Oxidation Of Primary Alcohols To Carboxylic Acids
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Oxidation Of Primary Alcohols To Carboxylic Acids
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Author : Gabriel Tojo
language : en
Publisher: Springer Science & Business Media
Release Date : 2007-05-31
Oxidation Of Primary Alcohols To Carboxylic Acids written by Gabriel Tojo and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-05-31 with Science categories.
As the second volume in a comprehensive encyclopedia of organic reactions, this work provides an elaborated description of the experimental methods used for the oxidation of alcohols to acids. It supplies important data on possible interferences from protecting groups and functional groups, as well as on potential side-reactions. This book is a must for anyone involved in the preparation of organic compounds.
Oxidation Of Alcohols To Aldehydes And Ketones
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Author : Gabriel Tojo
language : en
Publisher: Springer Science & Business Media
Release Date : 2006-06-15
Oxidation Of Alcohols To Aldehydes And Ketones written by Gabriel Tojo and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-06-15 with Science categories.
The aim of this book is to help people performing routine operations in Organic Synthesis in a laboratory. This book, the first one in a series, focuses on the oxidation of alcohols to aldehydes and ketones. Probably, this is the most important routine operation in Organic Synthesis.
Liquid Phase Aerobic Oxidation Catalysis
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Author : Shannon S. Stahl
language : en
Publisher: John Wiley & Sons
Release Date : 2016-07-13
Liquid Phase Aerobic Oxidation Catalysis written by Shannon S. Stahl and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-07-13 with Technology & Engineering categories.
The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.
Understanding Advanced Organic And Analytical Chemistry The Learner S Approach Revised Edition
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Author : Kim Seng Chan
language : en
Publisher: World Scientific Publishing Company
Release Date : 2016-09-29
Understanding Advanced Organic And Analytical Chemistry The Learner S Approach Revised Edition written by Kim Seng Chan and has been published by World Scientific Publishing Company this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-09-29 with Science categories.
This revised edition has been updated to meet the minimum requirements of the new Singapore GCE A level syllabus that would be implemented in the year 2016. Nevertheless, this book is also highly relevant to students who are studying chemistry for other examination boards. In addition, the authors have also included more Q&A to help students better understand and appreciate the chemical concepts that they are mastering.
Studies Of Heterogenous Palladium And Related Catalysts For Aerobic Oxidation Of Primary Alcohols
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Author : Maaz S. Ahmed
language : en
Publisher:
Release Date : 2017
Studies Of Heterogenous Palladium And Related Catalysts For Aerobic Oxidation Of Primary Alcohols written by Maaz S. Ahmed and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017 with categories.
Development of aerobic oxidation methods is of critical importance for the advancement of green chemistry, where the only byproduct produced is water. Recent work by our lab has produced an efficient Pd based heterogenous catalyst capable of preforming the aerobic oxidation of a wide spectrum of alcohols to either carboxylic acid or methyl ester. The well-defined catalyst PdBi0.35Te0.23/C (PBT/C) catalyst has been shown to can perform the aerobic oxidation of alcohols to carboxylic acids in basic conditions. Additionally, we explored this catalyst for a wide range of alcohols and probed the nature of the selectivity of PBT/C for methyl esterification over other side products. Finally, means by which the catalyst operates with respect to oxidation states of the three components, Pd, Bi, and Te, was probed. Carboxylic acids are an important functional group due to their prevalence in various pharmaceutically active agents, agrochemicals, and commodity scale chemicals. The well-defined catalyst PBT/C catalyst was discovered to be effective for the oxidation of a wide spectrum of alcohols to carboxylic acid. The demonstrated substrate scope and functional group tolerance are the widest reported for an aerobic heterogeneous catalyst. Additionally, the catalyst has been implemented in a packed bed reactor with quantitative yield of benzoic acid maintained throughout a two-day run. Biomass derived 5-(hydroxymethyl)furfural (HMF) is also oxidized to 2,5-furandicarboxylic acid (FDCA) in high yield. Exploration of PBT/C for the oxidative methyl esterification was found to exhibit exquisite selectivity for the initial oxidation of primary alcohol instead of methanol, which is the bulk solvent. We explored this selectivity and conclude that it results from various substrate-surface interactions, which are not attainable by methanol. The primary alcohol can outcompete the methanol for binding on the catalyst surface through various interactions between the side chain of the alcohol solvent and the surface of the catalyst: (listed in order of strength) lone pair-surface (heterocyclic primary alcohols)> [pi]-surface (aryl primary alcohols)> van der Waals-surface (alkyl primary alcohols). These interactions were previously underappreciated in condensed phase heterogeneously catalyzed aerobic oxidations. Bi and Te serve as synergistic promoters that enhance both the rate and yield of the reactions relative to reactions employing Pd alone or Pd in combination with Bi or with Te as the sole promoter. We report X-ray absorption spectroscopic studies of the heterogenous catalyst. These methods show that the promoters undergo oxidation in preference to Pd, maintaining the Pd surface in the active metallic state and preventing inhibition by surface Pd-oxide formation. The data also suggest formation of a Pd-Te alloy phase that modifies the electronic properties of the Pd catalyst. Collectively, these results provide valuable insights into the synergistic benefits of multiple promoters in heterogeneous catalytic oxidation reactions.
Methods For Oxidation Of Organic Compounds V2
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Author : Alan Haines
language : en
Publisher: Elsevier
Release Date : 2012-12-02
Methods For Oxidation Of Organic Compounds V2 written by Alan Haines and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
Methods for the Oxidation of Organic Compounds: Alcohols, Alcohol Derivatives, Alkyl Halides, Nitroalkanes, Alkyl Azides, Carbonyl Compounds, Hydroxyarenes and Aminoarenes describes the different methods used for the controlled oxidation of alcohols, alcohol derivatives, alkyl halides, nitroalkanes, alkyl azides, carbonyl compounds, hydroxyarenes, and aminoarenes. Most of the oxidative techniques considered are illustrated with detailed experimental procedures taken from the literature. This book is comprised of eight chapters and begins with a discussion on the oxidation of alcohols, with particular emphasis on the formation of carbonyl compounds and carboxylic acids. The following chapters focus on the oxidation of esters and alkyl halides; ethers, acetals, and metal derivatives of alcohols; amines, nitro compounds, and azides; carbonyl compounds; 1,2-diols and related compounds; and hydroxyarenes, aminoarenes, dihydroxyarenes, diaminoarenes, and aminohydroxyarenes. Methods such as catalytic oxidation, catalytic dehydrogenation, and electrochemical and biochemical oxidation are mentioned. This monograph should be of interest to organic chemists and research students.
Modern Oxidation Methods
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Author : Jan-Erling Bäckvall
language : en
Publisher: John Wiley & Sons
Release Date : 2006-03-06
Modern Oxidation Methods written by Jan-Erling Bäckvall and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-03-06 with Science categories.
At the very latest, with the award of the 2001 Nobel Prize for work on asymmetric oxidation, there has been a need for a comprehensive book on such methods. Edited by J.-E. Backvall, one of the world's leaders in the field, this book fills that gap by covering the topic, from classical to green chemistry methods. He has put together a plethora of well-established authors from all over the world who cover every important aspect in high-quality contributions -- whether aerobic oxidation or transition metal-catalyzed epoxidation of alkenes. By providing an overview of this huge topic, this book represents an unparalleled aid for any chemist working in the field. Chapters include: Recent Developments in the Osmium-Catalyzed Dihydroxylation of Olefins Transition Metal-Catalyzed Epoxidation of Alkenes Organocatalytic Oxidation - Ketone-Catalyzed Asymmetric Epoxidation of Olefins Modern Oxidation of Alcohols using environmentally Benign Oxidants Aerobic Oxidations and Related Reactions Catalyzed by N-Hydroxyphthalimide Ruthenium-Catalyzed Oxidation of Alkenes, Alcohols, Amines, Amides, b-Lactams, Phenols, and Hydrocarbons Selective Oxidations of Sulfides and Amines Liquid Phase Oxidation Reactions Catalyzed by Polyoxometalates Oxidation of Carbonyl Compounds Mn-catalysed Oxidation with Hydrogen Peroxide
Iron Catalysis
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Author : Bernd Plietker
language : en
Publisher: Springer Science & Business Media
Release Date : 2011-01-05
Iron Catalysis written by Bernd Plietker and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-01-05 with Science categories.
Juan I. Padrón and Víctor S. Martín: Catalysis by means of Fe-based Lewis acids; Hiroshi Nakazawa*, Masumi Itazaki: Fe–H Complexes in Catalysis; Kristin Schröder, Kathrin Junge, Bianca Bitterlich, and Matthias Beller: Fe-catalyzed Oxidation Reactions of Olefins, Alkanes and Alcohols: Involvement of Oxo- and Peroxo Complexes; Chi-Ming Che, Cong-Ying Zhou, Ella Lai-Ming Wong: Catalysis by Fe=X Complexes (X=NR, CR2); René Peters, Daniel F. Fischer and Sascha Jautze: Ferrocene and Half Sandwich Complexes as Catalysts with Iron Participation; Markus Jegelka, Bernd Plietker: Catalysis by Means of Complex Ferrates.
Catalysis From A To Z
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Author : Boy Cornils
language : en
Publisher: John Wiley & Sons
Release Date : 2020-01-13
Catalysis From A To Z written by Boy Cornils and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-01-13 with Technology & Engineering categories.
Provides a complete and accessible A to Z collection of information on catalysis This updated and enlarged must-have edition of a classic book on catalysis explains the important terms of all aspects of the subject - including biocatalysis, homogeneous catalysis, heterogeneous catalysis - as well as the terms associated with it. It also looks at related topics like spectroscopy or analytical methods. Featuring 20% more content than the previous edition, it comprehensively covers the topic in a clear and concise manner, and includes abbreviations, brief biographic entries of important scientists who have worked in catalysis, trade names, important catalytic processes, named reactions, reactions, and other important keywords in the general field of catalysis. Written by more than 200 top scientists and with more than 15,000 entries on all aspects of catalysis, Catalysis from A to Z: A Concise Encyclopedia, 5th Edition is filled with figures, tables, cross-references, and references. It covers acids, ligands, catalytic reactions in organic synthesis, kinetics and thermodynamics of catalytic reactions, and catalyst labeling. The book also looks at theoretical backgrounds of catalytic reactions, industrial catalytic processes, autoclaves, colloids, nanomaterials, spectroscopically methods for catalyst analysis, and more. Provides all the knowledge scientists need to know about homogeneous, heterogeneous, and biochemical catalysis Includes more than 15,000 keywords in compact entries Newly updated and expanded edition of the bestselling classic Comprehensive, succinct, and easy to use Edited by an experienced team of top editors and authors with contributions from over 200 scientific experts Offers German and French translations of the keywords to help students and non-native English speakers Catalysis from A to Z: A Concise Encyclopedia is an ideal resource for every student, chemist, scientist, and engineer involved in catalytic chemistry, chemical engineering, biochemistry, organic chemistry, and more.
Methods For The Oxidation Of Organic Compounds
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Author : Alan H. Haines
language : en
Publisher:
Release Date : 1988
Methods For The Oxidation Of Organic Compounds written by Alan H. Haines and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with Science categories.
Methods for Oxidation of Organic Compounds V2 ...