensing, as well as biomedical, environmental, and electrocatalysis applications. The book will appeal to anyone interested in nanomaterials and their synthesis, properties, and applications.



Mxenes Fundamentals And Applications


Mxenes Fundamentals And Applications
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Author : Abdullah M. Asiri
language : en
Publisher: Materials Research Forum LLC
Release Date : 2019-06-20

Mxenes Fundamentals And Applications written by Abdullah M. Asiri and has been published by Materials Research Forum LLC this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-06-20 with Technology & Engineering categories.


This is the very first book on the highly promising topic of MXenes; focusing on their fundamental characteristics and properties, fabrication techniques and applications. MXenes are two-dimensional materials consisting of few atoms thick layers of transition metal carbides or nitrides. These are characterized by high electrical conductivity, good hydrophilicity, chemical stability, and ultrathin 2D sheet-like morphology. Applications in the energy, environmental, biomedical and electronic industries include catalysis, membrane separation, supercapacitors, hybrid-ion capacitors, batteries, flexible electronics, hydrogen storage, nanoelectronics, and sensors.



Mxenes


Mxenes
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Author : Subhendu Chakroborty
language : en
Publisher: CRC Press
Release Date : 2024-08-07

Mxenes written by Subhendu Chakroborty and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-08-07 with Technology & Engineering categories.


This book introduces MXenes and provides a summary of current discoveries in their synthesis, properties, characterization techniques, and emerging applications in several fields. It explores MXenes' distinctive electrical, mechanical, and biological features, as well as their applications. It discusses the various emerging applications of MXenes in a variety of fields, including regenerative medicine and tissue engineering, separation membranes, photocatalytic hydrogen production, environmental applications, and so forth. Features: Provides comprehensive review of synthesis and application of MXenes in 2D materials Explores greener approaches that reduce the environmental impact and cost of the process Includes frameworks for assessing the balance between the synthesis and applications Discusses an overview of MXenes with a focus on energy, health, and medical applications that can be improved with new encapsulation Reviews the modern spectroscopic instruments that are utilized in sophisticated characterization methods This book is aimed at researchers and graduate students in materials engineering, nanomaterials, and 2D materials.



2d Metal Carbides And Nitrides Mxenes


2d Metal Carbides And Nitrides Mxenes
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Author : Babak Anasori
language : en
Publisher: Springer Nature
Release Date : 2019-10-30

2d Metal Carbides And Nitrides Mxenes written by Babak Anasori and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-10-30 with Technology & Engineering categories.


This book describes the rapidly expanding field of two-dimensional (2D) transition metal carbides and nitrides (MXenes). It covers fundamental knowledge on synthesis, structure, and properties of these new materials, and a description of their processing, scale-up and emerging applications. The ways in which the quickly expanding family of MXenes can outperform other novel nanomaterials in a variety of applications, spanning from energy storage and conversion to electronics; from water science to transportation; and in defense and medical applications, are discussed in detail.



Recent Advances And Allied Applications Of Mxenes


Recent Advances And Allied Applications Of Mxenes
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Author : Inamuddin
language : en
Publisher: Materials Research Forum LLC
Release Date : 2024-01-15

Recent Advances And Allied Applications Of Mxenes written by Inamuddin and has been published by Materials Research Forum LLC this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-01-15 with Technology & Engineering categories.


Since 2011, the MAX phase derivatives MXenes are constantly expanding in terms of crystallographic and composition variability. Several advancements have been made in the previous few years that have accelerated the production of novel MXenes with better chemical diversification and crystal structures. This book is intended to present the latest applicational advancements of MXenes in diversified sectors. Keywords: MAX Phase, MXene, MXene-Based Composite, MXene Symmetric Supercapacitor, MXene Asymmetric Supercapacitor, MXene Micro Supercapacitor, MXene Transparent Supercapacitor, 2D Materials, EMI shielding, Nanophotonics, MXenes in Photodetectors, MXenes in Electrocatalysis.



Fundamental Aspects And Perspectives Of Mxenes


Fundamental Aspects And Perspectives Of Mxenes
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Author : Mohammad Khalid
language : en
Publisher: Springer Nature
Release Date : 2022-06-06

Fundamental Aspects And Perspectives Of Mxenes written by Mohammad Khalid and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-06-06 with Technology & Engineering categories.


This book presents the fundamental aspects, recent developments in fabrication and characterization techniques, structure, properties, and emerging applications of MXenes. It shows the advancement in scale-up, challenges, and their futuristic perspectives. An overview of all the latest developments in energy storage and conversion applications, catalysis, environmental remediation, and radiation shielding, etc is reported.



Synthesis And Transport Properties Of 2d Transition Metal Carbides Mxenes


Synthesis And Transport Properties Of 2d Transition Metal Carbides Mxenes
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Author : Joseph Halim
language : en
Publisher: Linköping University Electronic Press
Release Date : 2018-09-28

Synthesis And Transport Properties Of 2d Transition Metal Carbides Mxenes written by Joseph Halim and has been published by Linköping University Electronic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-09-28 with categories.


Since the isolation and characterization of graphene, there has been a growing interest in 2D materials owing to their unique properties compared to their 3D counterparts. Recently, a family of 2D materials of early transition metal carbides and nitrides, labelled MXenes, has been discovered (Ti2CTz, Ti3C2Tz, Mo2TiC2Tz, Ti3CNTz, Ta4C3Tz, Ti4N3Tz among many others), where T stands for surface-terminating groups (O, OH, and F). MXenes are mostly produced by selectively etching A layers (where A stands for group A elements, mostly groups 13 and 14) from the MAX phases. The latter are a family of layered ternary carbides and/or nitrides and have a general formula of Mn+1AXn (n = 1-3), where M is a transition metal and X is carbon and/or nitrogen. The produced MXenes have a conductive carbide core and a non-conductive O-, OH- and/or F-terminated surface, which allows them to work as electrodes for energy storage applications, such as Li-ion batteries and supercapacitors. Prior to this work, MXenes were produced in the form of flakes of lateral dimension of about 1 to 2 microns; such dimensions and form are not suitable for electronic characterization and applications. I have synthesized various MXenes (Ti3C2Tz, Ti2CTz and Nb2CTz) as epitaxial thin films, a more suitable form for electronic and photonic applications. These films were produced by HF, NH4HF2 or LiF + HCl etching of magnetron sputtered epitaxial Ti3AlC2, Ti2AlC, and Nb2AlC thin films. For transport properties of the Ti-based MXenes, Ti2CTz and Ti3C2Tz, changing n from 1 to 2 resulted in an increase in conductivity but had no effect on the transport mechanism (i.e. both Ti3C2Tx and Ti2CTx were metallic). In order to examine whether the electronic properties of MXenes differ when going from a few layers to a single flake, similar to graphene, the electrical characterization of a single Ti3C2Tz flake with a lateral size of about 10 μm was performed. These measurements, the first for MXene, demonstrated its metallic nature, along with determining the nature of the charge carriers and their mobility. This indicates that Ti3C2Tz is inherently of 2D nature independent of the number of stacked layers, unlike graphene, where the electronic properties change based on the number of stacked layers. Changing the transition metal from Ti to Nb, viz. comparing Ti2CTz and Nb2CTz thin films, the electronic properties and electronic conduction mechanism differ. Ti2CTz showed metallic-like behavior (resistivity increases with increasing temperature) unlike Nb2CTz where the conduction occurs via variable range hopping mechanism (VRH) - where resistivity decreases with increasing temperature. Furthermore, these studies show the synthesis of pure Mo2CTz in the form of single flakes and freestanding films made by filtering Mo2CTz colloidal suspensions. Electronic characterization of free-standing films made from delaminated Mo2CTz flakes was investigated, showing that a VRH mechanism prevails at low temperatures (7 to ≈ 60 K). Upon vacuum annealing, the room temperature, RT, conductivity of Mo2CTx increased by two orders of magnitude. The conduction mechanism was concluded to be VRH most likely dominated by hopping within each flake. Other Mo-based MXenes, Mo2TiC2Tz and Mo2Ti2C3Tz, showed VRH mechanism at low temperature. However, at higher temperatures up to RT, the transport mechanism was not clearly understood. Therefore, a part of this thesis was dedicated to further investigating the transport properties of Mo-based MXenes. This includes Mo2CTz, out-of-plane ordered Mo2TiC2Tz and Mo2Ti2C3Tz, and vacancy ordered Mo1.33CTz. Magneto-transport of free-standing thin films of the Mo-based MXenes were studied, showing that all Mo-based MXenes have two transport regimes: a VRH mechanism at lower temperatures and a thermally activated process at higher temperatures. All Mo-based MXenes except Mo1.33CTz show that the electrical transport is dominated by inter-flake transfer. As for Mo1.33CTz, the primary electrical transport mechanism is more likely to be intra-flake. The synthesis of vacancy ordered MXenes (Mo1.33CTz and W1.33CTz) raised the question of possible introduction of vacancies in all MXenes. Vacancy ordered MXenes are produced by selective etching of Al and (Sc or Y) atoms from the parent 3D MAX phases, such as (Mo2/3Sc1/3)2AlC, with in-plane chemical ordering of Mo and Sc. However, not all quaternary parent MAX phases form the in-plane chemical ordering of the two M metals; thus the synthesis of the vacancy-ordered MXenes is restricted to a very limited number of MAX phases. I present a new method to obtain MXene flakes with disordered vacancies that may be generalized to all quaternary MAX phases. As proof of concept, I chose Nb-C MXene, as this 2D material has shown promise in several applications, including energy storage, photothermal cell ablation and photocatalysts for hydrogen evolution. Starting from synthetizing (Nb2/3Sc1/3)2AlC quaternary solid solution and etching both the Sc and Al atoms resulted in Nb1.33C material with a large number of vacancies and vacancy clusters. This method may be applicable to other quaternary or higher MAX phases wherein one of the transition metals is more reactive than the other, and it could be of vital importance in applications such as catalysis and energy storage.