Solvent Effects On Reaction Rates And Mechanisms
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Solvent Effects On Reaction Rates And Mechanisms
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Author : Edward Stephen Amis
language : en
Publisher:
Release Date : 1966
Solvent Effects On Reaction Rates And Mechanisms written by Edward Stephen Amis and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1966 with Science categories.
"Solvent Effects on Reaction Ratyes and mechanisms" is a title that will conjure up visions of different things to different investigators in the field of reaction kinetics. The physical chemist will envision the effects on rates of reactions of dieelectric constant, viscosity, internal cohesion, and externaL pressure as these are iinfluenced by the solvent. The physical-organic chemist will perhaps call to mind acidity, basicity, hydrogen bonding, structure effects, electro-negativity, and solvating ability as related to the solvent. The stricly organic chemist may simplyt think in terms of a medium in which reactants can be made to form products merely because of solubility relations, and his choice of solvent may depend on the ease of obtaining in a reasonable length of time a relatively pure product by extraction or other procedures. And, in fact, the topic includes all these and much more. Some of the phenomena are merely recorded as experimental observations. Some factors are subject to theoretical explanation, but even when theoretically explained or mathematically formulated they may not be sufficiently dominant ti justify the applicaton of the theory. Other effects may not be subject to theoretical explanations but may be included in correlations that are widely applicable. The explanation of some effects may be purely conjectural, but at least give some satisfaction to the seekers of the answer to the question, why? The material presented in the following pages will run the gamut of all the above possibilities.
Solvent Effects On Chemical Phenomena
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Author : Edward Amis
language : en
Publisher: Elsevier
Release Date : 2012-12-02
Solvent Effects On Chemical Phenomena written by Edward Amis and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
Solvent Effects on Chemical Phenomena, Volume I discusses the developments in the understanding of solvent effects on chemical phenomena in solution. This five-chapter volume begins with a discussion on the general concepts of various solvation types, including positive and negative, inner and outer sphere, and mixed component. The subsequent chapter deals with the determination of the actual solvation number for single ions. A short list of the total effective hydration numbers of electrolytes determined from temperature dependence of proton shifts is also provided in this chapter. Another chapter presents a number of examples of the unusual properties of certain mixed aqueous systems. The solvent effects on reaction rates and mechanisms are highlighted in the concluding chapter. This chapter also covers various types of solvents, such as protic and dipolar aprotic. The enthalpy and entropy of activation in salvation and the Finkelstein reactions are also discussed. Research chemists and scientists, teachers, and students with courses in solution chemistry will greatly benefit from this volume.
Solvent Effects In Chemistry
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Author : Erwin Buncel
language : en
Publisher: John Wiley & Sons
Release Date : 2015-08-03
Solvent Effects In Chemistry written by Erwin Buncel and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-08-03 with Technology & Engineering categories.
This book introduces the concepts, theory and experimental knowledge concerning solvent effects on the rate and equilibrium of chemical reactions of all kinds. It begins with basic thermodynamics and kinetics, building on this foundation to demonstrate how a more detailed understanding of these effects may be used to aid in determination of reaction mechanisms, and to aid in planning syntheses. Consideration is given to theoretical calculations (quantum chemistry, molecular dynamics, etc.), to statistical methods (chemometrics), and to modern day concerns such as "green" chemistry, where utilization and disposal of chemical waste or by-products in an environmentally safe way is as important as achieving the desired end products by all chemists nowadays. The treatment progresses from elementary to advanced material in straightforward fashion. The more advanced topics are not developed in an overly rigorous way so that upper-level undergraduates, graduates, and newcomers to the field can grasp the concepts easily.
Solvent Effects In Chemistry
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Author : E. Buncel
language : en
Publisher:
Release Date : 2016
Solvent Effects In Chemistry written by E. Buncel and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016 with Chemical reactions categories.
Rates And Mechanisms Of Chemical Reactions
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Author : W. C. Gardiner (Jr.)
language : en
Publisher: Benjamin-Cummings Publishing Company
Release Date : 1969
Rates And Mechanisms Of Chemical Reactions written by W. C. Gardiner (Jr.) and has been published by Benjamin-Cummings Publishing Company this book supported file pdf, txt, epub, kindle and other format this book has been release on 1969 with Science categories.
Inorganic Reaction Mechanisms
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Author : John Burgess
language : en
Publisher: Royal Society of Chemistry
Release Date : 1971
Inorganic Reaction Mechanisms written by John Burgess and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 1971 with Chemical reaction, Conditions and laws of categories.
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Chemical Kinetics
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Author : Kenneth Antonio Connors
language : en
Publisher: Wiley-VCH Verlag GmbH
Release Date : 1990
Chemical Kinetics written by Kenneth Antonio Connors and has been published by Wiley-VCH Verlag GmbH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990 with Science categories.
Chemical Kinetics The Study of Reaction Rates in Solution Kenneth A. Connors This chemical kinetics book blends physical theory, phenomenology and empiricism to provide a guide to the experimental practice and interpretation of reaction kinetics in solution. It is suitable for courses in chemical kinetics at the graduate and advanced undergraduate levels. This book will appeal to students in physical organic chemistry, physical inorganic chemistry, biophysical chemistry, biochemistry, pharmaceutical chemistry and water chemistry all fields concerned with the rates of chemical reactions in the solution phase.
Kinetics And Mechanism
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Author : John W. Moore
language : en
Publisher: John Wiley & Sons
Release Date : 1981-09-30
Kinetics And Mechanism written by John W. Moore and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 1981-09-30 with Science categories.
The third edition of a classic text originally by Frost and Pearson, that describes the fundamental principles and established practices that apply to the study and the rates and mechanisms of homogeneous chemical reactions in the gas phase and in solution. Incorporates new advances made during the past 20 years in the study of individual molecular collisions by molecular-beam, laser applications to experimental kinetics, theoretical treatments of reaction rates and our understanding of the principles that govern rates of reaction in solution. Presents numerous examples of the deduction of mechanism from experiment, including intimate details such as stereochemistry and the dependence of reaction pathway on the exact energy states of reacting particles.
Chemical Kinetics And Reaction Mechanisms
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Author : James H. Espenson
language : en
Publisher: McGraw-Hill Science, Engineering & Mathematics
Release Date : 1995
Chemical Kinetics And Reaction Mechanisms written by James H. Espenson and has been published by McGraw-Hill Science, Engineering & Mathematics this book supported file pdf, txt, epub, kindle and other format this book has been release on 1995 with Science categories.
Covering chemical kinetics from the working chemist's point of view, this book aims to prepare chemists to devise experiments to test different hypothesis. A number of examples from research literature have been included.
Solvent Effects On Reaction Rates And Mechanisms
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FREE 30 Days
Author : Edward Stephen Amis
language : en
Publisher:
Release Date : 1966
Solvent Effects On Reaction Rates And Mechanisms written by Edward Stephen Amis and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1966 with Science categories.
"Solvent Effects on Reaction Ratyes and mechanisms" is a title that will conjure up visions of different things to different investigators in the field of reaction kinetics. The physical chemist will envision the effects on rates of reactions of dieelectric constant, viscosity, internal cohesion, and externaL pressure as these are iinfluenced by the solvent. The physical-organic chemist will perhaps call to mind acidity, basicity, hydrogen bonding, structure effects, electro-negativity, and solvating ability as related to the solvent. The stricly organic chemist may simplyt think in terms of a medium in which reactants can be made to form products merely because of solubility relations, and his choice of solvent may depend on the ease of obtaining in a reasonable length of time a relatively pure product by extraction or other procedures. And, in fact, the topic includes all these and much more. Some of the phenomena are merely recorded as experimental observations. Some factors are subject to theoretical explanation, but even when theoretically explained or mathematically formulated they may not be sufficiently dominant ti justify the applicaton of the theory. Other effects may not be subject to theoretical explanations but may be included in correlations that are widely applicable. The explanation of some effects may be purely conjectural, but at least give some satisfaction to the seekers of the answer to the question, why? The material presented in the following pages will run the gamut of all the above possibilities.