Transition Metal Carbonyl Cluster Chemistry


Transition Metal Carbonyl Cluster Chemistry
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Transition Metal Carbonyl Cluster Chemistry


Transition Metal Carbonyl Cluster Chemistry
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Author : Paul J. Dyson
language : en
Publisher: CRC Press
Release Date : 2018-10-03

Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-10-03 with Science categories.


Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.



The Chemistry Of Metal Cluster Complexes


The Chemistry Of Metal Cluster Complexes
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Author : Duward F. Shriver
language : en
Publisher: Wiley-VCH
Release Date : 1990

The Chemistry Of Metal Cluster Complexes written by Duward F. Shriver and has been published by Wiley-VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990 with Science categories.


Seven chapters summarize the current status of organometallic cluster chemistry from the viewpoints of synthesis, structure and bonding, ligand substitution reactions, ligand transformations, polyhedral rearrangement, cluster fragmentation reactions, and metal clusters as homogeneous catalysts. An eighth provides an extensive bibliography of reviews for the period from 1965 to 1988. Annotation copyrighted by Book News, Inc., Portland, OR



Cluster Chemistry


Cluster Chemistry
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Author : Guillermo Gonzalez-Moraga
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-11-09

Cluster Chemistry written by Guillermo Gonzalez-Moraga and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-09 with Science categories.


Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.



Transition Metal Clusters


Transition Metal Clusters
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Author : Brian Frederick Gilbert Johnson
language : en
Publisher: John Wiley & Sons
Release Date : 1980

Transition Metal Clusters written by Brian Frederick Gilbert Johnson and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 1980 with Science categories.




Introduction To Cluster Chemistry


Introduction To Cluster Chemistry
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Author : D. M. P. Mingos
language : en
Publisher:
Release Date : 1990

Introduction To Cluster Chemistry written by D. M. P. Mingos and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990 with Science categories.




Metal Metal Bonds And Clusters In Chemistry And Catalysis


Metal Metal Bonds And Clusters In Chemistry And Catalysis
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Author : John P. Fackler Jr.
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-11-22

Metal Metal Bonds And Clusters In Chemistry And Catalysis written by John P. Fackler Jr. and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-22 with Science categories.


This book contains a series of papers and abstracts from the 7th Industry-University Cooperative Chemistry Program symposium held in the spring of 1989 at Texas A&M University. The symposium was larger than previous IUCCP symposia since it also celebrated the 25 years that had elapsed since the initial discovery by F. A. Cotton and his co-workers of the existence of metal-metal quadruple bonds. Cotton's discovery demonstrated that multiple bonding in inorganic systems is not governed by the same constraints observed in organic chemistry regarding s and p orbital involvement. The d orbitals are involved in the multiple bonding description. The quadruple bond involves considerable d orbital overlap between adjacent metal centers. Part I of this series of papers focuses upon the impact of this discovery and describes further contributions to the development of the field. Multiple metal-metal bonding now is known to permeate broad areas of transition metal chemistry. The understanding of metal-metal bonding that developed as a result of the discovery of multiple metal-metal bonding awakened a new chemistry involving metal clusters. Clusters were defined by Cotton to be species containing metal-metal bonding. Clusters in catalysis therefore seemed a logical grouping of papers in this symposium. Clusters play an every increasing role in the control of chemical reactions. Part II of this book describes some of the interesting new developments in this field. In Part III the papers examine the role clusters play in describing and understanding solid state materials.



Metal Metal Bonded Carbonyl Dimers And Clusters


Metal Metal Bonded Carbonyl Dimers And Clusters
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Author : Catherine E. Housecroft
language : en
Publisher:
Release Date : 2007

Metal Metal Bonded Carbonyl Dimers And Clusters written by Catherine E. Housecroft and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007 with Carbonyl compounds categories.


This text is designed in part as a companion volume to the Primer Cluster molecules of the p-block elements. Metal-metal bonded carbonyl dimers and clusters deals with the synthesis, structure, bonding, and reactivity of J-block metal carbonyl compounds and derivatives containing hydride, phosphine, phosphite, and organic ligands as well as clusters containing both transition metal and main group fragments. Like most areas of chemistry, this is a large one and this text is only intended to be an introduction to the field; the reader is guided to several more advanced texts and literature reviews for more in-depth explorations of metal carbonyl dimer and cluster chemistry.



The Interface Of Main Group And Transition Metal Cluster Chemistry


The Interface Of Main Group And Transition Metal Cluster Chemistry
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Author : Kenton Herbert Whitmire
language : en
Publisher:
Release Date : 1988

The Interface Of Main Group And Transition Metal Cluster Chemistry written by Kenton Herbert Whitmire and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with Transition metal compounds categories.




Metal Clusters In Chemistry


Metal Clusters In Chemistry
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Author : Pierre Braunstein
language : en
Publisher: Wiley-VCH
Release Date : 1999

Metal Clusters In Chemistry written by Pierre Braunstein and has been published by Wiley-VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999 with Science categories.


Metal cluster chemistry is at the cutting edge between molecular and solid-state chemistry and has therefore had a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science. The development of new sophisticated synthetic techniques has led to enormous progress in the synthesis of this diverse class of compounds. The number of clusters is growing rapidly, since the possible variations in the metal and ligand sphere are numerous. Modern bonding theories, such as the isolobal principle, have allowed a better understanding of the structures and properties of metal clusters, and thus paved the way for the usage of these versatile materials. Catalysis and nanomaterials are just two of the very promising application-oriented fields. Seventy six contributions, written by world experts in this research field, provide extensive coverage of different aspects of cluster chemistry, ranging from synthesis, structure determination, and dynamics to applications. Up-to-date information, including an impressive collection of structural data and illustrations, extensive coverage of the most important publications of the last decade, and many more features make this three-volume set a complete single-source guide for all researchers working in the area of cluster chemistry.



Gas Phase Inorganic Chemistry


Gas Phase Inorganic Chemistry
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Author : David H. Russell
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Gas Phase Inorganic Chemistry written by David H. Russell and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


The field of gas phase inorganic ion chemistry is relatively new; the early studies date back approximately twenty years, but there has been intense interest and development in the field in the last ten years. As with much of modern chemistry, the growth in gas phase inorganic ion chemistry can be traced to the development of instrumentation and new experimental methods. Studies in this area require sophisticated instruments and sample introduc tion/ ionization methods, and often these processes are complicated by the need for state-selecting (or collisionally stabilizing) the reactive species in order to assign the chemistry unequivocally. At the present level of experimental development, a wide range of experiments on diverse ionic systems are possible and many detailed aspects of the chemistry can be studied. Gas Phase Inorganic Chemistry focuses on the reactions of metal ions and metal clusters, and on the study of these species using the available modern spectroscopic methods. Three of the twelve chapters cover the chemistry of ionic monometal transition metal ions and the chemistry of these species with small diatomics and model organics. Two of the chapters focus on the studies of the chemical and physical properties of (primarily) transition metal clusters, and these chapters review experimental methods and capabilities. Two chapters also deal with the chemistry of transition metal carbonyl clusters, and these chapters address issues important to cluster growth and activation as well as the characterization of such species.