Structural Characterization Of Organocopper Reagents
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Structural Characterization Of Organocopper Reagents
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Author : Hui Huang
language : en
Publisher:
Release Date : 1997
Structural Characterization Of Organocopper Reagents written by Hui Huang and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1997 with categories.
The Chemistry Of Organocopper Compounds
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Author : Zvi Rappoport
language : en
Publisher: John Wiley & Sons
Release Date : 2009-12-21
The Chemistry Of Organocopper Compounds written by Zvi Rappoport and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-12-21 with Science categories.
Copper in organic synthesis has seen a tremendous development over the past ten years. This text represents the most comprehensive survey on the use of Copper and Cuprates in organic synthesis. The first time that the Patai Series touches on Copper compounds, it contains contributions by leading experts, and delivers the quality expected from the Patai Series.
An Introduction To Synthesis Using Organocopper Reagents
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Author : Gary H. Posner
language : en
Publisher:
Release Date : 1988
An Introduction To Synthesis Using Organocopper Reagents written by Gary H. Posner and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with Science categories.
Polar Organometallic Reagents
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Author : Andrew E. H. Wheatley
language : en
Publisher: John Wiley & Sons
Release Date : 2022-03-14
Polar Organometallic Reagents written by Andrew E. H. Wheatley and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-03-14 with Science categories.
Outlines recent advances in the field of polar organometallic chemistry, particularly in the context of the emergent areas of synergic and cooperative species. Polar Organometallic Reagents provides a critical overview of developments in the field of modern polar organometallic chemistry. With a particular focus on the emergent area of synergic heterometallic reagents, this timely volume describes our attempts to understand recently developed polar organometallics and their application in a range of new directions. Contributions from leading researchers present new synthetic work and discuss recent advances in characterization techniques, synthetic applications, and mechanistic understanding of heterometallic complexes. In-depth chapters provide detailed information on fundamental, structural, and theoretical aspects of polar organometallic chemistry while articulating the need and rationale for the advent of new reagents. Topics include alkali and alkaline earth organometallics, synergy and cooperativity, cationic p-block clusters and other developments in main group catalysis, synthetic trends in alkenyl copper, ate complex and borylmetal chemistry, non-traditional reaction environments, and trends in developing greener processes. Designed to keep readers updated with the latest progress in the field, this much-needed book: Includes an introductory chapter outlining the development of synergic bases and the logic behind their creation Highlights the role of solid-state structural work in elucidating the bonding and reactivity displayed by modern polar organometallics Examines the use of calculations in catalyst design and plotting more sustainable reaction pathways Discusses modern trends in solution techniques that have achieved new insights into the structures of active species Presents striking advances in the ease of handling of polar organometallics and the emergence of main group catalysis Polar Organometallic Reagents is essential reading for researchers in chemical disciplines including synthetic inorganic and coordination chemistry, main group chemistry, organometallic chemistry, organic synthesis and catalysis.
Comprehensive Organic Synthesis Additions To And Substitutions At C C Pi Bonds
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Author : Barry M. Trost
language : en
Publisher: Elsevier
Release Date : 1991
Comprehensive Organic Synthesis Additions To And Substitutions At C C Pi Bonds written by Barry M. Trost and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1991 with Science categories.
Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.
Modern Organocopper Chemistry
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Author : Norbert Krause
language : en
Publisher: John Wiley & Sons
Release Date : 2002
Modern Organocopper Chemistry written by Norbert Krause and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002 with Science categories.
Organocopper compounds are now an integral part of every modern synthesis laboratory, allowing important stages of synthesis to be carried out in an elegant fashion. Yet a certain amount of experience is needed if they are to be used effectively. Non-experts in the field often have difficulty in choosing the most suitable reagent for a particular substrate and the prerequisites for the reaction.This manual, edited by Norbert Krause, answers such questions, since it contains all the useful tips and tricks on organocopper compounds - information gained from personal experience by the international team of authors. This allows those working in laboratories in both academia and industry to determine the optimal reagent for their needs using the substrates available for reaction and the desired products. The result is a more effective use of these synthesis tools in everyday laboratory practice.
Additions To C X Bonds
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Author : Barry M. Trost
language : en
Publisher: Elsevier
Release Date : 1992-09-08
Additions To C X Bonds written by Barry M. Trost and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992-09-08 with Science categories.
Volume 2 deals mainly with the addition reactions of delocalized carbanions (enolates) and their synthetic relatives (metalloenamines, enol ethers, allyl organometallics) with carbonyl compounds, imines and iminium ions. Major emphasis is placed on C-C bond-forming reactions such as the aldol and Mannich reactions. Acylation reactions are also included in this volume. Several topics that have not previously been reviewed are covered, including the use of enzymatic aldol reactions in synthesis and the Passerini-Ugi reactions.
Combining C C Bonds
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Author : L.A. Paquette
language : en
Publisher: Elsevier
Release Date : 1992-09-08
Combining C C Bonds written by L.A. Paquette and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992-09-08 with Science categories.
The guiding principle underlying the subject matter specifically compiled in Volume 5 has been to make available to the organic chemical community a sourcebook comprehensively covering all the important &pgr;-bond-dependent transformations. Thermal, photochemical, and metal-catalyzed cycloadditions of every major type are expertly detailed by the most knowledgeable researchers in these areas. The synthetically useful electrocyclic and sigmatropic processes where alkenic centers are intimately involved in the structural change are similarly canvassed in compact detail. With added attention given to ene reactions, small-ring rearrangements, and related transition metal-associated reactions, coverage has been achieved of the full range of organic transformations directly involving the rebonding of alkenic centers. As a consequence, this volume should serve as the comprehensive sourcebook of the field for the next decade and beyond.
Carbon Carbon Bond Formation
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Author : G. Pattenden
language : en
Publisher: Elsevier
Release Date : 1992-09-08
Carbon Carbon Bond Formation written by G. Pattenden and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992-09-08 with Science categories.
Volume 3 covers carbon-to-carbon single bond forming reactions involving sp3, sp2 and sp carbon centers, but only those which do not involve additions to C-X &pgr;-bonds. The volume first compares and contrasts the alkylation reactions of all types of sp3 carbon nucleophiles and also covers vinyl and alkynyl carbanions. Following on from Volume 2, a separate section covers Friedel-Crafts alkylation reactions, which is complemented by discussions of polyene cyclizations and electrophilic transannular cyclizations in synthesis. Coupling reactions leading to &agr;-bond formation, and involving all types of combinations ofsp3, sp2 and sp carbon centers are next covered, including those reactions based on pinacol, acyloin and phenol oxidative coupling reactions, and also the Kolbe reaction. Rearrangement reactions, leading to carbon-to-carbon &agr;-bond formation, are often used in a clever manner in synthesis. The volume includes all those rearrangement reactions based on intermediate carbonium ions and carbanions, and also includes the benzil-benzilic acid and the Wolff rearrangements. The volume closes with coverage of carbonylation reactions, and the use of carbene insertion reactions into the C-H bond in synthesis.
Heteroatom Manipulation
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Author : E. Winterfeldt
language : en
Publisher: Elsevier
Release Date : 1992-09-08
Heteroatom Manipulation written by E. Winterfeldt and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992-09-08 with Science categories.
In this volume, those functional groups containing heteroatoms that have gained importance in organic synthesis are dealt with in detail. The introduction of these various groups and their relevant transformations are described and the various aspects of chemoselectivity, regioselectivity and stereoselectivity are discussed. After a compilation of the synthetically most useful substitution processes, there is a series of chapters on the various types of acylation reactions and in this context the different methods of acyl group activation are discussed. As functional group protection is of very general importance for organic synthesis, a corresponding chapter is included. This is followed by a section on the preparation of carbonyl derivatives and the most important transformations and rearrangements of functional group derivatives. At the end of the volume one finds chapters on all types of elimination reactions and related thermal reactions together with a survey on fragmentation processes in organic synthesis.