Reactivity And Transport Of Heavy Metals In Soils


Reactivity And Transport Of Heavy Metals In Soils
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Reactivity And Transport Of Heavy Metals In Soils


Reactivity And Transport Of Heavy Metals In Soils
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Author : H. Magdi Selim
language : en
Publisher: CRC Press
Release Date : 1996-10-09

Reactivity And Transport Of Heavy Metals In Soils written by H. Magdi Selim and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996-10-09 with Technology & Engineering categories.


The fate of heavy metal particles in the environment is important because they tend to be reactive, mobile, and highly toxic. Reactivity and Transport of Heavy Metals in Soils examines the sometimes complex interactions that occur between metals and the soil they occupy. It discusses basic kinetic concepts and covers the predictability and consequences of metal-soil interactions. This practical guide presents and explains heavy metal issues crucial to hazardous waste site cleanup, including:



Transport Fate Of Chemicals In Soils


Transport Fate Of Chemicals In Soils
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Author : H. Magdi Selim
language : en
Publisher: CRC Press
Release Date : 2014-09-17

Transport Fate Of Chemicals In Soils written by H. Magdi Selim and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-09-17 with Science categories.


During the last four decades, tremendous advances have been made towards the understanding of transport characteristics of contaminants in soils, solutes, and tracers in geological media. Transport & Fate of Chemicals in Soils: Principles & Applications offers a comprehensive treatment of the subject complete with supporting examples of mathematical models that describe contaminants reactivity and transport in soils and aquifers. This approach makes it a practical guide for designing experiments and collecting data that focus on characterizing retention as well as release kinetic reactions in soils and contaminant transport experiments in the laboratory, greenhouse), and in the field. The book provides the basic framework of the principals governing the sorption and transport of chemicalsin soils. It focuses on physical processes such as fractured media, multiregion, multiple porosities, and heterogeneity and effect of scale as well as chemical processes such as nonlinear kinetics, release and desorption hysteresis, multisite and multireaction reactions, and competitive-type reactions. The coverage also includes details of sorption behavior of chemicals with soil matrix surfaces as well the integration of sorption characteristics with mechanisms that govern solute transport in soils. The discussions of applications of the principles of sorption and transport are not restricted to contaminants, but also include nitrogen, phosphorus, and trace elements including essential micronutrients, heavy metals, military explosives, pesticides, and radionuclides. Written in a very clear and easy-to-follow language by a pioneer in soil science, this book details the basic framework of the physical and chemical processes governing the transport of contaminants, trace elements, and heavy metals in soils. Highly practical, it includes laboratory methods, examples, and empirical formulations. The approach taken by the author gives you not only the fundamentals of understanding of reactive chemicals retention and their transport in soils and aquifers, but practical guidance you can put to immediate use in designing experiments and collecting data.



Geochemical And Hydrological Reactivity Of Heavy Metals In Soils


Geochemical And Hydrological Reactivity Of Heavy Metals In Soils
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Author : H. Magdi Selim
language : en
Publisher: CRC Press
Release Date : 2003-03-26

Geochemical And Hydrological Reactivity Of Heavy Metals In Soils written by H. Magdi Selim and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-03-26 with Technology & Engineering categories.


The hydrological and geochemical interactions between clay minerals and organic matter in soils directly influence the reaction, behavior, and mobility of heavy metals in soils. Geochemical and Hydrological Reactivity of Heavy Metals in Soils is one of few books that comprehensively illustrates this cause-and-effect relationship. It highlights anal



Metal Speciation And Contamination Of Soil


Metal Speciation And Contamination Of Soil
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Author : Herbert E. Allen
language : en
Publisher: CRC Press
Release Date : 1994-11-29

Metal Speciation And Contamination Of Soil written by Herbert E. Allen and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994-11-29 with Technology & Engineering categories.


Metal Speciation and Contamination of Soil provides a thorough overview of the biogeochemical processes governing the behavior, transport, and bioavailability of heavy metals in contaminated soils and suggests alternative approaches for effective remediation. This important new book contains contributions from experts in various disciplines who explore the issues from theoretical, experimental, and pragmatic perspectives. Topics include redox chemistry, kinetics of metal reactions, spectroscopic characterization of metal ion reactions at surface, modeling hydrologic transport phenomena and colloid-associated transport of metals through the soil profile to ground water, and remediation alternatives.



Competitive Sorption And Transport Of Heavy Metals In Soils And Geological Media


Competitive Sorption And Transport Of Heavy Metals In Soils And Geological Media
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Author : H. Magdi Selim
language : en
Publisher: CRC Press
Release Date : 2016-04-19

Competitive Sorption And Transport Of Heavy Metals In Soils And Geological Media written by H. Magdi Selim and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-04-19 with Science categories.


Most reported incidents of soil contamination include an array of heavy metals species rather than a single ion. The various interactions in these multicomponent or multiple-ion systems significantly impact the fate and transport of heavy metals, and competition for sorption sites on soil matrix surfaces is a common phenomenon. Because of this, considering competitive sorption is an important part of predicting contaminant transport. Competitive Sorption and Transport of Heavy Metals in Soils and Geological Media gives you the information needed to understand heavy metals’ sorption and transport in the vadose zone and aquifers. The book brings together state-of-the art research on the competitive sorption and mobility of single versus multiple heavy metal species. It also relates the transport mechanisms to the processes that govern sorption mechanisms. The work offers new experimental evidence on the fate of multiple heavy metals in soil columns and new field results on how multiple ions influence the mobility of metals in the soil profile under water-unsaturated flow. Emphasizing modeling approaches, the book begins with an overview of the competitive behavior of heavy metals. It then takes a closer look at various heavy metals, discussing their behavior in tropical soils, speciation and fractionation, accumulation, migration, competitive retention, and the contamination of water resources at the watershed scale. The book also presents extensive data on phosphate, a commonly used fertilizer, and its role in facilitating the release of trace elements. The final chapter looks at the effect of waterlogged conditions on arsenic and cadmium solubilization. Edited by an internationally recognized researcher and featuring expert contributors, this comprehensive work addresses the complex physical and chemical phenomena of sorption mechanisms. Presenting the latest research, it helps you to better predict the potential mobility of multiple heavy metals in soils.



Geochemical And Hydrological Reactivity Of Heavy Metals In Soils


Geochemical And Hydrological Reactivity Of Heavy Metals In Soils
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Author : H. Magdi Selim
language : en
Publisher: CRC Press
Release Date : 2003-03-26

Geochemical And Hydrological Reactivity Of Heavy Metals In Soils written by H. Magdi Selim and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-03-26 with Technology & Engineering categories.


The hydrological and geochemical interactions between clay minerals and organic matter in soils directly influence the reaction, behavior, and mobility of heavy metals in soils. Geochemical and Hydrological Reactivity of Heavy Metals in Soils is one of few books that comprehensively illustrates this cause-and-effect relationship. It highlights anal



Heavy Metals Release In Soils


Heavy Metals Release In Soils
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Author : H. Magdi Selim
language : en
Publisher: CRC Press
Release Date : 2001-06-15

Heavy Metals Release In Soils written by H. Magdi Selim and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001-06-15 with Technology & Engineering categories.


Understanding the mechanisms associated with metal complexes and the sequestering metal contaminants in the environment is essential for effective remediation. Heavy Metal Release in Soils describes and quantifies desorption/release kinetics and dissolution reactions in the release of heavy metals from soil. The book focuses on: New techniques - microscopic surface techniques, NMR and electrophoresis, XAFS, SFM, and time-resolved ATR-FTIR Theoretical analysis and kinetic approaches - adsorption/desorption hysteresis, competitive sorption and transport, multi-component models, speciation kinetics, isotherms and soil and metal parameters, and the role of soil properties on transport Applications - arsenic speciation and mobility in contaminated soils, modeling activity of CD, Zn, and Cu in contaminated soils, and in situ chemical immobilization A timely addition to the literature, this book highlights the desorption/release mechanisms for the purpose of resolving remediation dilemmas in contaminated environments. It gives you the added advantage of case studies at both the microscopic and macroscopic scales, and provides both experimental and numerical investigations. With contributions from an international panel of authors, Heavy Metals Release in Soils fills a gap in the current literature concerned with subsurface contaminant fate and transport processes.



Transport And Fate Of Chemicals In Soils


Transport And Fate Of Chemicals In Soils
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Author : H. Magdi Selim
language : en
Publisher: CRC Press
Release Date : 2017-11-22

Transport And Fate Of Chemicals In Soils written by H. Magdi Selim and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-11-22 with categories.


During the last four decades, tremendous advances have been made towards the understanding of transport characteristics of contaminants in soils, solutes, and tracers in geological media. Transport & Fate of Chemicals in Soils: Principles & Applications offers a comprehensive treatment of the subject complete with supporting examples of mathematical models that describe contaminants reactivity and transport in soils and aquifers. This approach makes it a practical guide for designing experiments and collecting data that focus on characterizing retention as well as release kinetic reactions in soils and contaminant transport experiments in the laboratory, greenhouse), and in the field. The book provides the basic framework of the principals governing the sorption and transport of chemicalsin soils. It focuses on physical processes such as fractured media, multiregion, multiple porosities, and heterogeneity and effect of scale as well as chemical processes such as nonlinear kinetics, release and desorption hysteresis, multisite and multireaction reactions, and competitive-type reactions. The coverage also includes details of sorption behavior of chemicals with soil matrix surfaces as well the integration of sorption characteristics with mechanisms that govern solute transport in soils. The discussions of applications of the principles of sorption and transport are not restricted to contaminants, but also include nitrogen, phosphorus, and trace elements including essential micronutrients, heavy metals, military explosives, pesticides, and radionuclides. Written in a very clear and easy-to-follow language by a pioneer in soil science, this book details the basic framework of the physical and chemical processes governing the transport of contaminants, trace elements, and heavy metals in soils. Highly practical, it includes laboratory methods, examples, and empirical formulations. The approach taken by the author gives you not only the fundamentals of understanding of reactive chemicals retention and their transport in soils and aquifers, but practical guidance you can put to immediate use in designing experiments and collecting data.



Fate And Transport Of Heavy Metals In The Vadose Zone


Fate And Transport Of Heavy Metals In The Vadose Zone
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Author : I.K. Iskandar
language : en
Publisher: CRC Press
Release Date : 1999-04-23

Fate And Transport Of Heavy Metals In The Vadose Zone written by I.K. Iskandar and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999-04-23 with Science categories.


The chapters of this book were originally presented at the Fourth International Conference on the Biogeochemistry of Trace Elements, in June 1997 at Berkeley, California. The results of that symposium are now available to assist both specialists and those concerned with broader environmental issues. The first four chapters of Fate and Transport of Heavy Metals in the Vadose Zone are devoted to sorption-desorption processes. Subjects include the kinetics of trace metal sorption-desorption, adsorption of nickel and their isotherms, cadmium reactions, and retention mechanisms of both linear and nonlinear types. The next three sections describe complexation and speciation processes. The authors consider the effect of humic and fulvic acids, the binding of copper with organic matter, and the rate of dissolved selenium. Chapters eight through eleven scrutinize the bioavailability and retention of heavy metals and their mobility in the vadose zone. Twelve details plant-available concentration levels for heavy metals in the vadose zone. The last section relates case studies that are relevant to environmental affairs. Features



Dynamics And Bioavailability Of Heavy Metals In The Rootzone


Dynamics And Bioavailability Of Heavy Metals In The Rootzone
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Author : H. Magdi Selim
language : en
Publisher: CRC Press
Release Date : 2011-03-15

Dynamics And Bioavailability Of Heavy Metals In The Rootzone written by H. Magdi Selim and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-03-15 with Science categories.


Concerns regarding heavy metal contamination in terrestrial ecosystems have prompted increasing efforts on limiting their bioavailability in the root zone. The complexity of the hydrologic system gives rise to the need for understanding the fate and transport of trace elements in the soil-water-plant environment. Dynamics and Bioavailability of Heavy Metals in the Rootzone provides a multidisciplinary approach with emphasis on geohydrology, plant and soil science, and environmental chemistry. The primary focus of this book is on different approaches that describe the dynamics of heavy metals in the soil system. These approaches are key to providing direct information on the concentration of heavy metals and hence on their transport, toxicity, and bioavailability. The book includes chapters covering equilibrium and kinetic models of heavy metal interactions as well as non-equilibrium transport models. It also discusses chemical processes controlling soil solution concentrations and modeling of heavy metals adsorption. Addressing the biological component of heavy metal dynamics, this work examines rhizosphere microorganisms and phytoremediation. Colloid-associated transport, which can result in groundwater contamination, is discussed in relation to reclaimed mine sites. The authors also present an overview of recent advancements in the biogeochemistry of trace elements and their environmental implications. Additional chapters include examination of various natural environments including runoff waters at the watershed scale, heavy metal transformation in wetlands, dynamics of trace metals in frequently flooded soils, and effects on crops in biosolid-amended soils. Reliable assessment of potential risks resulting from the transport of trace elements in the soil environment requires the examination of complex chemical and biological interactions due to the heterogeneous nature of soils. This text describes the current state of the art in this field and explores innovative experimental and theoretical/modeling approaches that will enhance this knowledge. The book provides a coherent presentation of recent advances in techniques, modeling, and dynamics and bioavailability of heavy metals in the root zone.