Reactions Of Coordinated Ligands
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Reactions Of Coordinated Ligands
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Author : P.S. Braterman
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Reactions Of Coordinated Ligands written by P.S. Braterman and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
This, the second and final volume of Reactions of Coordinated Ligands, describes the chemistry of ligands bound through non-carbon atoms, and of coordinated carbon dioxide. As before, emphasis is on the underlying mechanisms, which provide a unity of understanding for superficially disparate processes. The wide range of topics covered illustrates well both the versatility and the usefulness of coordination chemistry in the controlled activation of ligands. Looking to the future, carbon dioxide is the feedstock of last resort. The homogeneous reduction of dinitrogen to ammonia now seems unlikely to replace the Haber process, but solution reactions also lead to more complex, varied, and valuable products. Nitrogen monoxide, a "non innocent" ligand, impinges as pollutant and reagent. Its rich chemistry stems from its linked roles as three-electron donor, and as extremely powerful -acceptor. In the hydrolysis and condensation of complexed amides, esters etc. , metals act both as templates and as tunable and poly functional Lewis acids. Here the control of hydrophobic and steric interactions begins to model the subtle mechanisms of biological specificity. Finally, phosphorus and sulfur are imporant both as ligand atoms in themselves, and as anchors for other functionalities. I would like to thank all those who have been involved in the writing and production of this work, and also my colleagues old and new, at Glasgow and the University of North Texas, for their support. Paul S. Braterman v CONTENTS 1. Reactions of Coordinated Carbon Dioxide 1 J. D. Miller 1.
Reactions Of Coordinated Ligands
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Author : P.S. Braterman
language : en
Publisher: Springer
Release Date : 1986
Reactions Of Coordinated Ligands written by P.S. Braterman and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1986 with Gardening categories.
This book is aimed at graduate students and research workers in aU branches of ohemistry, who wish to gain insight into what continues'to be one of the fastest growing areas of the subject. Aonding to a metal center may stabilize a ligand towards some reagents, activate it towards others, or modify its chemical behavior in more subtle ways. AU these effects have their uses, and aU invite understanding in terms of mechanism. Thus mechanistic insight is linked to control of reaction pathways. The detailed working out of this relationship provides the central theme of the book. The effect of the metal may be electronic or steric, and may involve the energy or the entropy of activation. It may depend on changes induced in the initial state of the ligand, or on those that only arise further along the reaction pathway. It may involve one coordination site or several, and the effects may be more, or less, specific to the metal involved and more, or less, amenable to control through the other Jigands. These remarks apply equaUy strongly to the carbon-bound ligands which occupy the major part of this work, and to those attached by other atoms. Thus the reactions discussed here are relevant in such diverse areas as bulk homogeneous catalysis, stereoselective stoichiometric synthesis, and bioinorganic chemistry.
Reactions Of Coordinated Ligands
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Author : Paul S. Braterman
language : en
Publisher:
Release Date : 1986
Reactions Of Coordinated Ligands written by Paul S. Braterman and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1986 with Coordination compounds categories.
Metals And Ligand Reactivity
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Author : Edwin C. Constable
language : en
Publisher: Wiley-VCH
Release Date : 1996-01-18
Metals And Ligand Reactivity written by Edwin C. Constable and has been published by Wiley-VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996-01-18 with Science categories.
Edwin C. Constable Metals and Ligand Reactivity An Introduction to the Organic Chemistry of Metal Complexes New, revised and expanded edition This book is a highly readable introduction to the reactions of coordinated ligands, which have become a useful tool in organic synthesis. Bridging the gap between the traditional fields, this text presents the basic concepts of ligand reactivity as well as synthetic applications of these reactions. Topics covered include Principles of metal-ligand interaction Reactions of coordinated ligands with nucleophiles and electrophiles Oxidation and reduction of coordinated ligands Cyclic and encapsulating ligands, template effects and supramolecular chemistry Carefully selected examples, lucidly designed figures and schemes as well as numerous study problems make this book an ideal guide for students and practitioners of organic synthesis. References to further reading are also included.
Reaction Mechanisms Of Metal Complexes
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Author : R W Hay
language : en
Publisher: Elsevier
Release Date : 2000-03-01
Reaction Mechanisms Of Metal Complexes written by R W Hay and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-03-01 with Technology & Engineering categories.
This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. Provides a general background as a course module in the area of inorganic reaction mechanisms, which has important research applications in the metallurgical industry Contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands
Reactions Of Coordinated Ligands And Homogeneous Catalysis
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Author : American Chemical Society. Division of Inorganic Chemistry
language : en
Publisher:
Release Date : 1963
Reactions Of Coordinated Ligands And Homogeneous Catalysis written by American Chemical Society. Division of Inorganic Chemistry and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1963 with Science categories.
Reactions Of Coordinated Ligands And Homogeneous Catalysis
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Author : Daryl Hadley Bush
language : en
Publisher:
Release Date : 1988
Reactions Of Coordinated Ligands And Homogeneous Catalysis written by Daryl Hadley Bush and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with categories.
Comprehensive Coordination Chemistry Ligands
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Author : Geoffrey Wilkinson
language : en
Publisher:
Release Date : 1987
Comprehensive Coordination Chemistry Ligands written by Geoffrey Wilkinson and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1987 with Coordination compounds categories.
Synthetic Coordination Chemistry
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Author : Julian A. Davies
language : en
Publisher: World Scientific
Release Date : 1996
Synthetic Coordination Chemistry written by Julian A. Davies and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996 with Science categories.
Although coordination chemistry naturally centers on the synthesis of coordination compounds, the synthesis of these materials is typically not an end in itself. Coordination compounds are utilized in all branches of chemistry; from theoretical modeling to industrial and consumer products. While a large amount of information is available on coordination chemistry in general and synthetic methods in particular, no comprehensive work has been presented on the preparation of coordination compounds with an emphasis on synthetic strategies rather than on detailed descriptions of specific syntheses. The goal of this book is to provide an approach to coordination chemistry that is based upon preparative strategies.The main aim of the authors is to present a systematic classification of synthetic reactions rather than an encyclopedic listing of experimental results. Hence, the coverage is more selective than exhaustive. Despite this, the book provides access to the original literature with ca. 2000 references. The edition is well-illustrated and contains almost 250 schemes, figures and illustrations of crystal structures of selected complexes.
Reactions Of Coordinated Ligands And Homogeneous Catalysis
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Author : Daryle H. Busch
language : en
Publisher:
Release Date : 1963
Reactions Of Coordinated Ligands And Homogeneous Catalysis written by Daryle H. Busch and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1963 with categories.