Oxygen The Key To Stereoelectronic Control In Chemistry
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Oxygen The Key To Stereoelectronic Control In Chemistry
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Author : Igor Alabugin
language : en
Publisher: American Chemical Society
Release Date : 2023-05-25
Oxygen The Key To Stereoelectronic Control In Chemistry written by Igor Alabugin and has been published by American Chemical Society this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-05-25 with Science categories.
Although carbon is considered the central element of organic chemistry, the broader chemical world has one more star player—oxygen. Billions of years of evolution have filled your room with oxygen as countless cyanobacteria and plants work on changing our planet. Oxygen is everywhere—from geology to biology, from the Earth's crust to the ozone layer. This digital primer aims to analyze chemical reactivity through the prism of oxygen chemistry. The key to understanding this chemistry is the lone pairs of oxygen (i.e., the underutilized "idle" electrons that do not directly contribute to the Lewis structure of molecules). By highlighting the many roles of oxygen, we will illustrate how chemistry rises above the limitations of Lewis structures and how electrons stay neither idle nor "lone" even if they are in "lone pairs" when an oxygen atom is near a reaction center. This digital primer will introduce important types of chemical bonding that transcend undergraduate textbooks but that are likely to drive the development of new chemical reactions in the future.
The Anomeric Effect And Related Stereoelectronic Effects At Oxygen
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Author : A. J. Kirby
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
The Anomeric Effect And Related Stereoelectronic Effects At Oxygen written by A. J. Kirby and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Stereoelectronic Effects In Organic Chemistry
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Author : Pierre Deslongchamps
language : en
Publisher: Pergamon
Release Date : 1983
Stereoelectronic Effects In Organic Chemistry written by Pierre Deslongchamps and has been published by Pergamon this book supported file pdf, txt, epub, kindle and other format this book has been release on 1983 with Science categories.
Steric And Stereoelectronic Effects In Organic Chemistry
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Author : Veejendra K. Yadav
language : en
Publisher: Springer Nature
Release Date : 2021-07-01
Steric And Stereoelectronic Effects In Organic Chemistry written by Veejendra K. Yadav and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-07-01 with Science categories.
In this second edition, the author has thoroughly updated each chapter and expanded the content with addition of three new chapters. This book comments on several key aspects of stereochemical control of organic reactions in measured detail to allow the reader easily grasp these concepts. In addition, emphasis is given to key information and important aspects of steric and stereoelectronic effects and their control on conformational profile and reactivity features. This book is not only an indispensable resource for advanced undergraduate and graduate students studying the stereochemical aspects of organic reactions, but also a good reference book for all organic chemists in both industry and academia.
Stereoelectronic Effects
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Author : Igor V. Alabugin
language : en
Publisher: John Wiley & Sons
Release Date : 2016-08-23
Stereoelectronic Effects written by Igor V. Alabugin and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-08-23 with Science categories.
Stereoelectronic Effects illustrates the utility of stereoelectronic concepts using structure and reactivity of organic molecules An advanced textbook that provides an up-to-date overview of the field, starting from the fundamental principles Presents a large selection of modern examples of stereoelectronic effects in organic reactivity Shows practical applications of stereoelectronic effects in asymmetric catalysis, photochemical processes, bioorganic chemistry and biochemistry, inorganic and organometallic reactivity, supramolecular chemistry and materials science
Steric And Stereoelectronic Effects In Organic Chemistry
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Author : Veejendra K. Yadav
language : en
Publisher: Springer
Release Date : 2016-06-06
Steric And Stereoelectronic Effects In Organic Chemistry written by Veejendra K. Yadav and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-06-06 with Science categories.
The steric and stereoelectronic effects control the rate and stereochemical outcome of reactions. Hence, a decent understanding of the related concepts is essential for successful synthetic planning. The book attempts to address several important issues related to these concepts in a simplified manner, and is intended for graduate students. It lays stress on the important aspects of steric and stereoelectronic effects and their control on the conformational profile and reactivity features. The book covers the geometrical requirements for reactions at saturated and unsaturated carbons in both cyclic and acyclic systems, and the resultant stereochemical features. The aspect of geometrical flexibility is also covered with a few examples involving intramolecular reactions. It deals with the facial selectivity of nucleophilic additions to acyclic and cyclic carbonyl compounds, and explains how the steric and stereoelectronic effects control the same. The work comments on allylic strains and their stereochemical control on different reactions with the related conformational control. It is a must read to understand the control elements, the prominent among these elements are spiro-conjugation, periselectivity, torquoselectivity, a-effect, Hammett’s substituent constants, Hammond postulate, and Curtin-Hammett principle.
Bioorganic Chemistry
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Author : Hermann Dugas
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Bioorganic Chemistry written by Hermann Dugas and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
This widely-praised textbook is particularly suited for advanced undergraduates or graduates in chemistry, biochemistry, medicinal chemistry, and pharmacology. The third edition has been substantially revised to reflect new research in the field, and features a major new chapter on self-assembly, auto-organization, and molecular devices. The outstanding figures remain a highlight of the book, and were described in an earlier edition as "the best I've seen for showing the organic chemistry of biomolecules." (Quart. Rev. Biol.)
Current Organic Chemistry
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Author :
language : en
Publisher:
Release Date : 1998-05
Current Organic Chemistry written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998-05 with categories.
Synthesis And Applications In Chemistry And Materials In 4 Volumes
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Author : Armando J L Pombeiro
language : en
Publisher: World Scientific
Release Date : 2024-01-16
Synthesis And Applications In Chemistry And Materials In 4 Volumes written by Armando J L Pombeiro and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-01-16 with Science categories.
Chemistry and Material Sciences naturally depend greatly on Synthesis as the initial stage for the existence of compounds and materials with desired behaviors, within the overall streamline of Design/Synthesis — Properties — Application/Function, and their relations. Such a general approach is of a too wide scope to be properly treated in a single set of publications, but this one on 'Synthesis and Applications in Chemistry and Materials' restricts itself by aiming to show the strength and international character of the current research in synthetic chemistry that is being developed in Portugal or abroad by teams that cooperate with this country. Hence, it gathers representative contributions of main Portuguese research groups and foreign collaborating ones. Nevertheless, the topic should be understood in a wide sense, being open to types of studies with significance on sustainable synthesis and applications in chemistry, materials and/or related sciences.
Stereoelectronic Effects
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Author : Igor V. Alabugin
language : en
Publisher: John Wiley & Sons
Release Date : 2016-10-17
Stereoelectronic Effects written by Igor V. Alabugin and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-10-17 with Science categories.
Stereoelectronic Effects illustrates the utility of stereoelectronic concepts using structure and reactivity of organic molecules An advanced textbook that provides an up-to-date overview of the field, starting from the fundamental principles Presents a large selection of modern examples of stereoelectronic effects in organic reactivity Shows practical applications of stereoelectronic effects in asymmetric catalysis, photochemical processes, bioorganic chemistry and biochemistry, inorganic and organometallic reactivity, supramolecular chemistry and materials science