Physics And Chemistry Of Finite Systems From Clusters To Crystals

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Physics And Chemistry Of Finite Systems From Clusters To Crystals
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Author : Peru Jena
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-11-11
Physics And Chemistry Of Finite Systems From Clusters To Crystals written by Peru Jena and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-11 with Science categories.
Recent innovations in experimental techniques such as molecular and cluster beam epitaxy, supersonic jet expansion, matrix isolation and chemical synthesis are increasingly enabling researchers to produce materials by design and with atomic dimension. These materials constrained by sire, shape, and symmetry range from clusters containing as few as two atoms to nanoscale materials consisting of thousands of atoms. They possess unique structuraI, electronic, magnetic and optical properties that depend strongly on their size and geometry. The availability of these materials raises many fundamental questions as weIl as technological possibilities. From the academic viewpoint, the most pertinent question concerns the evolution of the atomic and electronic structure of the system as it grows from micro clusters to crystals. At what stage, for example, does the cluster look as if it is a fragment of the corresponding crystal. How do electrons forming bonds in micro-clusters transform to bands in solids? How do the size dependent properties change from discrete quantum conditions, as in clusters, to boundary constrained bulk conditions, as in nanoscale materials, to bulk conditions insensitive to boundaries? How do the criteria of classification have to be changed as one goes from one size domain to another? Potential for high technological applications also seem to be endless. Clusters of otherwise non-magnetic materials exhibit magnetic behavior when constrained by size, shape, and dimension. NanoscaIe metal particles exhibit non-linear opticaI properties and increased mechanical strength. SimiIarly, materials made from nanoscale ceramic particIes possess plastic behavior.
Cluster Assembled Materials
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Author : Klaus Sattler
language : en
Publisher: CRC Press
Release Date : 1996
Cluster Assembled Materials written by Klaus Sattler and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996 with Technology & Engineering categories.
It is now some 15 years since atomic clusters were first produced and investigated in laboratories. Since then, knowledge concerning clusters has enjoyed rapid and sustained growth, and cluster research has become a new branch of science.
Dynamics Of Nonlinear And Disordered Systems
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Author : Gustavo Mart¡nez-Mekler
language : en
Publisher: World Scientific
Release Date : 1995
Dynamics Of Nonlinear And Disordered Systems written by Gustavo Mart¡nez-Mekler and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 1995 with Science categories.
This book deals with a series of topics on the cutting edge of nonlinear science, striking a balance between theory and experiment. It consists of two innovative introductory presentations on dynamical systems and fluid dynamics and six chapters on advanced research. A nontrivial interrelation between the different topics becomes apparent throughout the book as an indication of the underlying unity and genericity of nonlinear phenomena. There is a continuous emphasis on conceptual issues often introduced via concrete examples. A common feature is that most of the systems under study are extended, nonhomogeneous and far from equilibrium. The book also exhibits an interesting interplay between deterministic and stochastic approaches.
The Synergy Between Dynamics And Reactivity At Clusters And Surfaces
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Author : L.J. Farrugia
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
The Synergy Between Dynamics And Reactivity At Clusters And Surfaces written by L.J. Farrugia and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
The analogy between the chemistry of molecular transition metal clusters and the processes of chemisorption and catalysis at metal surfaces (the Cluster Surface analogy) has for a number of years provided an interplay between experimental and theoretical inorganic and physical chemists. This collaborative approach has born fruit in the use of well defined modes of metal-ligand bonding in discrete molecular clusters, models for metal-ligand binding on surfaces. Some of the key topics discussed in The Synergy between Dynamics and Reactivity at Clusters and Surfaces are: (1) Mechanisms of the fluxional behaviour in clusters in the liquid phase and the connections with diffusion processes on extended surfaces. The role of metal-metal bond breaking in diffusion. (2) Analogies in the structure of chemisorbed species and related ligands on metallic clusters. (3) Analogies between benzene surface chemistry on extended metal surfaces and on metal surfaces in molecular cluster compounds with particular reference to structural distortions. (4) The role of mobile precursors for dissociation of chemisorption on extended metals and on clusters. Are there analogies in the ligand attachment during cluster compound synthesis? (5) The role of defect sites on metal surfaces in catalyzing chemical reactions and the connection to the special bonding properties of sites on metal clusters having lowest metal-metal coordination. (6) The size of metal clusters needed to mimic surface phenomena on bulk metal surfaces. Different sites needed for different phenomena.
Clusters And Nanostructured Materials
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Author : P. Jena
language : en
Publisher: Nova Publishers
Release Date : 1996
Clusters And Nanostructured Materials written by P. Jena and has been published by Nova Publishers this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996 with Science categories.
Clusters & Nanostructured Materials
Clusters And Fullerenes Proceedings Of The Adriatico Research Conference
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Author : V Kumar
language : en
Publisher: World Scientific
Release Date : 1993-02-05
Clusters And Fullerenes Proceedings Of The Adriatico Research Conference written by V Kumar and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 1993-02-05 with Science categories.
In recent years very active research has been going on to understand the physics and chemistry of clusters, an intermediate state of matter between atoms and solids. Great excitement has been added to these efforts with the recent discovery of a new form of carbon, the fullerene and its aggregates, and subsequent observations of superconductivity with alkali doping. This volume critically reviews the recent progress made in the area of clusters and discusses the new problems opened up with the ongoing developments in fullerenes.
Nanoclusters
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Author : Purusottam Jena
language : en
Publisher: Elsevier
Release Date : 2011-02-08
Nanoclusters written by Purusottam Jena and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-02-08 with Science categories.
This comprehensive book on Nanoclusters comprises sixteen authoritative chapters written by leading researchers in the field. It provides insight into topics that are currently at the cutting edge of cluster science, with the main focus on metal and metal compound systems that are of particular interest in materials science, and also on aspects related to biology and medicine. While there are numerous books on clusters, the focus on clusters as a bridge across disciplines sets this book apart from others. Delivers cutting edge coverage of cluster science Covers a broad range of topics in physics, chemistry, and materials science Written by leading researchers in the field
Quasicrystals
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Author : Christian Janot
language : en
Publisher: Oxford University Press, USA
Release Date : 2012-10-18
Quasicrystals written by Christian Janot and has been published by Oxford University Press, USA this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-10-18 with Medical categories.
In 1984 physicists discovered a monster in the world of crystallography, a structure that appeared to contain five-fold symmetry axes, which cannot exist in strictly periodic structures. Such quasi-periodic structures became known as quasicrystals. A previously formulated theory in terms of higher dimensional space groups was applied to them and new alloy phases were prepared which exhibited the properties expected from this model more closely. Thus many of the early controversies were dissolved. In 2011, the Nobel Prize for Chemistry was awarded to Dan Shechtman for the discovery of quasicrystals. This primer provides a descriptive approach to the subject for those coming to it for the first time. The various practical, experimental, and theoretical topics are dealt with in an accessible style. The book is completed by problem sets and there is a computer program that generates a Penrose lattice.
Encyclopedia Of Chemical Physics And Physical Chemistry Applications
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Author : Nicholas D. Spencer
language : en
Publisher: Taylor & Francis
Release Date : 2001
Encyclopedia Of Chemical Physics And Physical Chemistry Applications written by Nicholas D. Spencer and has been published by Taylor & Francis this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001 with Chemistry, Physical and theoretical categories.
Metal Clusters At Surfaces
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Author : Karl-Heinz Meiwes-Broer
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Metal Clusters At Surfaces written by Karl-Heinz Meiwes-Broer and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Numerous experiments and calculations have shown that isolated metal clusters possess many interesting features, quite different from those known from surface and solid- state physics or from atomic and molecular physics. The technological exploitation of these new properties, e.g. in miniature electronic or mechanical components, requires the cluster to be brought into an environment such as an encapsulating matrix or a surface. Due to the interaction with the contact medium, the properties of the clusters may change or even disappear. Thus the physics of cluster-on-surface systems -- the main subject of this book -- is of fundamental importance. The book addresses a wide audience, from the newcomer to the expert. Starting from fundamental concepts of adsorbate-surface interactions, the modification of electronic properties through electron confinement, and concepts of cluster production, it elucidates the distinct properties of the new metallic nanostructures.