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Organochromium Chemistry With Formally Neutral Chelating Ancillary Ligands


Organochromium Chemistry With Formally Neutral Chelating Ancillary Ligands
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Organochromium Chemistry With Formally Neutral Chelating Ancillary Ligands


Organochromium Chemistry With Formally Neutral Chelating Ancillary Ligands
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Author : Kevin Allen Kreisel
language : en
Publisher: ProQuest
Release Date : 2008

Organochromium Chemistry With Formally Neutral Chelating Ancillary Ligands written by Kevin Allen Kreisel and has been published by ProQuest this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008 with Chelates categories.


This dissertation describes research on chromium complexes with formally neutral, chelating ligands. The goal of this research is the fundamental study of organochromium chemistry with the hope of preparing Cr(II) complexes that are active for the polymerization or oligomerization of ethylene. This would provide evidence for Cr(II) to be active for these processes. Chapter 1 of this dissertation describes the synthesis and characterization of a series of chromium complexes supported by a chelating N-heterocyclic carbene ligand. The second chapter details the preparation and structural characterization of several complexes of chromium supported by several diimine ligands. The third chapter examines the organochromium chemistry derived from the complexes described in chapter 2. The final chapter entails the synthesis of the shortest metal-metal distance ever reported.



Organochromium Compounds


Organochromium Compounds
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Author : R. P. A. Sneeden
language : en
Publisher: Academic Press
Release Date : 1975

Organochromium Compounds written by R. P. A. Sneeden and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1975 with Science categories.


Organochromium Compounds is a three-chapter text that covers the major developments in the preparation, characterization, and reaction of the five main classes of organochromium compounds. These classes include the chromium p and solvated sodium and lithium poly(organo)chromate(III) and (II) complexes, carbenoid-chromium, solvated s-bonded organochromium(III) and (II), solvated sodium and lithium poly(organo)chromate(III) and (II) complexes, and unsolvated s-bonded tetra(organo)chromium(IV) compounds. This book will be of value to organic chemists and researchers who are interested in organotransition metal chemistry.



Modern Carbonyl Olefination


Modern Carbonyl Olefination
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Author : Takeshi Takeda
language : en
Publisher: John Wiley & Sons
Release Date : 2006-03-06

Modern Carbonyl Olefination written by Takeshi Takeda and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-03-06 with Science categories.


While this important reaction class is among the most important and most widely used in organic chemistry, this is the first book to summarize the many different olefination methods, including: * Wittig reaction * Peterson reaction * Julia olefination * Utilizing the Tebbe and related reagents * Low-valent chromium, zinc or titanium mediated olefination * McMurry coupling plus the related reactions in each case and the application to asymmetric synthesis. It thus collates in one ready reference the current level of knowledge as well as new developments in this constantly evolving field -- information which until now has been dispersed throughout the literature.



Isocyanide Based Multicomponent Reactions


Isocyanide Based Multicomponent Reactions
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Author : Jonathan G. Rudick
language : en
Publisher: Frontiers Media SA
Release Date : 2020-02-20

Isocyanide Based Multicomponent Reactions written by Jonathan G. Rudick and has been published by Frontiers Media SA this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-02-20 with categories.


This eBook is a collection of articles from a Frontiers Research Topic. Frontiers Research Topics are very popular trademarks of the Frontiers Journals Series: they are collections of at least ten articles, all centered on a particular subject. With their unique mix of varied contributions from Original Research to Review Articles, Frontiers Research Topics unify the most influential researchers, the latest key findings and historical advances in a hot research area! Find out more on how to host your own Frontiers Research Topic or contribute to one as an author by contacting the Frontiers Editorial Office: frontiersin.org/about/contact.



Machine Learning In Chemistry


Machine Learning In Chemistry
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Author : Jon Paul Janet
language : en
Publisher: American Chemical Society
Release Date : 2020-05-28

Machine Learning In Chemistry written by Jon Paul Janet and has been published by American Chemical Society this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-05-28 with Science categories.


Recent advances in machine learning or artificial intelligence for vision and natural language processing that have enabled the development of new technologies such as personal assistants or self-driving cars have brought machine learning and artificial intelligence to the forefront of popular culture. The accumulation of these algorithmic advances along with the increasing availability of large data sets and readily available high performance computing has played an important role in bringing machine learning applications to such a wide range of disciplines. Given the emphasis in the chemical sciences on the relationship between structure and function, whether in biochemistry or in materials chemistry, adoption of machine learning by chemistsderivations where they are important



Topics In Inorganic And Organometallic Stereochemistry


Topics In Inorganic And Organometallic Stereochemistry
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Author : Gregory L. Geoffroy
language : en
Publisher: John Wiley & Sons
Release Date : 2009-09-17

Topics In Inorganic And Organometallic Stereochemistry written by Gregory L. Geoffroy and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-09-17 with Science categories.


This volume is devoted entirely to inorganic and organometallic stereochemical subjects. Discusses the systematic notations that have been developed to satisfy the needs for a rational and systematic stereochemical nomenclature. Reviews the stereochemical aspects of the changes of bonding at carbon centers induced by metals, either catalytically or stoiciometrically. Also reviews the major achievements in current stereochemical research—the synthesis of asymmetric compounds mediated by transition metals. Discusses the structures of transition metal carbonyl clusters, summarizing recent progress in this expanding area and providing a semiquantitative rationalization of the structures for these clusters.



The Chemistry Of Mycotoxins


The Chemistry Of Mycotoxins
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Author : Stefan Bräse
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-02-14

The Chemistry Of Mycotoxins written by Stefan Bräse and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-02-14 with Science categories.


The biological activity of mycotoxins ranges from weak and/or sometimes positive effects, such as antibacterial activity (see penicillin derivatives derived from Penicillium strains) to strong mutagenic (e. g. aflatoxins, patulin), carcinogenic (e. g. aflatoxins), teratogenic, neurotoxic (e. g. ochratoxins), nephrotoxic (e. g. fumonisins, citrinin), hepatotoxic, and immunotoxic (e. g. ochratoxins, diketopiperazines) activity. Nowadays, many laboratories around the world are specialized in the detection of mycotoxins in food products and contaminated material found in housing. In this volume, a focus on the most important classes of mycotoxins is provided and their chemistry of the last ten years is discussed. In each Section, the individual biological impact is outlined. Sections are arranged according to mycotoxin classes (e. g. aflatoxins) and/or structural classes (e. g. resorcinyl lactones, diketopiperazines). The biology of mycotoxins is also described.



Landmarks In Organo Transition Metal Chemistry


Landmarks In Organo Transition Metal Chemistry
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Author : Helmut Werner
language : en
Publisher: Springer Science & Business Media
Release Date : 2008-12-16

Landmarks In Organo Transition Metal Chemistry written by Helmut Werner and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-12-16 with Science categories.


Since the discovery of ferrocene and the sandwich-type complexes, the development of organometallic chemistry took its course like an avalanche and became one of the scientific success stories of the second half of the twentieth century. Based on this development, the traditional boundaries between inorganic and organic chemistry gradually disappeared and a rebirth of the nowadays highly important field of homogeneous catalysis occurred. It is fair to say that despite the fact that the key discovery, which sparked it all off, was made more than 50 years ago, organometallic chemistry remains a young and lively discipline.



From Coello To Inorganic Chemistry


From Coello To Inorganic Chemistry
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Author : Fred Basolo
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

From Coello To Inorganic Chemistry written by Fred Basolo and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


From boyhood in the coal-mining village of Coello, Illinois, to winning the Priestly Medal and becoming the president of the American Chemical Society, Professor Emeritus Fred Basolo of Northwestern University traces the intertwined development of his life, career, and the field of inorganic chemistry. With over a hundred photographs and dozens of structures and equations, From Coello to Inorganic Chemistry details the major innovations, travels, family life, and guests hosted while helping to build one of the world's leading inorganic chemistry departments from its humble beginnings at Northwestern University. Students and chemists with interests in bioinorganic chemistry, catalysis, nanoscience, new materials research, and organometallics can follow the emergence of inorganic chemistry as a rival to organic chemistry through the accomplishments of one of its most influential pioneers.



The Chemistry Of The Cyclopropyl Group Ny Handling Set Only


The Chemistry Of The Cyclopropyl Group Ny Handling Set Only
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Author : Zvi Rappoport
language : en
Publisher:
Release Date : 1987

The Chemistry Of The Cyclopropyl Group Ny Handling Set Only written by Zvi Rappoport and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1987 with Science categories.


The latest in a series of advanced treatises under the general editorship of Professor Saul Patai providing a comprehensive review of the chemistry of the cyclopropyl group including physical properties, analysis, reaction mechanisms and synthetic uses.