Unimolecular Kinetics
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Comprehensive Chemical Kinetics
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Author : Nicholas Green
language : en
Publisher: Elsevier
Release Date : 2003-11-21
Comprehensive Chemical Kinetics written by Nicholas Green and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-11-21 with Science categories.
Unimolecular reactions are in principle the simplest chemical reactions, because they only involve one molecule. The basic mechanism, in which the competition between the chemical reaction step and a collisional deactivation leads to a pressure-dependent coefficient, has been understood for a long time. However, this is a rapidly developing field, and many new and important discoveries have been made in the past decade. This First Part Part of Two CCK Volumes dealing with Unimolecular Rections, deals with the Reaction Step. The first chapter is an introduction to the whole project, aiming to cover the material necessary to understand the content of the detailed chapters, as well as the history of the development of the area. Chapter 2 is a review of the modern view of the statistical theories, as embodied in the various forms of RRKM theory. Chapter 3 deals with the fully quantum mechanical view of reactive states as resonances. . Presents considerable advances in the field made during the last decade. . Treats both the statistical as well as the fully quantum mechanical view.
Unimolecular Kinetics
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Author :
language : en
Publisher: Elsevier
Release Date : 2019-05-30
Unimolecular Kinetics written by and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-05-30 with Science categories.
Unimolecular Kinetics: Part 2: Collisional Energy Transfer and the Master Equation, Volume 43 in Elsevier’s Comprehensive Molecular Kinetics series, addresses collision energy transfer and the effects it has on gas phase reactions, particularly at low gas density. Such systems include combustion, industrial gas phase processes and atmospheric/environmental processes. The book also discusses The Master Equation to give a good overview of the mechanics underpinning unimolecular kinetics. This new volume will be of interest to researchers investigating gas phase processes which involve unimolecular reactions and the related intermolecular reactions. Discusses collision energy transfer and the effects it has on gas phase reactions Introduces stochastic techniques to energy transfer methods, allowing for an extension of the unimolecular theory beyond simple molecular dissociation Draws an important connection between detailed reaction dynamic studies and the rate of coefficient determination
Unimolecular Reactions
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Author : Kenneth A. Holbrook
language : en
Publisher: John Wiley & Sons
Release Date : 1996-07-10
Unimolecular Reactions written by Kenneth A. Holbrook and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996-07-10 with Science categories.
Representing major advances in this area of gas kinetics in the last twenty-five years, Unimolecular Reactions has been considerably rewritten to include important recent progress in both theory and experiment. New chapters cover the treatment of reactions with 'loose' transition states, the Master equation, and the approximate forms of Statistical Adiabatic Channel Theory. Extensive illustrations highlight both established activation methods and newer techniques such as the use of infrared and UV lasers, overtone excitation, molecular beam experiments and mass spectrometric methods.
Unimolecular Reactions
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Author : Wendell Forst
language : en
Publisher: Cambridge University Press
Release Date : 2003-09-25
Unimolecular Reactions written by Wendell Forst and has been published by Cambridge University Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-09-25 with Science categories.
This textbook covers the basics necessary for understanding the statistical theory of unimolecular reactions in its original and variational, phase-space and angular momentum-conserved incarnations. Because the emphasis is on "why" rather than "how to", there are many problems and answers to explore further. The book is targeted at graduate and advanced undergraduate students studying chemical dynamics, chemical kinetics and theoretical chemistry.
Theory Of Unimolecular Reactions
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Author : Wendell Forst
language : en
Publisher: Elsevier
Release Date : 2012-12-02
Theory Of Unimolecular Reactions written by Wendell Forst and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
Theory of Unimolecular Reactions provides a comprehensive analysis of the theory of unimolecular reactions, also known to kineticists as the Rice-Marcus or the Rice-Ramsperger-Kassel-Marcus theory, and to those working in mass spectrometry and related fields as the quasi-equilibrium theory or the theory of mass spectra. This book demonstrates how theoretical parameters are related to experimental observables and describes the methods that are used to obtain useful numerical answers. This monograph consists of 11 chapters and begins by explaining the derivation of the expression for the basic rate k(E), with emphasis on the unimolecular rate constant, intramolecular energy transfer, and potential energy surfaces in unimolecular reactions. The statistical calculation of unimolecular rate under vibrational potential is also given, along with pertinent degrees of freedom. The remaining chapters explore the energy distribution functions appropriate to each system, the averaging of k(E), and the relations between theoretical and experimental parameters. Thermal reactions, chemical activation systems, and the theory of mass spectra are examined. The last chapter is devoted to the transition state and its ambiguities. This text will be of interest to gas kineticists, mass spectrometrists, and students and researchers working in the field of physical chemistry.
The Theory Of Kinetics
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Author : R.G. Compton
language : en
Publisher: Elsevier
Release Date : 2012-12-02
The Theory Of Kinetics written by R.G. Compton and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
The Theory of Kinetics covers the practice and theory of kinetics and the kinetics of inorganic and organic reactions in gaseous and condensed phases and at interfaces. This text is composed of five chapters and starts with a review of the kinetic characterization of complex reaction systems. The succeeding chapter describes the formal and radical kinetics, as well as the energy factor in chain reactions. These topics are followed by a survey of the theory of the kinetics of elementary gas phase reactions and the unimolecular reaction of activated chemical species. The discussion then shifts to the general properties, reactions, and the theory of elementary reactions in solution. The last chapter examines the theory of kinetics of solid-state reactions. This book is of great value to physical, inorganic, and organic chemists.
Theory Of Unimolecular And Recombination Reactions
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Author : Robert G. Gilbert
language : en
Publisher: Wiley-Blackwell
Release Date : 1990-01-01
Theory Of Unimolecular And Recombination Reactions written by Robert G. Gilbert and has been published by Wiley-Blackwell this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990-01-01 with Science categories.
Selected Readings In Chemical Kinetics
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Author : Margaret H. Back
language : en
Publisher: Elsevier
Release Date : 2013-09-11
Selected Readings In Chemical Kinetics written by Margaret H. Back and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-09-11 with Science categories.
Selected Readings in Chemical Kinetics covers excerpts from 12 papers in the field of general and gas-phase kinetics. The book discusses papers on the laws of connexion between the conditions of a chemical change and its amount; on the reaction velocity of the inversion of the cane sugar by acids; and the calculation in absolute measure of velocity constants and equilibrium constants in gaseous systems. The text then tackles papers on simple gas reactions; on the absolute rate of reactions in condensed phases; on the radiation theory of chemical action; and on the theory of unimolecular reactions. Papers on the theories of unimolecular reactions at low pressures; on the reaction between hydrogen and bromine; and on the oxidation of phosphorus vapor at low pressures are also considered. The book further describes papers on the thermal decomposition of organic compounds from the standpoint of free radicals; as well as on a single chain mechanism for the thermal decomposition of hydrocarbons. The book will be invaluable to students of chemical kinetics.
Principles Of Chemical Kinetics
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Author : Gorden Hammes
language : en
Publisher: Elsevier
Release Date : 2012-12-02
Principles Of Chemical Kinetics written by Gorden Hammes and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
Principles of Chemical Kinetics is devoted to the principles and applications of chemical kinetics. The phenomenology and commonly used theories of chemical kinetics are presented in a critical manner, with particular emphasis on collision dynamics. How and what mechanistic information can be obtained from various experimental approaches is stressed throughout this book. Comprised of nine chapters, this text opens with an overview of reaction rates and their empirical analysis, along with theories of chemical kinetics. The following chapters consider reactions and unimolecular decompositions in the gas phase; chemical reactions in molecular beams; and energy transfer and partitioning in chemical reactions. Kinetics in liquid solutions and fast reactions in liquids are also described. The final chapter looks at the kinetics of enzymes, with particular reference to steady state and transient state kinetics, the pH and temperature dependence of kinetic parameters, and the mechanism underlying enzymatic action. This monograph is intended for students with a general college background in chemistry, physics, and mathematics, and with a typical undergraduate course in physical chemistry.
Chemical Kinetics
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Author : Ralph E. Weston
language : en
Publisher: Prentice Hall
Release Date : 1972
Chemical Kinetics written by Ralph E. Weston and has been published by Prentice Hall this book supported file pdf, txt, epub, kindle and other format this book has been release on 1972 with Science categories.