Photofunctionalization Of Molecular Switch Based On Pyrimidine Ring Rotation In Copper Complexes

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Photofunctionalization Of Molecular Switch Based On Pyrimidine Ring Rotation In Copper Complexes
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Author : Michihiro Nishikawa
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-12-16
Photofunctionalization Of Molecular Switch Based On Pyrimidine Ring Rotation In Copper Complexes written by Michihiro Nishikawa and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-12-16 with Science categories.
This book provides a detailed description of photofunctionalization of molecular switch based on pyrimidine ring rotational isomerization in copper complexes bearing two bidentate ligands. The most important features of this work focus on the properties associated with the rotational isomerization based on the two possible coordination geometries at the copper center derived from two nitrogen atoms on the unsymmetrically substituted pyrimidine ring. The functions of systems such as dual emission and redox potential switching based on photo-driven rotation will be of particular interest to readers. Both the functions and the procedures for proving these phenomena are beneficial for the development of more functionalized systems based on material science, molecular science, nanoscience, nanotechnology, electrochemistry, photochemistry, coordination chemistry, physical chemistry, and related disciplines. The finding elucidated here holds promise for handling the photoprocesses of metal complexes, valid for both applications and novel properties. This system is expected make it possible to extract an electrochemical potential response from molecular switches, aiming to simulate the five senses of human beings at a single molecular level.