Structure Of Electrified Interfaces
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Structure Of Electrified Interfaces
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Author : Jacek Lipkowski
language : en
Publisher: Wiley-VCH
Release Date : 1993
Structure Of Electrified Interfaces written by Jacek Lipkowski and has been published by Wiley-VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1993 with Science categories.
This second volume in the Frontiers of Electrochemistry series provides a modern description of the metal-solution interface and describes the advances made in interfacial electrochemistry during the past decade. Contributing authors summarize the impact of new ex situ and in situ techniques in studying electrode surfaces, and illustrate the significance of the development of new experimental techniques and the availability of reliable data in the theory of electrified interfaces. The review articles demonstrate how a molecular picture of the interface has emerged from traditional models that treated the solution as a dielectric and metal as an electronic continuum. Annotation copyright by Book News, Inc., Portland, OR
Electrified Interfaces In Physics Chemistry And Biology
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Author : R Guidelli
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Electrified Interfaces In Physics Chemistry And Biology written by R Guidelli and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Electrified interfaces span from metaVsemiconductor and metaVelectrolyte interfaces to disperse systems and biological membranes, and are notably important in so many physical, chemical and biological systems that their study has been tackled by researchers with different scientific backgrounds using different methodological approaches. The various electrified interfaces have several common features. The equilibrium distribution of positive and negative ions in an electrolytic solution is governed by the same Poisson-Boltzmann equation independent of whether the solution comes into contact with a metal, a colloidal particle or a biomembrane, and the same is true for the equilibrium distribution of free electrons and holes of a semiconductor in contact with a different conducting phase. Evaluation of electric potential differences across biomembranes is based on the same identity of electrochemical potentials which holds for a glass electrode and which yields the Nernst equation when applied to a metal/solution interface. The theory of thermally activated electron tunneling, which was developed by Marcus, Levich, Dogonadze and others to account for electron transfer across metaVelectrolyte interfaces, is also applied to light induced charge separation and proton translocation reactions across intercellular membranes. From an experimental viewpoint, the same electrochemical and in situ spectroscopic techniques can equally well be employed for the study of apparently quite different electrified interfaces.
Frontiers Of Electrochemistry Structure Of Electrified Interfaces
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Author : Jacek Lipkowski
language : en
Publisher: Wiley-VCH
Release Date : 1993-02-17
Frontiers Of Electrochemistry Structure Of Electrified Interfaces written by Jacek Lipkowski and has been published by Wiley-VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1993-02-17 with Science categories.
Leading scientists provide a modern description of the metal-solution interface and describe the numerous advances made in interfacial electrochemistry during the past decade. Contributing authors summarize the impact of new ex situ and in situ techniques in studying electrode surfaces, and illustrate the significance of the developments of new experimental techniques and the availability of reliable data for the progress in the theory of electrified interfaces. The carefully selected review articles demonstrate how a molecular picture of the interface has emerged from traditional models that treated the solution as a dielectric and metals as an electronic continuum. This latest volume in the series leads the reader into the world of modern techniques, which probe the properties of atoms and the molecules at surfaces of metal electrodes. It will be of interest to graduate students and scientists, chemists and physicists interested in surface science and electrochemistry.
Vibrational Spectroscopy At Electrified Interfaces
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Author : Andrzej Wieckowski
language : en
Publisher: John Wiley & Sons
Release Date : 2013-07-15
Vibrational Spectroscopy At Electrified Interfaces written by Andrzej Wieckowski and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-07-15 with Science categories.
Reviews the latest theory, techniques, and applications Surface vibrational spectroscopy techniques probe the structure and composition of interfaces at the molecular level. Their versatility, coupled with their non-destructive nature, enables in-situ measurements of operating devices and the monitoring of interface-controlled processes under reactive conditions. Vibrational Spectroscopy at Electrified Interfaces explores new and emerging applications of Raman, infrared, and non-linear optical spectroscopy for the study of charged interfaces. The book draws from hundreds of findings reported in the literature over the past decade. It features an internationally respected team of authors and editors, all experts in the field of vibrational spectroscopy at surfaces and interfaces. Content is divided into three parts: Part One, Nonlinear Vibrational Spectroscopy, explores properties of interfacial water, ions, and biomolecules at charged dielectric, metal oxide, and electronically conductive metal catalyst surfaces. In addition to offering plenty of practical examples, the chapters present the latest measurement and instrumental techniques. Part Two, Raman Spectroscopy, sets forth highly sensitive approaches for the detection of biomolecules at solid-liquid interfaces as well as the use of photon depolarization strategies to elucidate molecular orientation at surfaces. Part Three, IRRAS Spectroscopy (including PM-IRRAS), reports on wide-ranging systems from small fuel molecules at well-defined surfaces to macromolecular complexes that serve as the building blocks for functional interfaces in devices designed for chemical sensing and electric power generation. The Wiley Series on Electrocatalysis and Electrochemistry is dedicated to reviewing important advances in the field, exploring how these advances affect industry. The series defines what we currently know and can do with our knowledge of electrocatalysis and electrochemistry as well as forecasts where we can expect the field to be in the future.
Heterogeneous Catalysts
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Author : Wey Yang Teoh
language : en
Publisher: John Wiley & Sons
Release Date : 2021-02-23
Heterogeneous Catalysts written by Wey Yang Teoh and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-02-23 with Technology & Engineering categories.
Presents state-of-the-art knowledge of heterogeneous catalysts including new applications in energy and environmental fields This book focuses on emerging techniques in heterogeneous catalysis, from new methodology for catalysts design and synthesis, surface studies and operando spectroscopies, ab initio techniques, to critical catalytic systems as relevant to energy and the environment. It provides the vision of addressing the foreseeable knowledge gap unfilled by classical knowledge in the field. Heterogeneous Catalysts: Advanced Design, Characterization and Applications begins with an overview on the evolution in catalysts synthesis and introduces readers to facets engineering on catalysts; electrochemical synthesis of nanostructured catalytic thin films; and bandgap engineering of semiconductor photocatalysts. Next, it examines how we are gaining a more precise understanding of catalytic events and materials under working conditions. It covers bridging pressure gap in surface catalytic studies; tomography in catalysts design; and resolving catalyst performance at nanoscale via fluorescence microscopy. Quantum approaches to predicting molecular reactions on catalytic surfaces follows that, along with chapters on Density Functional Theory in heterogeneous catalysis; first principles simulation of electrified interfaces in electrochemistry; and high-throughput computational design of novel catalytic materials. The book also discusses embracing the energy and environmental challenges of the 21st century through heterogeneous catalysis and much more. Presents recent developments in heterogeneous catalysis with emphasis on new fundamentals and emerging techniques Offers a comprehensive look at the important aspects of heterogeneous catalysis Provides an applications-oriented, bottoms-up approach to a high-interest subject that plays a vital role in industry and is widely applied in areas related to energy and environment Heterogeneous Catalysts: Advanced Design, Characterization and Applications is an important book for catalytic chemists, materials scientists, surface chemists, physical chemists, inorganic chemists, chemical engineers, and other professionals working in the chemical industry.
Modern Electrochemistry
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Author : John O'M. Bockris
language : en
Publisher: Springer Science & Business Media
Release Date : 1973-10-31
Modern Electrochemistry written by John O'M. Bockris and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 1973-10-31 with Science categories.
7 The Electrified Interface.- 7.1 Electrification of an Interface.- 7.1.1 The Electrode-Electrolyte Interface: The Basis of Electrodics.- 7.1.2 New Forces at the Boundary of an Electrolyte.- 7.1.3 The Interphase Region Has New Properties and New Structures.- 7.1.4 An Electrode Is Like a Giant Central Ion.- 7.1.5 The Consequences of Compromise Arrangements: The Electrolyte Side of the Boundary Acquires a Charge.- 7.1.6 Both Sides of the Interface Become Electrified: The So-Called "Electrical Double Layer"--7.1.7 Double Layers Are Characteristic of All Phase Boundaries.- 7.1.8 A Look into an El.
Atomic Scale Modelling Of Electrochemical Systems
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Author : Marko M. Melander
language : en
Publisher: John Wiley & Sons
Release Date : 2021-09-14
Atomic Scale Modelling Of Electrochemical Systems written by Marko M. Melander and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-09-14 with Science categories.
Atomic-Scale Modelling of Electrochemical Systems A comprehensive overview of atomistic computational electrochemistry, discussing methods, implementation, and state-of-the-art applications in the field The first book to review state-of-the-art computational and theoretical methods for modelling, understanding, and predicting the properties of electrochemical interfaces. This book presents a detailed description of the current methods, their background, limitations, and use for addressing the electrochemical interface and reactions. It also highlights several applications in electrocatalysis and electrochemistry. Atomic-Scale Modelling of Electrochemical Systems discusses different ways of including the electrode potential in the computational setup and fixed potential calculations within the framework of grand canonical density functional theory. It examines classical and quantum mechanical models for the solid-liquid interface and formation of an electrochemical double-layer using molecular dynamics and/or continuum descriptions. A thermodynamic description of the interface and reactions taking place at the interface as a function of the electrode potential is provided, as are novel ways to describe rates of heterogeneous electron transfer, proton-coupled electron transfer, and other electrocatalytic reactions. The book also covers multiscale modelling, where atomic level information is used for predicting experimental observables to enable direct comparison with experiments, to rationalize experimental results, and to predict the following electrochemical performance. Uniquely explains how to understand, predict, and optimize the properties and reactivity of electrochemical interfaces starting from the atomic scale Uses an engaging “tutorial style” presentation, highlighting a solid physicochemical background, computational implementation, and applications for different methods, including merits and limitations Bridges the gap between experimental electrochemistry and computational atomistic modelling Written by a team of experts within the field of computational electrochemistry and the wider computational condensed matter community, this book serves as an introduction to the subject for readers entering the field of atom-level electrochemical modeling, while also serving as an invaluable reference for advanced practitioners already working in the field.
Transport Mediated By Electrified Interfaces
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Author :
language : en
Publisher: Elsevier
Release Date : 2003-08-14
Transport Mediated By Electrified Interfaces written by and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-08-14 with Business & Economics categories.
Transport Mediated by Electrified Interfaces provides an overview of the innovative use of electro-kinetic phenomena in experimentally exploring non-equilibrium regions of chemically non-reacting systems. Transport phenomena mediated by charged liquid-liquid interfaces and solid-liquid interfaces are also covered. Transport phenomena mediated by electrified interfaces are discussed in the context of a number of important areas, including, soil/water systems, phase transfer catalysis, animal/plant physiology and mimicking taste/smell sensing mechanisms. Provides an overview of the innovative use of electro-kinetic phenomena Discusses conventional electro-kinetics and other transport phenomena mediated by charged interfaces Of special interest to those working in the area of interface science
Modern Electrochemistry 2a
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Author : John O'M. Bockris
language : en
Publisher: Springer Science & Business Media
Release Date : 2007-05-08
Modern Electrochemistry 2a written by John O'M. Bockris and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-05-08 with Science categories.
This book had its nucleus in some lectures given by one of us (J. O’M. B. ) in a course on electrochemistry to students of energy conversion at the University of Pennsyl- nia. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all of whom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry which could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importance. Thus, conversion to electrochemically powered transportation systems appears to be an important step by means of which the difficulties of air pollution and the effects of an increasing concentration in the atmosphere of carbon dioxide may be met. Cor- sion is recognized as having an electrochemical basis. The synthesis of nylon now contains an important electrochemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of American organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the United States.
Double Layer And Electrode Kinetics
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Author : Paul Delahay
language : en
Publisher:
Release Date : 1975
Double Layer And Electrode Kinetics written by Paul Delahay and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1975 with categories.