Non Equilibrium Thermodynamics Of Heterogeneous Systems

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Non Equilibrium Thermodynamics Of Heterogeneous Systems
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Author : Signe Kjelstrup
language : en
Publisher: World Scientific
Release Date : 2008
Non Equilibrium Thermodynamics Of Heterogeneous Systems written by Signe Kjelstrup and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008 with Technology & Engineering categories.
The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.
Non Equilibrium Thermodynamics Of Heterogeneous Systems Second Edition
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Author : Signe Kjelstrup
language : en
Publisher: World Scientific
Release Date : 2020-08-27
Non Equilibrium Thermodynamics Of Heterogeneous Systems Second Edition written by Signe Kjelstrup and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-08-27 with Science categories.
This book utilizes non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. There are large coupling effects between transport of heat, mass, charge and chemical reactions at surfaces, and it is important to know how one should properly integrate across systems where different phases are in contact. There is no other book available today that gives a prescription of how to set up flux equations for transports across heterogeneous systems.
Experimental Thermodynamics Volume X
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Author : Dick Bedeaux
language : en
Publisher: Royal Society of Chemistry
Release Date : 2015-10-14
Experimental Thermodynamics Volume X written by Dick Bedeaux and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-10-14 with Science categories.
The book covers recent developments in the theory of non-equilibrium thermodynamics and its applications. Four chapters are devoted to the foundations; an overview chapter is followed by recent results addressing the underlying principles of the theory. The applications are concerned with bulk systems, with heterogeneous systems where interfaces are central and with process units in industry where entropy production minimization is useful. There is also a collection of chapters under the heading mesoscopic non-equilibrium thermodynamics, giving in the end an overview of extensions of the theory into the non-linear regime. Bringing the literature up to date and detailing new approaches in this area of research, it is aimed at a predominantly, but not exclusively, academic audience of practitioners of thermodynamics and energy conversion.
Nonequilibrium Thermodynamics
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Author : Yasar Demirel
language : en
Publisher: Newnes
Release Date : 2013-12-16
Nonequilibrium Thermodynamics written by Yasar Demirel and has been published by Newnes this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-12-16 with Technology & Engineering categories.
Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and may lead to self-organized structures, fluctuations, instabilities, and evolutionary systems. Nonequilibrium Thermodynamics, Third Edition emphasizes the unifying role of thermodynamics in analyzing the natural phenomena. This third edition updates and expands on the first and second editions by focusing on the general balance equations for coupled processes of physical, chemical, and biological systems. The new edition contains a new chapter on stochastic approaches to include the statistical thermodynamics, mesoscopic nonequilibrium thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems in thermodynamic analysis. This new addition also comes with more examples and practice problems. - Informs and updates on all the latest developments in the field - Contributions from leading authorities and industry experts - A useful text for seniors and graduate students from diverse engineering and science programs to analyze some nonequilibrium, coupled, evolutionary, stochastic, and dissipative processes - Highlights fundamentals of equilibrium thermodynamics, transport processes and chemical reactions - Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical, and biological systems - Presents a unified analysis for transport and rate processes in various time and space scales - Discusses stochastic approaches in thermodynamic analysis including fluctuation and information theories - Has 198 fully solved examples and 287 practice problems - An Instructor Resource containing the Solution Manual can be obtained from the author: [email protected]
Applied Thermodynamics Of Fluids
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Author : A. R. H. Goodwin
language : en
Publisher: Royal Society of Chemistry
Release Date : 2010
Applied Thermodynamics Of Fluids written by A. R. H. Goodwin and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010 with Science categories.
Published under the auspices of both IUPAC and its affiliated body, the International Association of Chemical Thermodynamics (IACT), this book will serve as a guide to scientists or technicians who use equations of state for fluids. Concentrating on the application of theory, the practical use of each type of equation is discussed and the strengths and weaknesses of each are addressed. It includes material on the equations of state for chemically reacting and non-equilibrium fluids which have undergone significant developments and brings up to date the equations of state for fluids and fluid mixtures. Applied Thermodynamics of Fluids addresses the needs of practitioners within academia, government and industry by assembling an international team of distinguished experts to provide each chapter. The topics presented in the book are important to the energy business, particularly the hydrocarbon economy and the development of new power sources and are also significant for the application of liquid crystals and ionic liquids to commercial products. This reference will be useful for post graduate researchers in the fields of chemical engineering, mechanical engineering, chemistry and physics.
Non Equilibrium Thermodynamics For Engineers Second Edition
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Author : Signe Kjelstrup
language : en
Publisher: World Scientific Publishing Company
Release Date : 2017-02-15
Non Equilibrium Thermodynamics For Engineers Second Edition written by Signe Kjelstrup and has been published by World Scientific Publishing Company this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-02-15 with Technology & Engineering categories.
Kjelstrup, Bedeaux, Johannessen, and Gross describe what non-equilibrium thermodynamics is in a simple and practical way and how it can add to engineering design. They explain how to describe proper equations of transport that are more precise than those used so far, and how to use them to understand the waste of energy resources in central process units in the industry. The authors introduce the entropy balance as an additional equation to use in engineering; to create consistent thermodynamic models, and to systematically minimize energy losses that are connected with the transport of heat, mass, charge and momentum.Non-equilibrium Thermodynamics for Engineers teaches the essence of non-equilibrium thermodynamics and its applications at a level comprehensible to engineering students, practitioner engineers, and scientists working on industrial problems. The book may be used as a textbook in basic engineering curricula or graduate courses.
Extended Irreversible Thermodynamics
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Author : David Jou
language : en
Publisher: Springer Science & Business Media
Release Date : 2010-09-16
Extended Irreversible Thermodynamics written by David Jou and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010-09-16 with Science categories.
The fast progress in many areas of research related to non-equilibrium ther- dynamics has prompted us to write a fourth edition of this book. Like in the previous editions, our main concern is to open the subject to the widest au- ence, including students, teachers, and researchers in physics, chemistry, engine- ing, biology, and materials sciences. Our objective is to present a general view on several open problems arising in non-equilibrium situations, and to afford a wide perspective of applications illustrating their practical outcomes and con- quences. A better comprehension of the foundations is generally correlated to an increase of the range of applications, implying mutual feedback and cross fert- ization. Truly, thermodynamic methods are widely used in many areas of science but, surprisingly, the active dynamism of thermodynamics as a ?eld on its own is not suf?ciently perceived outside a relatively reduced number of specialized researchers. Extended irreversible thermodynamics (EIT) goes beyond the classical f- malisms based on the local equilibrium hypothesis; it was also referred to in an earlier publication by the authors (Lebon et al. 1992) as a thermodynamics of the third type, as it provides a bridge between classical irreversible thermodynamics and rational thermodynamics, enlarging at the same time their respective range of application. The salient feature of the theory is that the ?uxes are incorporated into the set of basic variables.
Introduction To Stochastic Processes And Nonequilibrium Statistical Physics An Revised Edition
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Author : Horacio Sergio Wio
language : en
Publisher: World Scientific Publishing Company
Release Date : 2012-09-05
Introduction To Stochastic Processes And Nonequilibrium Statistical Physics An Revised Edition written by Horacio Sergio Wio and has been published by World Scientific Publishing Company this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-09-05 with Science categories.
This book aims to provide a compact and unified introduction to the most important aspects in the physics of non-equilibrium systems. It first introduces stochastic processes and some modern tools and concepts that have proved their usefulness to deal with non-equilibrium systems from a purely probabilistic angle. The aim is to show the important role played by fluctuations in far-from-equilibrium situations, where noise can promote order and organization, switching among non-equilibrium states, etc. The second part adopts a more historical perspective, retracing the first steps taken from the purely thermodynamic as well as from the kinetic points of view to depart (albeit slightly) from equilibrium. The third part revisits the path outlined in the first one, but now undertakes the mesoscopic description of extended systems, where new phenomena (patterns, long-range correlations, scaling far from equilibrium, etc.) are observed.This book is a revised and extended version of an earlier edition published in 1994. It includes topics of current research interest in far-from-equilibrium situations like noise-induced phenomena and free energy-like functionals, surface growth and roughening, etc. It can be used as an advanced textbook by graduate students in physics. It also covers topics of current interest in other disciplines and interdisciplinary approaches in engineering, biophysics, and economics, among others. The level of detail in the book is enough to capture the interest of the reader and facilitate the path to more learning by exploring the modern research literature provided. At the same time, the book is also complete enough to be self-contained for those readers who just need an overview of the subject.
Multicomponent Interfacial Transport
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Author : Kirill Glavatskiy
language : en
Publisher: Springer Science & Business Media
Release Date : 2011-01-18
Multicomponent Interfacial Transport written by Kirill Glavatskiy and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-01-18 with Science categories.
A thermodynamically consistent description of the transport across interfaces in mixtures has for a long time been an open issue. This research clarifies that the interface between a liquid and a vapor in a mixture is in local equilibrium during evaporation and condensation. It implies that the thermodynamics developed for interfaces by Gibbs can be applied also away from equilibrium, which is typically the case in reality. A description of phase transitions is of great importance for the understanding of both natural and industrial processes. For example, it is relevant for the understanding of the increase of CO2 concentration in the atmosphere, or improvements of efficiency in distillation columns. This excellent work of luminescent scientific novelty has brought this area a significant step forward. The systematic documentation of the approach will facilitate further applications of the theoretical framework to important problems.
Springer Handbook Of Electrochemical Energy
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Author : Cornelia Breitkopf
language : en
Publisher: Springer
Release Date : 2016-12-05
Springer Handbook Of Electrochemical Energy written by Cornelia Breitkopf and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-12-05 with Technology & Engineering categories.
This comprehensive handbook covers all fundamentals of electrochemistry for contemporary applications. It provides a rich presentation of related topics of electrochemistry with a clear focus on energy technologies. It covers all aspects of electrochemistry starting with theoretical concepts and basic laws of thermodynamics, non-equilibrium thermodynamics and multiscale modeling. It further gathers the basic experimental methods such as potentiometry, reference electrodes, ion-sensitive electrodes, voltammetry and amperometry. The contents cover subjects related to mass transport, the electric double layer, ohmic losses and experimentation affecting electrochemical reactions. These aspects of electrochemistry are especially examined in view of specific energy technologies including batteries, polymer electrolyte and biological fuel cells, electrochemical capacitors, electrochemical hydrogen production and photoelectrochemistry. Organized in six parts, the overall complexity of electrochemistry is presented and makes this handbook an authoritative reference and definitive source for advanced students, professionals and scientists particularly interested in industrial and energy applications.