Synthetic Multidentate Macrocyclic Compounds
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Synthetic Multidentate Macrocyclic Compounds
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Author : Reed Izatt
language : en
Publisher: Elsevier
Release Date : 2012-12-02
Synthetic Multidentate Macrocyclic Compounds written by Reed Izatt and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
Synthetic Multidentate Macrocyclic Compounds attempts to bring together selected chapters in which the authors discuss in depth investigations in important areas of macrocycle research. The chapters deal mainly with macrocyclic compounds (saturated polyethers and their derivatives), and macrobicyclic compounds (cryptates). The book contains six chapters and opens with a first-hand account of the initial synthesis of the cyclic polyethers. This is followed by separate chapters on the synthesis of cyclic polyethers, polyether amines, and polyether sulfides; the synthesis of multidentate compounds; and the structure of synthetic macrocyclic compounds and their cation complexes. Subsequent chapters deal with the rates of reactions and the mechanism by which synthetic macrocyclic ligands complex substrates in solution; and commercial applications of the synthetic macrocyclic ligands. This book is primarily aimed at researchers and students in organic, physical, analytical, and inorganic chemistry, and in chemical engineering. However, it will also be of interest to many in the areas of biology, biochemistry, and physiology. Extensive literature references are found in each chapter.
Host Guest Complex Chemistry Macrocycles
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Author : F. Vögtle
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Host Guest Complex Chemistry Macrocycles written by F. Vögtle and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
The scientific and practical interest in coronands (crown ethers), cryptands, podands as complexing agents for cations as well as for anions and neutral low molecular species is undeniable 1,2). The chemistry of crown compounds is steadily increasing. About 250 original papers dealing with crown chemistry appeared only in 1980. New molecules· with crown ether properties are constantly synthesized and new applications discov,?red. Owing to lack of space, only a small number of the original publications is men tioned here. Thus, in the literature compilation only some, but relevant works are selected for each chapter. Whenever possible, reference is made to reviews or review-like articles alone by means of which origin,al works can be consulted. The reviews given under ref. 1) are considered to be the most relevant. The formulae presented in the figures should be understood as representative structures outlining a specific field. 2 Classification of Oligo-/Multidentate Neutral Ligands and of their Complexes Today, a distinction is made between the classical ring oligoethers (crown ethers) and monocyclic coronands, oligocyclic spherical cryptands and the acyclic podands with respect to topological aspects 3). This classification and the topology are illustrated in Fig. 1, each figure representing the minimum number of donor atoms and chain segments characteristic of each class of compounds. Multidentate mono cyclic ligands with any type of donor atoms are called coronands ("crown compounds"), while the term crown ether should be reserved for cyclic oligoethers exclusively containing oxygen as donor atom.
Coordination Chemistry Of Macrocyclic Compounds
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Author : Gordon Melson
language : en
Publisher: Springer
Release Date : 1979-10
Coordination Chemistry Of Macrocyclic Compounds written by Gordon Melson and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1979-10 with Science categories.
Chemists have been aware of the existence of coordination compounds con taining organic macrocyclic ligands since the first part of this century ; however, only during the past few years have they expanded research into the chemistry of these compounds. The expansion was initiated in the early 1960s by the synthesis and characterization of compounds containing some new macrocyclic ligands. The synthesis of compounds which may serve as model systems for some natural products containing large rings as ligands provided the main goal for the early expansion of research effort; indeed, a recurrent theme behind much of the reported chemistry has been the analogy between synthetic macrocyclic compounds and many natural-product systems. More recently, the emphases of reported research have ranged over the whole spectrum of chemistry, and the number of publications that discuss macrocyclic chemistry has increased at a dramatic rate. The completed research has been reported in a variety of journals throughout the world but there has been no previous attempt to bring the major developments together under one cover. This book, therefore, attempts to satisfy the need for a single source in which there is both a collection and a correlation of information concerning the coordination chemistry of macrocyclic compounds. The chapters in this book discuss various aspects of macrocyclic chemistry, and while these chapters as a whole constitute an in-depth survey of the state-of the-art of the field, each chapter is written as a complete unit.
Coordination Chemistry Of Macrocyclic Compounds
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Author : Gordon Melson
language : en
Publisher:
Release Date : 1979-10-01
Coordination Chemistry Of Macrocyclic Compounds written by Gordon Melson and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1979-10-01 with categories.
Coordination And Transport Properties Of Macrocyclic Compounds In Solution
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Author : Brian G. Cox
language : en
Publisher: Elsevier Publishing Company
Release Date : 1992
Coordination And Transport Properties Of Macrocyclic Compounds In Solution written by Brian G. Cox and has been published by Elsevier Publishing Company this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992 with Science categories.
This book covers the fundamental physical principles of the selective complexation, extraction, and transport of ions and molecules by macrocyclic compounds - both natural and synthetic. It also treats the use of these compounds for the extraction and transport of substrates in chemical and biological systems. Included are solution kinetic and thermodynamic properties of the complexes, along with relevant experimental methods, complemented by solution and solid-state structures. General and specific methods for the synthesis of macro(poly)cyclic specialised ligands are described. The book is useful as additional reading for undergraduate courses in chemistry (e.g. inorganic complexation chemistry, analytical chemistry, solution kinetics, synthesis) and biochemistry (ion transport/membrane phenomena); for graduate students in chemistry and biochemistry; for research workers in macrocyclic chemistry and biophysical chemistry; and for industrial laboratories involved in metal ion extraction and recovery.
Template Synthesis Of Macrocyclic Compounds
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Author : N. V. Gerbeleu
language : en
Publisher: John Wiley & Sons
Release Date : 2008-07-11
Template Synthesis Of Macrocyclic Compounds written by N. V. Gerbeleu and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-07-11 with Science categories.
The synthesis of macrocycles is an art in itself. Template-controlled synthesis provides elegant access to fascinating macrocyclic structures. Polyazamacrocycles, crown ethers, cryptands, rotaxanes, knots -- the range of macrocyclic compounds is as broad as their potential application as molecular switches, in ion exchange, electron transfer or catalysis. This book provides authoritative information on all aspects of template-controlled macrocyclizations. It covers in depth the current state of research on template processes - novel synthetic techniques and mechanistic approaches. The critical discussion of the diverse synthetic routes includes the detailed characterization of the broad variety of macrocyclic products. References to applications of macrocyclic compounds and over 1,500 citations make this handbook an indispensable tool for chemists in academia and industry. Researchers in organic and supramolecular chemistry, biotechnology, and inorganic chemistry will find inspiration for the design, synthesis, and myriad uses of new synthetic macrocycles.
Coordination Chemistry Of Macrocyclic Compounds
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Author : Edwin C. Constable
language : en
Publisher:
Release Date : 2006
Coordination Chemistry Of Macrocyclic Compounds written by Edwin C. Constable and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006 with Coordination compounds categories.
This primer describes the coordination chemistry of macrocyclic ligands. Common types of ligands are introduced and strategies for the synthesis of the free ligands and their metal complexes are discussed.
Synthetic Coordination And Organometallic Chemistry
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Author : Alexandr D. Garnovskii
language : en
Publisher: CRC Press
Release Date : 2003-04-25
Synthetic Coordination And Organometallic Chemistry written by Alexandr D. Garnovskii and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-04-25 with Science categories.
This reference offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system.
Coordination Chemistry Of Macrocyclic Compounds
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Author : Gordon Melson
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Coordination Chemistry Of Macrocyclic Compounds written by Gordon Melson and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Chemists have been aware of the existence of coordination compounds con taining organic macrocyclic ligands since the first part of this century ; however, only during the past few years have they expanded research into the chemistry of these compounds. The expansion was initiated in the early 1960s by the synthesis and characterization of compounds containing some new macrocyclic ligands. The synthesis of compounds which may serve as model systems for some natural products containing large rings as ligands provided the main goal for the early expansion of research effort; indeed, a recurrent theme behind much of the reported chemistry has been the analogy between synthetic macrocyclic compounds and many natural-product systems. More recently, the emphases of reported research have ranged over the whole spectrum of chemistry, and the number of publications that discuss macrocyclic chemistry has increased at a dramatic rate. The completed research has been reported in a variety of journals throughout the world but there has been no previous attempt to bring the major developments together under one cover. This book, therefore, attempts to satisfy the need for a single source in which there is both a collection and a correlation of information concerning the coordination chemistry of macrocyclic compounds. The chapters in this book discuss various aspects of macrocyclic chemistry, and while these chapters as a whole constitute an in-depth survey of the state-of the-art of the field, each chapter is written as a complete unit.
The Chemistry Of Macrocyclic Ligand Complexes
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Author : L. F. Lindoy
language : en
Publisher: Cambridge University Press
Release Date : 1989-03-23
The Chemistry Of Macrocyclic Ligand Complexes written by L. F. Lindoy and has been published by Cambridge University Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1989-03-23 with Science categories.
The study of macrocyclic ligand systems represents a major activity impinging on a wide range of areas in chemistry and biochemistry. This book contains an overview of the macrocyclic ligand systems and discusses the structure and properties of macrocyclic systems; the synthesis of macrocycles; polyether crown and related systems; metal-ion and molecular recognition (host-guest chemistry); and kinetic, thermodynamic, and electrochemical aspects of these complexes. The author also covers the various categories of synthetic and naturally occuring macrocycles.