Organophosphorus Reagents In Organic Synthesis
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Organophosphorus Reagents
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Author : Dr. Patrick J. Murphy
language : en
Publisher: Practical Approach in Chemistr
Release Date : 2004
Organophosphorus Reagents written by Dr. Patrick J. Murphy and has been published by Practical Approach in Chemistr this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004 with Science categories.
Organophosphorus Chemistry: A Practical Approach in Chemistry provides a practical introduction to the field by mixing a brief review of the subject area with key experimental details and sample procedures. Phosphorus is an element that has been central to the development of our modern way of life. Its chemistry plays a key role in the development of such important areas as pharmaceuticals, agrochemicals, modern materials and molecular biology. Much of this work requires a sound understanding of the organic chemistry of phosphorus and this volume is designed to instruct the reader in the essential methodology used. Topics covered include phosphines, applications of phosphorus (III) and (V) compounds as reagents in synthesis, the chemistry of phosphorus ylides, applications of the Wittig reaction in the synthesis of heterocyclic and carbocyclic compounds, preparation of Iminophosphoranes and their synthetic applications in the aza-Wittig reaction, phospho-transfer processes leading to [P-C] bond formation, low valent phosphorus compounds and phosphorus methods in oligonucleotide chemistry. It is intended not only for the specialist in organophosphorus chemistry, but also for the organic chemist with little experience in the field who wishes to add phophorus-based techniques to his or her ensemble of synthetic methods.
Organophosphorus Reagents In Organic Synthesis
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Author : John Ivan George Cadogan
language : en
Publisher:
Release Date : 1979
Organophosphorus Reagents In Organic Synthesis written by John Ivan George Cadogan and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1979 with Science categories.
Organophosphorus Chemistry 2018
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Author : György Keglevich
language : en
Publisher: MDPI
Release Date : 2020-03-05
Organophosphorus Chemistry 2018 written by György Keglevich and has been published by MDPI this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-03-05 with Science categories.
Organophosphorus chemistry is an important discipline within organic chemistry. Phosphorus compounds, such as phosphines, trialkyl phosphites, phosphine oxides (chalcogenides), phosphonates, phosphinates and >P(O)H species, etc., may be important starting materials or intermediates in syntheses. Let us mention the Wittig reaction and the related transformations, the Arbuzov- and the Pudovik reactions, the Kabachnik–Fields condensation, the Hirao reaction, the Mitsunobu reaction, etc. Other reactions, e.g., homogeneous catalytic transformations or C-C coupling reactions involve P-ligands in transition metal (Pt, Pd, etc.) complex catalysts. The synthesis of chiral organophosphorus compounds means a continuous challenge. Methods have been elaborated for the resolution of tertiary phosphine oxides and for stereoselective organophosphorus transformations. P-heterocyclic compounds, including aromatic and bridged derivatives, P-functionalized macrocycles, dendrimers and low coordinated P-fragments, are also of interest. An important segment of organophosphorus chemistry is the pool of biologically-active compounds that are searched and used as drugs, or as plant-protecting agents. The natural analogue of P-compounds may also be mentioned. Many new phosphine oxides, phosphinates, phosphonates and phosphoric esters have been described, which may find application on a broad scale. Phase transfer catalysis, ionic liquids and detergents also have connections to phosphorus chemistry. Green chemical aspects of organophosphorus chemistry (e.g., microwave-assisted syntheses, solvent-free accomplishments, optimizations, and atom-efficient syntheses) represent a dynamically developing field. Last, but not least, theoretical approaches and computational chemistry are also a strong sub-discipline within organophosphorus chemistry.
Asymmetric Synthesis In Organophosphorus Chemistry
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Author : Oleg I. Kolodiazhnyi
language : en
Publisher: John Wiley & Sons
Release Date : 2016-12-19
Asymmetric Synthesis In Organophosphorus Chemistry written by Oleg I. Kolodiazhnyi and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-12-19 with Science categories.
Authored by one of the leading experts in the field, this is the only comprehensive overview of chiral organophosphorus compounds, from asymmetric synthesis to catalysis and pharmacological applications. As such, this unique reference covers the chemical background as well as spectroscopical analysis of phosphorus compounds, and thoroughly describes all the various synthetic strategies for these substances. Metal-, organo- and biocatalyzed reactions for the introduction of phosphorus are explained as are asymmetric oxidation and reduction methods for the preparation of all possible oxidation states of phosphorus. The text also includes industrial applications for these compounds. Of particular interest to chemists working in the field of asymmetric synthesis, as well as to the pharmaceutical industry due to the increasing number of phosphorous-containing drugs.
Phosphorus Ylides
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Author : Oleg I. Kolodiazhnyi
language : en
Publisher: John Wiley & Sons
Release Date : 2008-09-26
Phosphorus Ylides written by Oleg I. Kolodiazhnyi and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-09-26 with Science categories.
When Wittig first developed and described phosphorus ylides, nobody could have imagined how useful and versatile this class of compounds could be. This book provides a comprehensive and up-to-date compilation of the chemistry and applications of phosphorus ylides in organic synthesis. The ylides are discussed as reagents in the synthesis of a broad range of substances, amongst them olefins, acetylenes, cyclic and heterocyclic compounds, in such naturally occurring compounds as pheromones, steroids and carotenoids, and pharmaceutically and biologically active compounds such as antibiotics and prostaglandins. A particularly beneficial feature of this book is the 150 key experimental procedures with all the necessary data, allowing the preparation to start immediately without the need for an extremely time-consuming literature search. But should a search prove inevitable, around 2,500 references provide easy access to the primary literature. Every chemist in academia and industry working in organic, bioorganic, inorganic, and medicinal chemistry will welcome this book as an inspiration of concepts, ideas and practical syntheses.
A Guide To Organophosphorus Chemistry
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Author : Louis D. Quin
language : en
Publisher: John Wiley & Sons
Release Date : 2000-02-04
A Guide To Organophosphorus Chemistry written by Louis D. Quin and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-02-04 with Science categories.
Die organische Chemie des Phosphors - ein großes, äußerst lebendiges Forschungsfeld - umfaßt sowohl Verbindungen mit Kohlenstoff-Phosphor-Bindungen als auch organische Ester anorganischer Phosphorsäuren. Dieser Band behandelt die meisten phosphorhaltigen funktionellen Gruppen und daneben aktuelle Fragen wie z.B. ungewöhnliche Koordinationszustände, Heterocyclen, Anwendungen der 31P-NMR und andere spektroskopische Verfahren. Soweit bekannt, werden auch elektronische Reaktionsmechanismen und reaktive Intermediate diskutiert. Mit zahlreichen Literaturhinweisen! (03/00)
Organophosphorus Chemistry
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Author : Viktor Iaroshenko
language : en
Publisher: John Wiley & Sons
Release Date : 2019-01-07
Organophosphorus Chemistry written by Viktor Iaroshenko and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-01-07 with Science categories.
Filling the gap for an up-to-date reference that presents the field of organophosphorus chemistry in a comprehensive and clearly structured way, this one-stop source covers the chemistry, properties, and applications from life science and medicine. Divided into two parts, the first presents the chemistry of various phosphorus-containing compounds and their synthesis, including ylides, acids, and heterocycles. The second part then goes on to look at applications in life science and bioorganic chemistry. Last but not least, such important practical aspects as 31P-NMR and protecting strategies for these compounds are presented. For organic, bioinorganic, and medicinal chemists, as well as those working on organometallics, and for materials scientists. The book, a contributed work, features a team of renowned scientists from around the world whose expertise spans the many aspects of modern organophosphorus chemistry.
Organophosphorus Chemistry
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Author : David W Allen
language : en
Publisher: Royal Society of Chemistry
Release Date : 2020-04-15
Organophosphorus Chemistry written by David W Allen and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-04-15 with Science categories.
This annual review of the literature presents a comprehensive and critical survey of the vast field of study involving organophosphorus compounds, from phosphines and related P-C bonded compounds to phosphorus acids, phosphine chalcogenides and nucleotides. The Editors have added to the content with a timely chapter on the recent developments in green synthetic approaches in organophosphorus chemistry to reflect current interests in the area. With an emphasis on interdisciplinary content, this book is aimed at the worldwide organic chemistry and engineering research communities.
Handbook Of Organophosphorus Chemistry
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Author : Robert Engel
language : en
Publisher: CRC Press
Release Date : 1992-06-19
Handbook Of Organophosphorus Chemistry written by Robert Engel and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992-06-19 with Science categories.
This practical work summarizes the development of organophosphorus chemistry in topical areas and details the discipline's current state - providing applications and experimental procedures throughout.;Written by 18 leading authorities in the field, the Handbook of Organophosphorus Chemistry: examines advances in the mechanistic understanding of th
Organophosphorus Chemistry
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Author : György Keglevich
language : en
Publisher:
Release Date : 2005
Organophosphorus Chemistry written by György Keglevich and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2005 with categories.