Organosulfur Compounds In Transition Metal Mediated Cross Coupling Reactions
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Organosulfur Compounds In Transition Metal Mediated Cross Coupling Reactions
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Author : Daniel Richard Marshall (Jr.)
language : en
Publisher:
Release Date : 1999
Organosulfur Compounds In Transition Metal Mediated Cross Coupling Reactions written by Daniel Richard Marshall (Jr.) and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999 with categories.
Oxidative Cross Coupling Reactions
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Author : Aiwen Lei
language : en
Publisher: John Wiley & Sons
Release Date : 2016-11-14
Oxidative Cross Coupling Reactions written by Aiwen Lei and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-11-14 with Technology & Engineering categories.
The first handbook on this emerging field provides a comprehensive overview of transition metal-catalyzed coupling reactions in the presence of an oxidant. Following an introduction to the general concept and mechanism of this reaction class, the team of authors presents chapters on C-C cross-coupling reactions using organometallic partners, C-Heteroatom bond forming reactions via oxidative couplings, and C-H couplings via C-H activation. The text also covers such groundbreaking topics as recent achievements in the fields of C-C and C-X bond formation reactions as well as C-H activation involving oxidative couplings. With its novel and concise approach towards important building blocks in organic chemistry and its focus on synthetic applications, this handbook is of great interest to all synthetic chemists in academia and industry alike.
Cross Coupling Reactions
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Author : Joffrey Vrijdag
language : en
Publisher: Nova Science Publishers
Release Date : 2020
Cross Coupling Reactions written by Joffrey Vrijdag and has been published by Nova Science Publishers this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020 with Aromatic compounds categories.
"Cross-Coupling Reactions: An Overview opens with an overview of the fundamentals and applications of the young and fast developing area of transition metal catalyzed/mediated oxidative (dehydrogenative) C-H/C-H coupling reactions between two (hetero)arenes. Continuing, the authors highlight the recent advances regarding the ligand supported transition metal-catalyzed domino (cascade) or one-pot syntheses of various heterocycles involving cross-coupling reactions. The recent advances in Cu catalyzed tandem reactions for heterocycle synthesis are also addressed. Cu metal chemistry has garnered attention as a potential alternative to precious transition metals, being cheaper, more sustainable and more easily available. A comprehensive account of research on green chemical routes is provided, involving various palladium metal-based catalysts utilized in facilitating cross-coupling reaction in aqueous media. Reported decarboxylative cross-coupling reactions are discussed along with suitable examples, focusing on their mechanism of action"--
Transition Metal Catalyzed Oxidative Cross Coupling Reactions
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Author : Aiwen Lei
language : en
Publisher:
Release Date : 2019
Transition Metal Catalyzed Oxidative Cross Coupling Reactions written by Aiwen Lei and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019 with SCIENCE categories.
This book is a comprehensive text covering the research and development trends in the booming field of transition metal catalyzed oxidative cross-coupling reactions. Oxidative cross-coupling reaction is a new method to forming chemical bonds besides the traditional cross-coupling reactions. This book provides the answers to how this coupling reaction occurs and what its advantages are. The palladium, copper and iron catalyzed oxidative cross-coupling reactions as the main focuses of interest are described in detail. The oxidative cross-coupling reactions catalyzed by other metals and transition-metal-free oxidative coupling reactions are also introduced.This book provides a useful reference source for researchers and graduates in the field of transition metal catalyzed coupling reactions. It is also valuable to researchers working in pharmaceutical companies, fine organic chemical companies, and etc.
Grignard Reagents And Transition Metal Catalysts
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Author : Janine Cossy
language : en
Publisher: Walter de Gruyter GmbH & Co KG
Release Date : 2016-04-25
Grignard Reagents And Transition Metal Catalysts written by Janine Cossy and has been published by Walter de Gruyter GmbH & Co KG this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-04-25 with Science categories.
In 1912, the Chemistry Nobel Prize was awarded for the discovery of the so-called Grignard reagents. Nowadays, many transition metal variants are developed to modify reactivity and selectivity of the C–C bond formation reaction. The Grignard reaction is one of the fundamental organometallic reactions, often used in alcohol syntheses. With transition metals like iron, cobalt and nickel or with noble metals like copper, silver and palladium, modern Grignard reagents can be designed in reactivity, selectivity and functional group tolerance. This book, written by international experts, presents an overview on timely Grignard chemistry involving transition metals.
Organozinc Derivatives And Transition Metal Catalysts
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Author : Janine Cossy
language : en
Publisher: Walter de Gruyter GmbH & Co KG
Release Date : 2023-05-22
Organozinc Derivatives And Transition Metal Catalysts written by Janine Cossy and has been published by Walter de Gruyter GmbH & Co KG this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-05-22 with Science categories.
Organozinc reagents are less reactive than Grignard reagents but they are much more chemoselective. Since the Negishi cross-coupling reaction developed by Ei-ichi Negishi, who was awarded the Nobel Price in chemistry in 2010, a number of cross-coupling reactions involving organozinc derivatives and transition metal catalysts (Pd, Ni, Fe, Co, Cu, ...) has been tuned up to form C-C bonds. This book on "Organozinc derivatives and transition metal catalysts" has been written by experts in the field and is a complement to the book entitled "Grignard reagents and transition metal catalysts" (a De Gruyter book, edited by J. Cossy). Grignard reagents or organozinc reagents, that is the question? From a given substrate, what is the best organometallic reagent and the best transition metal to form a C-C bond by using a cross-coupling reaction? The solution might be found in these two books.
Homogeneous Catalysis For Unreactive Bond Activation
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Author : Zhang-Jie Shi
language : en
Publisher: John Wiley & Sons
Release Date : 2014-10-17
Homogeneous Catalysis For Unreactive Bond Activation written by Zhang-Jie Shi and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-10-17 with Science categories.
This book offers a comprehensive overview of different catalytic reactions applied to the activation of chemical bonds. Each of the seven chapters covers key C-X classes where carbon is combined with another element: chlorine, fluorine, nitrogen, sulfur, oxygen, hydrogen, and carbon. The first part of the book discusses homogeneous catalysis in the activation and transformation of C-Cl and C-F, highlighting their basic activation modes, cross-coupling, and intensive mechanisms. The second part of the book focuses on C-N, C-S, and C-O bonds, mentioning their catalytic pathways. Finally, C-H and C-C bonds, their activation, chemical transformations, and applicability are covered. Overall, the book presents methodologies that can be applied to the efficient synthesis of drug molecules and fine chemicals. Through their presentation, the authors show that synthetic chemistry can be done in greener ways that limit hazards and pollution.
Transition Metal Catalyzed Cross Coupling Reactions
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Author : Ioannis D Kostas
language : en
Publisher: Mdpi AG
Release Date : 2021-12-23
Transition Metal Catalyzed Cross Coupling Reactions written by Ioannis D Kostas and has been published by Mdpi AG this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-12-23 with Science categories.
Transition metal-catalyzed cross-coupling reactions have proved to be powerful tools for carbon-carbon as well as carbon-heteroatom bond formation in the development of synthetic methodologies for applications ranging from pharmaceuticals to materials. This book, consisting of an editorial, two reviews and two articles, focuses on recent promising research and novel trends in the field of cross-coupling reactions, employing a range of different catalysts. A review by Kostas and Steele provides a survey of the research in the area of cross-coupling catalytic reactions with transition metal complexes based on the thiosemicarbazone unit and a discussion of the prospects for future developments. Another review by Polychronopoulou, Shaya and co-authors describes the progress made over the 21st century concerning the utilization of C(sp3)-organoboranes as partners in metal-catalyzed C(sp3)-C(sp2) cross-couplings, such as B-alkyl Suzuki-Miyaura reactions. The article by Waldvogel, Breinbauer and co-authors demonstrates for the first time the synthetic potential of combining the electro-oxidative dehydrogenative cross coupling of ortho-substituted phenols with Pd-catalyzed cross-coupling reactions. In the second article, Stĕpnička and co-workers describe the preparation of palladium catalysts deposited over silica gel-bearing composite amide-donor functional moieties on the surface, which were evaluated in the Sonogashira-type cross-coupling of acyl chlorides with terminal alkynes.
Transition Metal Catalysed Reactions
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Author : International Union of Pure and Applied Chemistry
language : en
Publisher:
Release Date : 1999
Transition Metal Catalysed Reactions written by International Union of Pure and Applied Chemistry and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999 with Science categories.
Activation Of Grignard Reagents By Transition Metal Compounds
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Author : Hugh Felkin
language : en
Publisher: Elsevier Science & Technology
Release Date : 1976
Activation Of Grignard Reagents By Transition Metal Compounds written by Hugh Felkin and has been published by Elsevier Science & Technology this book supported file pdf, txt, epub, kindle and other format this book has been release on 1976 with Science categories.