Reactivity Of Low Valent Group 14 Species Toward Main Group Element Transition Metal And Lanthanide Compounds
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Reactivity Of Low Valent Group 14 Species Toward Main Group Element Transition Metal And Lanthanide Compounds
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Author : Xiaofei Sun
language : en
Publisher: Cuvillier Verlag
Release Date : 2022-08-22
Reactivity Of Low Valent Group 14 Species Toward Main Group Element Transition Metal And Lanthanide Compounds written by Xiaofei Sun and has been published by Cuvillier Verlag this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-08-22 with Science categories.
Die Dissertation befasst sich mit der Anwendung von niedervalenten Gruppe-14-Verbindungen in metallorganischer Chemie und Hauptgruppenchemie. Ausgehend von mono- und divalenten Siliziumverbindungen wurde die analoge Siliziumverbindung des 2π-Hückel-aromatischen Verbindung dargestellt (Kapitel 3.1). Ein chirales Silen wurde synthetisiert und weitere Reaktivität mit unterschiedlichen kleinen Molekülen untersucht (Kapitel 3.2). Außerdem wurden bidentate Silylene als Liganden zur Stabilisierung von Seldenerdelementen, Erdalkalielementen und Gruppe-12-Metallen eingesetzt (Kapitel 3.3-3.4). Verschiedene Polyphosphide wurden aus reduzierenden Silylenen oder Plumbolen generiert (Kapitel 3.5-3.6). Die dianionischen Gruppe-14-Metallole, Silol, Germol und Plumbol wurden als Liganden für sandwichartige Lanthanidkomplexe eingesetzt und die magnetischen Eigenschaften der Er-Verbindung wurden untersucht (Kapitel 3.7-3.8).
Organosilicon Compounds
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Author : Vladimir Ya Lee
language : en
Publisher: Academic Press
Release Date : 2017-08-22
Organosilicon Compounds written by Vladimir Ya Lee and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-08-22 with Science categories.
Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds’ structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry Covers important breakthroughs in the field, along with the historically significant achievements of the past Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology
Frustrated Lewis Pairs Ii
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Author : Gerhard Erker
language : en
Publisher: Springer
Release Date : 2013-12-12
Frustrated Lewis Pairs Ii written by Gerhard Erker and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-12-12 with Science categories.
Frustrated Lewis Pairs: From Dihydrogen Activation to Asymmetric Catalysis, by Dianjun Chen, Jürgen Klankermayer Coexistence of Lewis Acid and Base Functions: A Generalized View of the Frustrated Lewis Pair Concept with Novel Implications for Reactivity, by Heinz Berke, Yanfeng Jiang, Xianghua Yang, Chunfang Jiang, Subrata Chakraborty, Anne Landwehr New Organoboranes in "Frustrated Lewis Pair" Chemistry, by Zhenpin Lu, Hongyan Ye, Huadong Wang Paracyclophane Derivatives in Frustrated Lewis Pair Chemistry, by Lutz Greb, Jan Paradies Novel Al-Based FLP Systems, by Werner Uhl, Ernst-Ulrich Würthwein N-Heterocyclic Carbenes in FLP Chemistry, by Eugene L. Kolychev, Eileen Theuergarten, Matthias Tamm Carbon-Based Frustrated Lewis Pairs, by Shabana Khan, Manuel Alcarazo Selective C-H Activations Using Frustrated Lewis Pairs. Applications in Organic Synthesis, by Paul Knochel, Konstantin Karaghiosoff, Sophia Manolikakes FLP-Mediated Activations and Reductions of CO2 and CO, by Andrew E. Ashley, Dermot O’Hare Radical Frustrated Lewis Pairs, by Timothy H. Warren and Gerhard Erker Polymerization by Classical and Frustrated Lewis Pairs, by Eugene Y.-X. Chen Frustrated Lewis Pairs Beyond the Main Group: Transition Metal-Containing Systems, by D. Wass Reactions of Phosphine-Boranes and Related Frustrated Lewis Pairs with Transition Metal Complexes, by Abderrahmane Amgoune, Ghenwa Bouhadir, Didier Bourissou
2000 International Chemical Congress Of Pacific Basin Societies
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Author :
language : en
Publisher:
Release Date : 2000
2000 International Chemical Congress Of Pacific Basin Societies written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000 with Chemistry categories.
Metal To Metal Bonded States Of The Main Group Elements
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Author : Michael James Taylor
language : en
Publisher:
Release Date : 1975
Metal To Metal Bonded States Of The Main Group Elements written by Michael James Taylor and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1975 with Science categories.
Synthesis And Reactivity Of Lanthanide Transition Metal Polyhydride Complexes
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Author : Daniel Alvarez
language : en
Publisher:
Release Date : 1990
Synthesis And Reactivity Of Lanthanide Transition Metal Polyhydride Complexes written by Daniel Alvarez and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990 with Rare earth metals categories.
Energy Research Abstracts
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Author :
language : en
Publisher:
Release Date : 1978
Energy Research Abstracts written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1978 with Power resources categories.
Bulletin Of The Chemical Society Of Japan
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Author : Nihon Kagakkai
language : en
Publisher:
Release Date : 1997
Bulletin Of The Chemical Society Of Japan written by Nihon Kagakkai and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1997 with Chemistry categories.
Cumulated Index Medicus
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Author :
language : en
Publisher:
Release Date : 1989
Cumulated Index Medicus written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1989 with Medicine categories.
The Chemical Bond
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Author : Gernot Frenking
language : en
Publisher: John Wiley & Sons
Release Date : 2014-07-08
The Chemical Bond written by Gernot Frenking and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-07-08 with Science categories.
This is the perfect complement to "Chemical Bonding - Across the Periodic Table" by the same editors, who are two of the top scientists working on this topic, each with extensive experience and important connections within the community. The resulting book is a unique overview of the different approaches used for describing a chemical bond, including molecular-orbital based, valence-bond based, ELF, AIM and density-functional based methods. It takes into account the many developments that have taken place in the field over the past few decades due to the rapid advances in quantum chemical models and faster computers.
