Symmetry In Inorganic And Coordination Compounds
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Symmetry In Inorganic And Coordination Compounds
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Author : Franca Morazzoni
language : en
Publisher: Springer Nature
Release Date : 2021-04-28
Symmetry In Inorganic And Coordination Compounds written by Franca Morazzoni and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-04-28 with Science categories.
This book addresses the nature of the chemical bond in inorganic and coordination compounds. In particular, it explains how general symmetry rules can describe chemical bond of simple inorganic molecules. Since the complexity of studying even simple molecules requires approximate methods, this book introduces a quantum mechanical treatment taking into account the geometric peculiarities of the chemical compound. In the case of inorganic molecules, a convenient approximation comes from symmetry, which constrains both the electronic energies and the chemical bonds. The book also gives special emphasis on symmetry rules and compares the use of symmetry operators with that of Hamiltonian operators. Where possible, the reactivity of molecules is also rationalized in terms of these symmetry properties. As practical examples, electronic spectroscopy and magnetism give experimental confirmation of the predicted electronic energy levels. Adapted from university lecture course notes, this book is the ideal companion for any inorganic chemistry course dealing with group theory.
Symmetry In Inorganic And Coordination Compounds
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Author : Franca Morazzoni
language : en
Publisher:
Release Date : 2021
Symmetry In Inorganic And Coordination Compounds written by Franca Morazzoni and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021 with categories.
This book addresses the nature of the chemical bond in inorganic and coordination compounds. In particular, it explains how general symmetry rules can describe chemical bond of simple inorganic molecules. Since the complexity of studying even simple molecules requires approximate methods, this book introduces a quantum mechanical treatment taking into account the geometric peculiarities of the chemical compound. In the case of inorganic molecules, a convenient approximation comes from symmetry, which constrains both the electronic energies and the chemical bonds. The book also gives special emphasis on symmetry rules and compares the use of symmetry operators with that of Hamiltonian operators. Where possible, the reactivity of molecules is also rationalized in terms of these symmetry properties. As practical examples, electronic spectroscopy and magnetism give experimental confirmation of the predicted electronic energy levels. Adapted from university lecture course notes, this book is the ideal companion for any inorganic chemistry course dealing with group theory.
Symmetry In Coordination Chemistry
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Author : John P. Jr. Fackler
language : en
Publisher: Elsevier
Release Date : 2012-12-02
Symmetry In Coordination Chemistry written by John P. Jr. Fackler and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
Symmetry in Coordination Chemistry provides a comprehensive discussion of molecular symmetry. It attempts to bridge the gap between the elementary ideas of bonding and structure learned by freshmen, and those more sophisticated concepts used by the practicing chemist. The book emphasizes the use of symmetry in describing the bonding and structure of transition metal coordination compounds. The book begins with a review of basic concepts such as molecular symmetry, coordination numbers, symmetry classification, and point group symmetry. This is followed by separate chapters on the electronic, atomic, and magnetic properties of d-block transition elements; the representation of orbital symmetries in a manner consistent with the point group of a molecule. Also included are discussions of vibrational symmetry; crystal field theory, ligand field theory, and molecular orbital theory; and the chemistry of a select few d-block transition elements and their compounds. This book is meant to supplement the traditional course work of junior-senior inorganic students. It is for them that the problems and examples have been chosen.
Symmetry In Coordination Chemistry
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Author : John P. Fackler
language : en
Publisher:
Release Date : 2000
Symmetry In Coordination Chemistry written by John P. Fackler and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000 with categories.
Symmetry And Spectroscopy Of Molecules
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Author : K. Veera Reddy
language : en
Publisher: New Age International
Release Date : 2007
Symmetry And Spectroscopy Of Molecules written by K. Veera Reddy and has been published by New Age International this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007 with Group theory categories.
Stereochemistry Of Coordination Compounds
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Author : Alexander von Zelewsky
language : en
Publisher: John Wiley & Sons
Release Date : 1996-06-03
Stereochemistry Of Coordination Compounds written by Alexander von Zelewsky and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996-06-03 with Science categories.
This well-illustrated and well-referenced book provides a systematic introduction to the modern aspects of the topographical stereochemistry of coordination compounds, which are made up of metal ions surrounded by other non-metal atoms, ions and molecules.
Symmetry In Chemical Theory
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Author : John P. Fackler
language : en
Publisher:
Release Date : 1973
Symmetry In Chemical Theory written by John P. Fackler and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1973 with Science categories.
Physical Inorganic Chemistry
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Author : S. F. A. Kettle
language : en
Publisher: Springer
Release Date : 2013-11-11
Physical Inorganic Chemistry written by S. F. A. Kettle and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-11 with Science categories.
GEORGE CHRISTOU Indiana University, Bloomington I am no doubt representative of a large number of current inorganic chemists in having obtained my undergraduate and postgraduate degrees in the 1970s. It was during this period that I began my continuing love affair with this subject, and the fact that it happened while I was a student in an organic laboratory is beside the point. I was always enchanted by the more physical aspects of inorganic chemistry; while being captivated from an early stage by the synthetic side, and the measure of creation with a small c that it entails, I nevertheless found the application of various theoretical, spectroscopic and physicochemical techniques to inorganic compounds to be fascinating, stimulating, educational and downright exciting. The various bonding theories, for example, and their use to explain or interpret spectroscopic observations were more or less universally accepted as belonging within the realm of inorganic chemistry, and textbooks of the day had whole sections on bonding theories, magnetism, kinetics, electron-transfer mechanisms and so on. However, things changed, and subsequent inorganic chemistry teaching texts tended to emphasize the more synthetic and descriptive side of the field. There are a number of reasons for this, and they no doubt include the rise of diamagnetic organometallic chemistry as the dominant subdiscipline within inorganic chemistry and its relative narrowness vis-d-vis physical methods required for its prosecution.
Making And Breaking Symmetry In Chemistry Syntheses Mechanisms And Molecular Rearrangements
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Author : Michael James Mcglinchey
language : en
Publisher: World Scientific
Release Date : 2022-03-09
Making And Breaking Symmetry In Chemistry Syntheses Mechanisms And Molecular Rearrangements written by Michael James Mcglinchey and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-03-09 with Science categories.
The elucidation of reaction mechanisms generally requires the carefully designed control of molecular symmetry to distinguish between the many possible reaction pathways. Making and Breaking Symmetry in Chemistry emphasises the crucial role played by symmetry in modern synthetic chemistry. After discussion of a number of famous classical experiments, the advances brought about by the introduction of new techniques, in particular NMR spectroscopy, are exemplified in numerous cases taken from the recent literature. Experimental verification of many of the predictions made in Woodward and Hoffmann's explication of the Conservation of Orbital Symmetry are described. Applications that involve the breaking of molecular symmetry to resolve these and other mechanistic problems in organic, inorganic and organometallic chemistry are presented in the first sections of the book, together with many examples of the detection of hitherto hidden rearrangement processes.Subsequently, under the aegis of making molecular symmetry, examples of the preparation of highly symmetrical molecules found in the organic, organometallic or inorganic domains are discussed. These include Platonic hydrocarbons or boranes, tetrahedranes, cubanes, prismanes, dodecahedrane, fullerene fragments such as corannulene, sumanene or semibuckminsterfullerene, and other systems of unusual geometries or bonding characteristics (Möbius strips, molecular brakes and gears, Chauvin's carbomers, Fitjer's rotanes, persubstituted rings, metal-metal multiple bonds, etc.). The text also contains vignettes of many of the scientists who made these major advances, as well as short sections that briefly summarise key features of important topics that underpin the more descriptive material. These include some aspects of chirality, NMR spectroscopy, and the use of isotopic substitution to break molecular symmetry. A brief appendix on point group symmetry and nomenclature is also helpfully provided.
Coordination Compounds
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Author : Ramanee D. Wijesekera
language : en
Publisher: Alpha Science International, Limited
Release Date : 2008
Coordination Compounds written by Ramanee D. Wijesekera and has been published by Alpha Science International, Limited this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008 with Science categories.
Organised in a way that students will find both understandable and enjoyable, this book comprehensively covers important topics in Inorganic Chemistry for undergraduates.