Reagents For Silicon Mediated Organic Synthesis
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Reagents For Silicon Mediated Organic Synthesis
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Author : Philip L. Fuchs
language : en
Publisher: John Wiley & Sons
Release Date : 2011-11-07
Reagents For Silicon Mediated Organic Synthesis written by Philip L. Fuchs and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-11-07 with Technology & Engineering categories.
Over the last three decades the importance of organosilicon chemistry has greatly increased because it has opened a number of new synthetic strategies. Silicon reagents are usually low-cost, versatile and allow a wide range of reactions. This is the first Handbook to compile essential Silicon containing reagents and makes use of the leading reagent database e-EROS. Another hot volume in the series Handbooks of Reagents for Organic Synthesis, this is a must-have resource for all synthetic chemists working in drug development and medicinal chemistry. For the selection the Editor focussed on three key synthetic approaches with the greatest impact: 1. Use of silicon as a 'temporary tether' by unifying a reactive pair of functional groups and taking advantage of their template-biased intramolecular cyclization. 2. The specific use of the silane functionality as a hetero t-butyl group, often colloquially referred to as the use of silicon as a 'fat proton'. 3. The use of the Brook rearrangement as an 'anion relay stratagem'. A new feature in this Handbook is the reagent finder, an alphabetically organized lookup table arranged by organic functionality and specific structure of the silicon atom to which it is bound.
Reagents For Silicon Mediated Organic Synthesis
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Author : Philip L. Fuchs
language : en
Publisher: John Wiley & Sons
Release Date : 2013-05-30
Reagents For Silicon Mediated Organic Synthesis written by Philip L. Fuchs and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-05-30 with Technology & Engineering categories.
Over the last three decades the importance of organosiliconchemistry has greatly increased because it has opened a number ofnew synthetic strategies. Silicon reagents are usually low-cost,versatile and allow a wide range of reactions. This is the firstHandbook to compile essential Silicon containing reagents and makesuse of the leading reagent database e-EROS. Another hotvolume in the series Handbooks of Reagents for OrganicSynthesis, this is a must-have resource for all syntheticchemists working in drug development and medicinal chemistry. For the selection the Editor focussed on three key syntheticapproaches with the greatest impact: 1. Use of silicon as a 'temporary tether' by unifying a reactivepair of functional groups and taking advantage of theirtemplate-biased intramolecular cyclization. 2. The specific use of the silane functionality as a heterot-butyl group, often colloquially referred to as the use ofsilicon as a 'fat proton'. 3. The use of the Brook rearrangement as an 'anion relaystratagem'. A new feature in this Handbook is the reagent finder, analphabetically organized lookup table arranged by organicfunctionality and specific structure of the silicon atom to whichit is bound.
Silicon Reagents For Organic Synthesis
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Author : William P. Weber
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Silicon Reagents For Organic Synthesis written by William P. Weber and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Silicon Reagents In Organic Synthesis
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Author : Ernest W. Colvin
language : en
Publisher:
Release Date : 1988
Silicon Reagents In Organic Synthesis written by Ernest W. Colvin and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with Science categories.
This work provides a full coverage of organosilicon chemistry, with pertinent references to more detailed treatment given at appropriate points in the book.
Silicon Mediated Transformations Of Functional Groups
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Author : Helmut Vorbrueggen
language : en
Publisher: John Wiley & Sons
Release Date : 2006-03-06
Silicon Mediated Transformations Of Functional Groups written by Helmut Vorbrueggen and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-03-06 with Science categories.
In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbrüggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar with different aspects of silylation for the protection of functional groups, this book covers the concept of protection while simultaneously silylating-activating various functional groups, such as amides and ureas. This novel methodology opens thus numerous synthetic pathways while effecting the elimination of water in it volatile persilylated form under rather mild reaction conditions, which are often advantageous compared to conventional methods. The compact form and clear structure of this monograph make this a long-awaited ready reference. From the contents: Introduction * Techniques of Preparative Silylations-Desilylations * Preparation and Properties of Siliconoxy-Leaving Groups * Reactions of Free and Derivatized Carboxylic Acids and Carbon Dioxide * Reactions of Aldehydes and Ketones * Reactions of Alcohols, Ethers and Epoxides * Reaction of N-O Systems * Reactions of S-O and Se-O Systems * Cyclizations and Ring Enlargements * Base and Acid-Catalyzed as well as Thermal Eliminations of Trimethylsilanol. Peterson Reactions * Formation of Carbon-Phosphorous Double- and Triple Bonds * Reductions and Oxidations * Dehydration-Activation as well as Silylation of Inorganic and Organic Salts and Metalorganic Compounds * Formation of Polymers
Silicon In Organic Synthesis
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Author : Ernest W. Colvin
language : en
Publisher: Butterworth-Heinemann
Release Date : 2013-10-22
Silicon In Organic Synthesis written by Ernest W. Colvin and has been published by Butterworth-Heinemann this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-22 with Science categories.
Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a “ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of α-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon; the preparation and chemistry of vinylsilanes, allylsilanes, arylsilanes, and organosilyl metallic compounds. Subsequent chapters cover the synthesis of compounds such as alkene, alkynylsilanes, allenylsilanes, silylketenes, alkyl silyl ethers, acyloxysilanes, and silyl enol ethers. This book aims to serve as a timely introduction to organic chemistry for students and practitioners of synthetic organic chemistry, as well as provide a source of useful information and possibly of new ideas to those already experienced in the area.
Handbook Of Reagents For Organic Synthesis
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Author :
language : en
Publisher:
Release Date : 1999
Handbook Of Reagents For Organic Synthesis written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999 with categories.
The Chemistry Of Silicon
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Author : E. G. Rochow
language : en
Publisher: Elsevier
Release Date : 2013-10-22
The Chemistry Of Silicon written by E. G. Rochow and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-22 with Science categories.
Pergamon Texts in Organic Chemistry, Volume 9: The Chemistry of Silicon presents information essential in understanding the chemical properties of silicon. The book first covers the fundamental aspects of silicon, such as its nuclear, physical, and chemical properties. The text also details the history of silicon, its occurrence and distribution, and applications. Next, the selection enumerates the compounds and complexes of silicon, along with organosilicon compounds. The text will be of great interest to chemists and chemical engineers. Other researchers working on research study involving silicon will also benefit from the book.
Sulfur Reagents In Organic Synthesis
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Author : Patrick Metzner
language : en
Publisher: Elsevier
Release Date : 2013-10-22
Sulfur Reagents In Organic Synthesis written by Patrick Metzner and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-22 with Science categories.
Designed for the practising organic chemist, this book details over a hundred experimental procedures using sulfer compounds in organic synthesis. Many of these methods are new to the literature, having been published since 1991, and illustrate the striking versatility of the use of sulfur reagents. Examples are simple to perform and extremely useful, and as such this book will be an invaluable aid to all involved in synthetic organic chemistry, whether in academic or industrial laboratories.
Silicon In Organic Synthesis
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Author : Ernest W. Colvin
language : en
Publisher:
Release Date : 1981
Silicon In Organic Synthesis written by Ernest W. Colvin and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1981 with Composés organosiliciés categories.