Review And Evaluation Of Alternative Chemical Disposal Technologies


Review And Evaluation Of Alternative Chemical Disposal Technologies
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Review And Evaluation Of Alternative Chemical Disposal Technologies


Review And Evaluation Of Alternative Chemical Disposal Technologies
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Author : National Research Council
language : en
Publisher: National Academies Press
Release Date : 1996-12-15

Review And Evaluation Of Alternative Chemical Disposal Technologies written by National Research Council and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996-12-15 with Political Science categories.


In 1994 the National Research Council published Recommendations for the Disposal of Chemical Agents and Munitions, which assessed the status of various alternative destruction technologies in comparison to the Army's baseline incineration system. The volume's main finding was that no alternative technology was preferable to incineration but that work should continue on the neutralization technologies under Army consideration. In light of the fact that alternative technologies have evolved since the 1994 study, this new volume evaluates five Army-chosen alternatives to the baseline incineration system for the disposal of the bulk nerve and mustard agent stored in ton containers at Army sites located in Newport, Indiana, and Aberdeen, Maryland, respectively. The committee assessed each technology by conducting site visits to the locations of the technology proponent companies and by meeting with state regulators and citizens of the affected areas. This volume makes recommendations to the Army on which, if any, of the five technologies has reached a level of maturity appropriate for consideration for pilot-scale testing at the two affected sites.



Review And Evaluation Of Alternative Technologies For Demilitarization Of Assembled Chemical Weapons


Review And Evaluation Of Alternative Technologies For Demilitarization Of Assembled Chemical Weapons
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Author : Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons
language : en
Publisher: National Academies Press
Release Date : 1999-12-08

Review And Evaluation Of Alternative Technologies For Demilitarization Of Assembled Chemical Weapons written by Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999-12-08 with Nature categories.


This report examines seven disposal technologies being considered by the U.S. government as alternative methods to the process of incineration for destroying mortars, rockets, land mines, and other weapons that contain chemical warfare agents, such as mustard gas. These weapons are considered especially dangerous because they contain both chemical warfare agent and explosive materials in an assembled package that must be disassembled for destruction. The study identifies the strengths and weaknesses and advantages and disadvantages of each technology and assesses their potential for full-scale implementation.



Review And Evaluation Of Alternative Technologies For Demilitarization Of Assembled Chemical Weapons


Review And Evaluation Of Alternative Technologies For Demilitarization Of Assembled Chemical Weapons
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Author : National Research Council
language : en
Publisher: National Academies Press
Release Date : 1999-12-24

Review And Evaluation Of Alternative Technologies For Demilitarization Of Assembled Chemical Weapons written by National Research Council and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999-12-24 with Science categories.


This report examines seven disposal technologies being considered by the U.S. government as alternative methods to the process of incineration for destroying mortars, rockets, land mines, and other weapons that contain chemical warfare agents, such as mustard gas. These weapons are considered especially dangerous because they contain both chemical warfare agent and explosive materials in an assembled package that must be disassembled for destruction. The study identifies the strengths and weaknesses and advantages and disadvantages of each technology and assesses their potential for full-scale implementation.



Evaluation Of Alternative Technologies For Disposal Of Liquid Wastes From The Explosive Destruction System


Evaluation Of Alternative Technologies For Disposal Of Liquid Wastes From The Explosive Destruction System
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Author : National Research Council
language : en
Publisher: National Academies Press
Release Date : 2002-01-20

Evaluation Of Alternative Technologies For Disposal Of Liquid Wastes From The Explosive Destruction System written by National Research Council and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002-01-20 with Science categories.


Chemical warfare materiel (CWM) encompasses diverse items that were used during 60 years of efforts by the United States to develop a capability for conducting chemical warfare. Non-Stockpile CWM (NSCWM) is materiel not included in the current U.S. inventory of chemical munitions and includes buried materiel, recovered materiel, components of binary chemical weapons, former production facilities, and miscellaneous materiel. Because NSCWM is stored or buried at many locations, the Army is developing transportable treatment systems that can be moved from site to site as needed. Originally, the Army planned to develop three transportable treatment systems for nonstockpile chemical materiel: the rapid response system (RRS), the munitions management device (MMD), and the explosive destruction system (EDS). This report supplements an earlier report that evaluated eight alternative technologies for destruction of the liquid waste streams from two of the U.S. Army's transportable treatment systems for nonstockpile chemical materiel: the RRS and the MMD. This report evaluates the same technologies for the destruction of liquid waste streams produced by the EDS and discusses the regulatory approval issues and obstacles for the combined use of the EDS and the alternative technologies that treat the EDS secondary waste streams. Although it focuses on the destruction of EDS neutralent, it also takes into consideration the ability of posttreatment technologies to process the more dilute water rinses that are used in the EDS following treatment with a reagent.



Disposal Of Neutralent Wastes


Disposal Of Neutralent Wastes
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Author : National Research Council
language : en
Publisher: National Academies Press
Release Date : 2001-04-29

Disposal Of Neutralent Wastes written by National Research Council and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001-04-29 with Science categories.


Chemical warfare materiel (CWM) is a collection of diverse items that were used during 60 years of efforts by the United States to develop a capability for conducting chemical warfare. Nonstockpile CWM, which is not included in the current U.S. inventory of chemical munitions, includes buried materiel, recovered materiel, binary chemical weapons, former production facilities, and miscellaneous materiel. CWM that was buried in pits on former military sites is now being dug up as the land is being developed for other purposes. Other CWM is on or near the surface at former test and firing ranges. According to the Chemical Weapons Convention (CWC), which was ratified by the United States in April 1997, nonstockpile CWM items in storage at the time of ratification must be destroyed by 2007. The U.S. Army is the designated executive agent for destroying CWM. Nonstockpile CWM is being handled by the Non-Stockpile Chemical Materiel Program (NSCMP); stockpile CWM is the responsibility of the Chemical Stockpile Disposal Program. Because nonstockpile CWM is stored or buried in many locations, the Army is developing transportable disposal systems that can be moved from site to site as needed. The Army has plans to test prototypes of three transportable systems-the rapid response system (RRS), the munitions management device (MMD), and the explosive destruction system (EDS)-for accessing and destroying a range of nonstockpile chemical agents and militarized industrial chemicals. The RRS is designed to treat recovered chemical agent identification sets (CAIS), which contain small amounts of chemical agents and a variety of highly toxic industrial chemicals. The MMD is designed to treat nonexplosively configured chemical munitions. The EDS is designed to treat munitions containing chemical agents with energetics equivalent to three pounds of TNT or less. These munitions are considered too unstable to be transported or stored. A prototype EDS system has recently been tested in England by non-stockpile program personnel. Although originally proposed for evaluation in this report, no test data were available to the committee on the composition of wastes from the EDS. Therefore, alternative technologies for the destruction of EDS wastes will be discussed in a supplemental report in fall 2001. Treatment of solid wastes, such as metal munition bodies, packing materials, and carbon air filters, were excluded from this report. Review and Evaluation of the Army Non-Stockpile Chemical Materiel Disposal Program: Disposal of Neutralent Wastes evaluates the near-term (1999-2005) application of advanced (nonincineration) technologies, such as from the Army's Assembled Chemical Weapons Assessment Program and the Alternative Technologies and Approaches Project, in a semi-fixed, skid-mounted mode to process Rapid Response System, Munitions Management Device, and Explosive Destruction System liquid neutralization wastes.



Integrated Design Of Alternative Technologies For Bulk Only Chemical Agent Disposal Facilities


Integrated Design Of Alternative Technologies For Bulk Only Chemical Agent Disposal Facilities
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Author : National Research Council
language : en
Publisher: National Academies Press
Release Date : 2000-06-19

Integrated Design Of Alternative Technologies For Bulk Only Chemical Agent Disposal Facilities written by National Research Council and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-06-19 with Technology & Engineering categories.


The U.S. Army is pilot testing chemical hydrolysis as a method for destroying the chemical agents stockpiled at Aberdeen, Maryland (HD mustard agent), and Newport, Indiana (VX nerve agent). The chemical agents at both locations, which are stored only in bulk ton containers, will be hydrolyzed (using aqueous sodium hydroxide for VX and water for HD) at slightly below the boiling temperature of the solution. The resulting hydrolysate at Aberdeen, which will contain thiodiglycol as the primary reaction product, will be treated by activated sludge biodegradation in sequencing batch reactors to oxidize organic constituents prior to discharge to an on-site federally owned wastewater treatment facility. The hydrolysate at Newport, which will contain a thiol amine and methyl phosphonic acid as the major reaction products, is not readily amenable to treatment by biodegradation. Therefore, organic constituents will be treated using supercritical water oxidation (SCWO). Integrated Design of Alternative Technologies for Bulk-Only Chemical Agent Disposal Facilities focuses on the overarching issues in the process designs integrating individual processing steps, including potential alternative configurations and process safety and reliability. This report reviews the acquisition design packages (ADPs) for the ABCDF and NECDF prepared by Stone and Webster Engineering Company for the U.S. Army.



Review And Evaluation Of Alternative Chemical Disposal Technologies


Review And Evaluation Of Alternative Chemical Disposal Technologies
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Author : Panel on Review and Evaluation of Alternative Chemical Disposal Technologies
language : en
Publisher: National Academies Press
Release Date : 1996-11-29

Review And Evaluation Of Alternative Chemical Disposal Technologies written by Panel on Review and Evaluation of Alternative Chemical Disposal Technologies and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996-11-29 with Science categories.


In 1994 the National Research Council published Recommendations for the Disposal of Chemical Agents and Munitions, which assessed the status of various alternative destruction technologies in comparison to the Army's baseline incineration system. The volume's main finding was that no alternative technology was preferable to incineration but that work should continue on the neutralization technologies under Army consideration. In light of the fact that alternative technologies have evolved since the 1994 study, this new volume evaluates five Army-chosen alternatives to the baseline incineration system for the disposal of the bulk nerve and mustard agent stored in ton containers at Army sites located in Newport, Indiana, and Aberdeen, Maryland, respectively. The committee assessed each technology by conducting site visits to the locations of the technology proponent companies and by meeting with state regulators and citizens of the affected areas. This volume makes recommendations to the Army on which, if any, of the five technologies has reached a level of maturity appropriate for consideration for pilot-scale testing at the two affected sites.



Systems And Technologies For The Treatment Of Non Stockpile Chemical Warfare Materiel


Systems And Technologies For The Treatment Of Non Stockpile Chemical Warfare Materiel
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Author : National Research Council
language : en
Publisher: National Academies Press
Release Date : 2002-08-01

Systems And Technologies For The Treatment Of Non Stockpile Chemical Warfare Materiel written by National Research Council and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002-08-01 with Science categories.


The main approach adopted by the U.S. Army for destruction of all declared chemical weapon materiel (CWM) is incineration. There has been considerable public opposition to this approach, however, and the Army is developing a mix of fixed site and mobile treatment technologies to dispose of non-stockpile CWM. To assist in this effort, the Army requested NRC to review and evaluate these technologies, and to assess its plans for obtaining regulatory approval for and to involve the public in decisions about the application of those technologies. This book presents an assessment of non-stockpile treatment options and the application of these systems to the non-stockpile inventory, of regulatory and permitting issues, and of the role of the public.



Analysis Of Engineering Design Studies For Demilitarization Of Assembled Chemical Weapons At Pueblo Chemical Depot


Analysis Of Engineering Design Studies For Demilitarization Of Assembled Chemical Weapons At Pueblo Chemical Depot
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Author : National Research Council
language : en
Publisher: National Academies Press
Release Date : 2001-09-27

Analysis Of Engineering Design Studies For Demilitarization Of Assembled Chemical Weapons At Pueblo Chemical Depot written by National Research Council and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001-09-27 with Science categories.


The Program Manager for Assembled Chemical Weapons Assessment (PMACWA) of the Department of Defense (DOD) requested the National Research Council (NRC) to assess the engineering design studies (EDSs) developed by Parsons/Honeywell and General Atomics for a chemical demilitarization facility to completely dispose of the assembled chemical weapons at the Pueblo Chemical Depot in Pueblo, Colorado. To accomplish the task, the NRC formed the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (ACW II Committee). This report presents the results of the committee's scientific and technical assessment, which will assist the Office of the Secretary of Defense in selecting the technology package for destroying the chemical munitions at Pueblo. The committee evaluated the engineering design packages proposed by the technology providers and the associated experimental studies that were performed to validate unproven unit operations. A significant part of the testing program involved expanding the technology base for the hydrolysis of energetic materials associated with assembled weapons. This process was a concern expressed by the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (ACW I Committee) in its original report in 1999 (NRC, 1999). The present study took place as the experimental studies were in progress. In some cases, tests for some of the supporting unit operations were not completed in time for the committee to incorporate results into its evaluation. In those cases, the committee identified and discussed potential problem areas in these operations. Based on its expertise and its aggressive data-gathering activities, the committee was able to conduct a comprehensive review of the test data that had been completed for the overall system design. This report summarizes the study.



Recommendations For The Disposal Of Chemical Agents And Munitions


Recommendations For The Disposal Of Chemical Agents And Munitions
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Author : National Research Council
language : en
Publisher: National Academies Press
Release Date : 1994-02-01

Recommendations For The Disposal Of Chemical Agents And Munitions written by National Research Council and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994-02-01 with Science categories.


The U.S. Army's chemical stockpile is aging and gradually deteriorating. Its elimination has public, political, and environmental ramifications. The U.S. Department of Defense has designated the Department of the Army as the executive agent responsible for the safe, timely, and effective elimination of the chemical stockpile. This book provides recommendations on the direction the Army should take in pursuing and completing its Chemical Stockpile Disposal Program.