The Chemistry Of Tributyl Phosphate

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The Chemistry Of Tributyl Phosphate

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Author : L. L. Burger
language : en
Publisher:
Release Date : 1955

The Chemistry Of Tributyl Phosphate written by L. L. Burger and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1955 with Chemistry categories.

Science And Tech Tributyl Phosp Part A

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Author : Leland L. Burger
language : en
Publisher: Springer
Release Date : 1987-02-28

Science And Tech Tributyl Phosp Part A written by Leland L. Burger and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1987-02-28 with Science categories.

The Chemistry Of Tributyl Phosphate At Elevated Temperatures In The Plutonium Finishing Plant Process Vessels

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Author :
language : en
Publisher:
Release Date : 1994

The Chemistry Of Tributyl Phosphate At Elevated Temperatures In The Plutonium Finishing Plant Process Vessels written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994 with categories.

Potentially violent chemical reactions of the tributyl phosphate solvent used by the Plutonium Finishing Plant at the Hanford Site were investigated. There is a small probability that a significant quantity of this solvent could be accidental transferred to heated process vessels and react there with nitric acid or plutonium nitrate also present in the solvent extraction process. The results of laboratory studies of the reactions show that exothermic oxidation of tributyl phosphate by either nitric acid or actinide nitrates is slow at temperatures expected in the heated vessels. Less than four percent of the tributyl phosphate will be oxidized in these vented vessels at temperatures between 125°C and 250°C because the oxidant will be lost from the vessels by vaporization or decomposition before the tributyl phosphate can be extensively oxidized. The net amounts of heat generated by oxidation with concentrated nitric acid and with thorium nitrate (a stand-in for plutonium nitrate) were determined to be about -150 and -220 joules per gram of tributyl phosphate initially present, respectively. This is not enough heat to cause violent reactions in the vessels. Pyrolysis of the tributyl phosphate occurred in these mixtures at temperatures of 110°C to 270°C and produced mainly 1-butene gas, water, and pyrophosphoric acid. Butene gas generation is slow at expected process vessel temperatures, but the rate is faster at higher temperatures. At 252°C the rate of butene gas generated was 0.33 g butene/min/g of tributyl phosphate present. The measured heat absorbed by the pyrolysis reaction was 228 J/g of tributyl phosphate initially present (or 14.5 kcal/mole of tributyl phosphate). Release of flammable butene gas into process areas where it could ignite appears to be the most serious safety consideration for the Plutonium Finishing Plant.

Some Factors Influencing The Use Of Tributyl Phosphate For The Extraction Of Uranium In Analysis

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Author : T. W. Bartlett
language : en
Publisher:
Release Date : 1951

Some Factors Influencing The Use Of Tributyl Phosphate For The Extraction Of Uranium In Analysis written by T. W. Bartlett and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1951 with Chemistry categories.

Sci Tech Tributyl Phosphate Extraction Water Acids

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Author : A. Steven Kertes
language : en
Publisher: CRC-Press
Release Date : 1990-11-30

Sci Tech Tributyl Phosphate Extraction Water Acids written by A. Steven Kertes and has been published by CRC-Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990-11-30 with Science categories.

Literature Search

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Author : Robert H. Ellerhorst
language : en
Publisher:
Release Date : 1958

Literature Search written by Robert H. Ellerhorst and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1958 with Kerosene categories.

The Esters Of The Acids Of Phosphorus As Solvents

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Author : L. L. Burger
language : en
Publisher:
Release Date : 1957

The Esters Of The Acids Of Phosphorus As Solvents written by L. L. Burger and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1957 with Chemistry categories.

Sci Tech Tributyl Phosp Appl Tbp In Nuc Fuel

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Author : Leland L. Burger
language : en
Publisher: CRC-Press
Release Date : 1989-11-30

Sci Tech Tributyl Phosp Appl Tbp In Nuc Fuel written by Leland L. Burger and has been published by CRC-Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1989-11-30 with Science categories.

Science And Technology Of Tributyl Phosphate Selected Technical And Industrial Uses

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Author :
language : en
Publisher:
Release Date : 1987

Science And Technology Of Tributyl Phosphate Selected Technical And Industrial Uses written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1987 with Tributyl phosphate categories.

Science And Tech Tributyl Phosp

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Author : Wallace W. Schulz
language : en
Publisher: CRC-Press
Release Date : 2000-12-01

Science And Tech Tributyl Phosp written by Wallace W. Schulz and has been published by CRC-Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-12-01 with Science categories.