Neutral Nickel And Palladium Complexes Of Chelating Anionic N Heterocyclic Carbenes


Neutral Nickel And Palladium Complexes Of Chelating Anionic N Heterocyclic Carbenes
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Neutral Nickel And Palladium Complexes Of Chelating Anionic N Heterocyclic Carbenes


Neutral Nickel And Palladium Complexes Of Chelating Anionic N Heterocyclic Carbenes
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Author : Benjamin E. Ketz
language : en
Publisher:
Release Date : 2005

Neutral Nickel And Palladium Complexes Of Chelating Anionic N Heterocyclic Carbenes written by Benjamin E. Ketz and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2005 with categories.




Neutral Nickel Complexes Of Chelating Anionic N Heterocyclic Carbenes


Neutral Nickel Complexes Of Chelating Anionic N Heterocyclic Carbenes
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Author : Bridgett Ashley Payne
language : en
Publisher:
Release Date : 2006

Neutral Nickel Complexes Of Chelating Anionic N Heterocyclic Carbenes written by Bridgett Ashley Payne and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006 with categories.




Functionalised N Heterocyclic Carbene Complexes


Functionalised N Heterocyclic Carbene Complexes
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Author : Olaf Kühl
language : en
Publisher: John Wiley & Sons
Release Date : 2010-02-02

Functionalised N Heterocyclic Carbene Complexes written by Olaf Kühl and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010-02-02 with Science categories.


N-heterocyclic carbenes (NHCs) have found increasing use as reagents for a range of organic transformations and in asymmetric organocatalysis. The performance of these molecules can be improved and tuned by functionalisation. Functionalised carbenes can anchor free carbenes to the metal site, introduce hemilability, provide a means to immobilise transition metal carbene catalysts, introduce chirality, provide a chelate ligand or bridge two metal centres. NHC can be attached to carbohydrates and campher, derived from amino acids and purines, they can be used as organocatalysts mimicking vitamin B1 or as weak “solvent” donors in lanthanide chemistry. Functionalised N-Heterocyclic Carbene Complexes describes major trends in functionalised NHC ligands, aiming to assist readers in their attempts to develop and apply their own functionalised carbenes. After an introduction to the chemistry and behaviour of NHC, the book gives a detailed description of functionalised carbenes and their complexes according to a range of functional groups, each with a discussion of the synthetic route, structure, stability and performance. Functionalised N-Heterocyclic Carbene Complexes is an essential guide to fine-tuning this important class of compounds for practitioners, researchers and advanced students working in synthetic organometallic and organic chemistry and catalysis.



N Heterocyclic Carbenes In Synthesis


N Heterocyclic Carbenes In Synthesis
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Author : Steven P. Nolan
language : en
Publisher: John Wiley & Sons
Release Date : 2006-10-27

N Heterocyclic Carbenes In Synthesis written by Steven P. Nolan and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-10-27 with Science categories.


This first handbook to focus solely on the application of N-heterocyclic carbenes in synthesis covers metathesis, organocatalysis, oxidation and asymmetric reactions, along with experimental procedures. Written by leading international experts this is a valuable and practical source for every organic chemist.



N Heterocyclic Carbenes In Transition Metal Catalysis


N Heterocyclic Carbenes In Transition Metal Catalysis
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Author : Frank Glorius
language : en
Publisher: Springer
Release Date : 2007-02-05

N Heterocyclic Carbenes In Transition Metal Catalysis written by Frank Glorius and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-02-05 with Science categories.


In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.



The Organometallic Chemistry Of N Heterocyclic Carbenes


The Organometallic Chemistry Of N Heterocyclic Carbenes
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Author : Han Vinh Huynh
language : en
Publisher: John Wiley & Sons
Release Date : 2017-02-03

The Organometallic Chemistry Of N Heterocyclic Carbenes written by Han Vinh Huynh and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-02-03 with Science categories.


The Organometallic Chemistry of N-heterocyclic Carbenes describes various aspects of N-heterocyclic Carbenes (NHCs) and their transition metal complexes at an entry level suitable for advanced undergraduate students and above. The book starts with a historical overview on the quest for carbenes and their complexes. Subsequently, unique properties, reactivities and nomenclature of the four classical NHCs derived from imidazoline, imidazole, benzimidazole and 1,2,4-triazole are elaborated. General and historically relevant synthetic aspects for NHCs, their precursors and complexes are then explained. The book continues with coverage on the preparation and characteristics of selected NHC complexes containing the most common metals in this area, i.e. Ni, Pd, Pt, Ag, Cu, Au, Ru, Rh and Ir. The book concludes with an overview and outlook on the development of various non-classical NHCs beyond the four classical types. Topics covered include: Stabilization, dimerization and decomposition of NHCs Stereoelectronic properties of NHCs and their evaluation Diversity of NHCs Isomers of NHC complexes and their identification NMR spectroscopic signatures of NHC complexes normal, abnormal and mesoionic NHCs The Organometallic Chemistry of N-heterocyclic Carbenes is an essential resource for all students and researchers interested in this increasingly important and popular field of research.



Chemistry Of Iron


Chemistry Of Iron
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Author : J. Silver
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Chemistry Of Iron written by J. Silver and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


This book is designed to be of use to the reader in two different ways. First, it is intended to provide a general introduction to all aspects of iron chemistry for readers from a variety of different scientific backgrounds. It has been written at a level suitable for use by graduates and advanced undergraduates in chemistry and biochemistry, and graduates in physics, geology, materials science, metallurgy and biology. It is not designed to be a dictionary of iron compounds but rather to provide each user with the necessary tools and background to pursue their ,individual interests in the wide areas that are influenced by the chemistry of iron. To achieve this goal each chapter has been written by a contemporary expert active in the subject so that the reader will benefit from their individual insight. Although it is generally assumed that the reader will have an understanding of bonding theories and general chemistry, the book is well referenced so that any deficiencies in the reader's background can be addressed. The book was also designed as a general reference book for initial pointers into a scientific literature that is growing steadily as the understanding and uses of this astonishingly versatile element continue to develop. To meet this aim the book attempts some coverage of all aspects of the chemistry of iron, not only outlining what understanding has been achieved to date but also identifying targets to be aimed at in the future.



The Chemistry Of Pincer Compounds


The Chemistry Of Pincer Compounds
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Author : David Morales-Morales
language : en
Publisher: Elsevier
Release Date : 2011-08-11

The Chemistry Of Pincer Compounds written by David Morales-Morales and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-08-11 with Science categories.


Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties.The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds* Covers the areas in which pincer complexes have had an impact* Includes information on more recent and interesting pincer compounds not just those that are well-known



Organometallic Pincer Chemistry


Organometallic Pincer Chemistry
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Author : Gerard van Koten
language : en
Publisher: Springer
Release Date : 2012-09-17

Organometallic Pincer Chemistry written by Gerard van Koten and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-09-17 with Science categories.


Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and Libor Dostál: The Chemistry of Pincer Complexes of 13 - 15 Main Group Elements.- Kálmán J. Szabo: Pincer Complexes as Catalysts in Organic Chemistry.- Jun-ichi Ito and Hisao Nishiyama: Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multi-potent Catalysts.- Anthony St. John, Karen I. Goldberg, and D. Michael Heinekey: Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.- Dmitri Gelman and Ronit Romm: PC(sp3)P Transition Metal Pincer Complexes: Properties and Catalytic Applications.- Jennifer Hawk and Steve Craig: Physical Applications of Pincer Complexes.



Carbene Chemistry


Carbene Chemistry
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Author : Guy Bertrand
language : en
Publisher: CRC Press
Release Date : 2002-05-14

Carbene Chemistry written by Guy Bertrand and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002-05-14 with Science categories.


Highlights recent discoveries in the development of rapid kinetic techniques that allow for direct visualization and state-of-the-art computational methods.