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Non Equilibrium Phenomena Near Vapor Liquid Interfaces


Non Equilibrium Phenomena Near Vapor Liquid Interfaces
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Non Equilibrium Phenomena Near Vapor Liquid Interfaces


Non Equilibrium Phenomena Near Vapor Liquid Interfaces
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Author : Alexei Kryukov
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-03-28

Non Equilibrium Phenomena Near Vapor Liquid Interfaces written by Alexei Kryukov and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-03-28 with Science categories.


This book presents information on the development of a non-equilibrium approach to the study of heat and mass transfer problems using vapor-liquid interfaces, and demonstrates its application to a broad range of problems. In the process, the following peculiarities become apparent: 1. At vapor condensation on the interface from gas-vapor mixture, non-condensable components can lock up the interface surface and condensation stops completely. 2. At the evolution of vapor film on the heater in superfluid helium (He-II), the boiling mass flux density from the vapor-liquid interface is effectively zero at the macroscopic scale. 3. In problems concerning the motion of He-II bridges inside capillaries filled by vapor, in the presence of axial heat flux the He-II bridge cannot move from the heater as would a traditional liquid, but in the opposite direction instead. Thus the heater attracts the superfluid helium bridge. 4. The shape of liquid-vapor interface at film boiling on the axis-symmetric heaters immersed in liquid greatly depends on heat flux in the interface. Thus a new type of hydrostatic problems appears when in contrast to traditional statements the shape of the liquid-vapor interface has a complex profile with a point of inflection and a smooth exit on a free liquid surface.



Non Equilibrium Phenomena Near Vapor Liquid Interfaces


Non Equilibrium Phenomena Near Vapor Liquid Interfaces
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Author : Alexei Kryukov
language : en
Publisher: Springer
Release Date : 2013-05-04

Non Equilibrium Phenomena Near Vapor Liquid Interfaces written by Alexei Kryukov and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-05-04 with Science categories.


This book presents information on the development of a non-equilibrium approach to the study of heat and mass transfer problems using vapor-liquid interfaces, and demonstrates its application to a broad range of problems. In the process, the following peculiarities become apparent: 1. At vapor condensation on the interface from gas-vapor mixture, non-condensable components can lock up the interface surface and condensation stops completely. 2. At the evolution of vapor film on the heater in superfluid helium (He-II), the boiling mass flux density from the vapor-liquid interface is effectively zero at the macroscopic scale. 3. In problems concerning the motion of He-II bridges inside capillaries filled by vapor, in the presence of axial heat flux the He-II bridge cannot move from the heater as would a traditional liquid, but in the opposite direction instead. Thus the heater attracts the superfluid helium bridge. 4. The shape of liquid-vapor interface at film boiling on the axis-symmetric heaters immersed in liquid greatly depends on heat flux in the interface. Thus a new type of hydrostatic problems appears when in contrast to traditional statements the shape of the liquid-vapor interface has a complex profile with a point of inflection and a smooth exit on a free liquid surface.



Dynamics Of Adsorption At Liquid Interfaces


Dynamics Of Adsorption At Liquid Interfaces
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Author : S.S. Dukhin
language : en
Publisher: Elsevier
Release Date : 1995-04-11

Dynamics Of Adsorption At Liquid Interfaces written by S.S. Dukhin and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1995-04-11 with Technology & Engineering categories.


As the first of its kind, this book provides a valuable introduction for scientists and engineers interested in liquid/fluid interfaces and disperse systems to the rapidly developing area of adsorption dynamics. It is the first extensive review available on the subject of dynamics of adsorption and gives a general summary of the current state of adsorption kinetics theory and experiments. Current progress in recently designed set-ups and improved and generalised known methods for studying interfacial relaxations is reviewed. In addition, the role of the electric charge of surfactants in the adsorption process is discussed in terms of a non-equilibrium distribution of adsorbing ions in the diffuse layer.Present theories of the effect of dynamic adsorption layers on mobile surfaces, such as moving drops and bubbles, based on both diffusion and kinetic controlled adsorption models are described and efficient approximate analytical methods to solve the mathematical problem of coupling surfactant transport and hydrodynamics are introduced. The role of a dynamic adsorption layer in bubble rising, film drainage and film stabilisation and in complex processes such as flotation and microflotation is discussed.Containing more than 1100 references, the book is essential reading for industrial scientists and graduate and post-graduate students in physical, surface and colloid chemistry, physico-chemical hydrodynamics, water purification and mineral processing.



Kinetics Of Evaporation


Kinetics Of Evaporation
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Author : Denis N. Gerasimov
language : en
Publisher: Springer
Release Date : 2018-09-03

Kinetics Of Evaporation written by Denis N. Gerasimov and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-09-03 with Science categories.


This monograph discusses the essential principles of the evaporationprocess by looking at it at the molecular and atomic level. In the first part methods of statistical physics, physical kinetics andnumerical modeling are outlined including the Maxwell’s distributionfunction, the Boltzmann kinetic equation, the Vlasov approach, and theCUDA technique. The distribution functions of evaporating particles are then defined.Experimental results on the evaporation coefficient and the temperaturejump on the evaporation surface are critically reviewed and compared tothe theory and numerical results presented in previous chapters. The book ends with a chapter devoted to evaporation in differentprocesses, such as boiling and cavitation.This monograph addressesgraduate students and researchers working on phase transitions andrelated fields.



Vapor Liquid Interfaces Bubbles And Droplets


Vapor Liquid Interfaces Bubbles And Droplets
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Author : Shigeo Fujikawa
language : en
Publisher: Springer Science & Business Media
Release Date : 2011-04-16

Vapor Liquid Interfaces Bubbles And Droplets written by Shigeo Fujikawa and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-04-16 with Technology & Engineering categories.


Physically correct boundary conditions on vapor-liquid interfaces are essential in order to make an analysis of flows of a liquid including bubbles or of a gas including droplets. Suitable boundary conditions do not exist at the present time. This book is concerned with the kinetic boundary condition for both the plane and curved vapor-liquid interfaces, and the fluid dynamics boundary condition for Navier-Stokes(fluid dynamics) equations. The kinetic boundary condition is formulated on the basis of molecular dynamics simulations and the fluid dynamics boundary condition is derived by a perturbation analysis of Gaussian-BGK Boltzmann equation applicable to polyatomic gases. The fluid dynamics boundary condition is applied to actual flow problems of bubbles in a liquid and droplets in a gas.



Non Equilibrium Phenomena In Confined Soft Matter


Non Equilibrium Phenomena In Confined Soft Matter
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Author : Simone Napolitano
language : en
Publisher: Springer
Release Date : 2015-08-28

Non Equilibrium Phenomena In Confined Soft Matter written by Simone Napolitano and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-08-28 with Science categories.


This book deals with those properties of non-equilibrium soft matter that deviate greatly from the bulk properties as a result of nanoscale confinement.The ultimate physical origin of these confinement effects is not yet fully understood. At the state of the art, the discussion on confinement effects focuses on equilibrium properties, finite size effects and interfacial interactions. However this is a limited vision which does not fully capture the peculiar behaviour of soft matter under confinement and some exotic phenomena that are displayed. This volume will be organized in the following three main themes. Equilibration and physical aging: treating non-equilibrium via the formal methodology of statistical physics in bulk, we analyse physical origin of the non-equilibrium character of thin polymer. We then focus on the impact of nanoconfinement on the equilibration of glasses of soft matter (a process of tremendous technological interest, commonly known as physical aging), comparing the latest trends of polymers in experiments, simulations with those of low-molecular weight glass formers. Irreversible adsorption: the formation of stable adsorbed layers occurs at timescales much larger than the time necessary to equilibrate soft matter in bulk. Recent experimental evidence show a strong correlation between the behaviour of polymers under confinement and the presence of a layer irreversibly adsorbed onto the substrate. This correlation hints at the possibility to tailor the properties of ultrathin films by controlling the adsorption kinetics. The book reports physical aspects of irreversible chain adsorption, such as the dynamics, structure, morphology, and crystallization of adsorbed layers. Glass transition and material properties: this section of the book focuses on the spread of absolute values in materials properties of confined systems, when measured by different experimental and computation techniques and a new method to quantify the effects of confinement in thin films and nanocomposites independently on the investigation procedure will be presented.



Liquid Vapor Phase Change Phenomena


Liquid Vapor Phase Change Phenomena
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Author : Van P. Carey
language : en
Publisher: CRC Press
Release Date : 2007-11-19

Liquid Vapor Phase Change Phenomena written by Van P. Carey and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-11-19 with Science categories.


Liquid-Vapor Phase-Change Phenomena presents the basic thermophysics and transport principles that underlie the mechanisms of condensation and vaporization processes. The text has been thoroughly updated to reflect recent innovations in research and to strengthen the fundamental focus of the first edition. Starting with an integrated presentation of the nonequilibrium thermodynamics and interfacial phenomena associated with vaporization and condensation, coverage follows of the heat transfer and fluid flow mechanisms in such processes. The second edition includes significant new material on the nanoscale and microscale thermophysics of boiling and condensation phenomena and the use of advanced computational tools to create new models of phase-change events. The importance of basic phenomena to a wide variety of applications is emphasized and illustrated throughout using examples and problems. Suitable for senior undergraduate and first-year graduate students in mechanical or chemical engineering, the book can also be a helpful reference for practicing engineers or scientists studying the fundamental physics of nucleation, boiling and condensation.



Current Hydraulic Laboratory Research In The United States


Current Hydraulic Laboratory Research In The United States
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Author :
language : en
Publisher:
Release Date : 1966

Current Hydraulic Laboratory Research In The United States written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1966 with Hydraulic engineering categories.




Report


Report
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Author : United States. National Bureau of Standards
language : en
Publisher:
Release Date : 1966

Report written by United States. National Bureau of Standards and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1966 with Hydraulic engineering categories.




Single Ion Solvation


Single Ion Solvation
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Author : Philippe Hunenberger
language : en
Publisher: Royal Society of Chemistry
Release Date : 2015-10-20

Single Ion Solvation written by Philippe Hunenberger and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-10-20 with Science categories.


Ions are ubiquitous in chemical, technological, ecological and biological processes. Characterizing their role in these processes in the first place requires the evaluation of the thermodynamic parameters associated with the solvation of a given ion. However, due to the constraint of electroneutrality, the involvement of surface effects and the ambiguous connection between microscopic and macroscopic descriptions, the determination of single-ion solvation properties via both experimental and theoretical approaches has turned out to be a very difficult and highly controversial problem. This unique book provides an up-to-date, compact and consistent account of the research field of single-ion solvation thermodynamics that has over one hundred years of history and still remains largely unsolved. By reviewing the various approaches employed to date, establishing the relevant connections between single-ion thermodynamics and electrochemistry, resolving conceptual ambiguities, and giving an exhaustive data compilation (in the context of alkali and halide hydration), this book provides a consistent synthesis, in depth understanding and clarification of a large and sometimes very confusing research field. The book is primarily aimed at researchers (professors, postgraduates, graduates, and industrial researchers) concerned with processes involving ionic solvation properties (these are ubiquitous, eg. in physical/organic/analytical chemistry, electrochemistry, biochemistry, pharmacology, geology, and ecology). Because of the concept definitions and data compilations it contains, it is also a useful reference book to have in a university library. Finally, it may be of general interest to anyone wanting to learn more about ions and solvation. Key features: - discusses both experimental and theoretical approaches, and establishes the connection between them - provides both an account of the past research (covering over one hundred years) and a discussion of current directions (in particular on the theoretical side) - involves a comprehensive reference list of over 2000 citations - employs a very consistent notation (including table of symbols and unambiguous definitions of all introduced quantities) - provides a discussion and clarification of ambiguous concepts (ie. concepts that have not been defined clearly, or have been defined differently by different authors, leading to confusion in past literature) - encompasses an exhaustive data compilation (in the restricted context of alkali and halide hydration), along with recommended values (after critical analysis of this literature data) - is illustrated by a number of synoptic colour figures, that will help the reader to grasp the connections between different concepts in one single picture