Adsorption Of Organic Compounds On Electrodes
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Adsorption Of Organic Compounds On Electrodes
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Author : Boris Damaskin
language : en
Publisher: Springer
Release Date : 1971
Adsorption Of Organic Compounds On Electrodes written by Boris Damaskin and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1971 with Science categories.
The systematic study of the adsorption of organic compounds on electrodes began with the comprehensive survey of adsorption on mercury carried out by Gouy in the first decade of this century. His studies with the capillary electrometer are still useful but do not lend themselves to detailed quantitative analysis. A more de tailed study of a few systems by Frumkin in his thesis (1919) led him to propose a quantitative phenomenological theory of organic adsorption (1925, 1926) at almost the same time as Stern proposed the model of the electrical double layer which remains the picture accepted in general terms today. The attempt at a molecular model made by Butler (1929) should be more satisfying but up to the pres ent the formidable difficulties of a molecular theory of interfacial phenomena have prevented the full interpretation of experimental results along these lines. In his work with Proskurnin (1935), Frumkin is also respon sible for the major experimental advance in the demonstration that reliable measurements of the capacity of an electrode-solution interface can be obtained provided that the work is carried out under conditions of scrupulous cleanliness. Even so, preCise mea surements of double layer capacities were not obtained until Grahame (1941) showed how convenient and reliable the dropping mercury electrode was the for these studies. This method and the hanging drop electrode remain the preferred methods for study of adsorp tion on mercury. Solid electrodes present a more difficult problem.
Adsorption Of Organic Compounds On Electrodes
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Author : Boris B. Damaskin
language : en
Publisher:
Release Date : 1981
Adsorption Of Organic Compounds On Electrodes written by Boris B. Damaskin and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1981 with Adsorption categories.
Adsorption Of Organic Compounds On Electrodes
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Author : Boris Damaskin
language : en
Publisher: Springer
Release Date : 1971-04-15
Adsorption Of Organic Compounds On Electrodes written by Boris Damaskin and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1971-04-15 with Science categories.
The systematic study of the adsorption of organic compounds on electrodes began with the comprehensive survey of adsorption on mercury carried out by Gouy in the first decade of this century. His studies with the capillary electrometer are still useful but do not lend themselves to detailed quantitative analysis. A more de tailed study of a few systems by Frumkin in his thesis (1919) led him to propose a quantitative phenomenological theory of organic adsorption (1925, 1926) at almost the same time as Stern proposed the model of the electrical double layer which remains the picture accepted in general terms today. The attempt at a molecular model made by Butler (1929) should be more satisfying but up to the pres ent the formidable difficulties of a molecular theory of interfacial phenomena have prevented the full interpretation of experimental results along these lines. In his work with Proskurnin (1935), Frumkin is also respon sible for the major experimental advance in the demonstration that reliable measurements of the capacity of an electrode-solution interface can be obtained provided that the work is carried out under conditions of scrupulous cleanliness. Even so, preCise mea surements of double layer capacities were not obtained until Grahame (1941) showed how convenient and reliable the dropping mercury electrode was the for these studies. This method and the hanging drop electrode remain the preferred methods for study of adsorp tion on mercury. Solid electrodes present a more difficult problem.
Adsorption Of Organic Compounds On Electrodes
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Author : Boris Borisovich Damaskin
language : en
Publisher:
Release Date : 1971
Adsorption Of Organic Compounds On Electrodes written by Boris Borisovich Damaskin and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1971 with Adsorption categories.
Adsorption Of Organic Compounds On Antimony Bismuth And Cadmium Electrodes
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Author : Alar Jänes
language : en
Publisher:
Release Date : 1998
Adsorption Of Organic Compounds On Antimony Bismuth And Cadmium Electrodes written by Alar Jänes and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998 with Electrodes categories.
Adsorption Of Molecules At Metal Electrodes
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Author : Jacek Lipkowski
language : en
Publisher: New York : VCH
Release Date : 1992
Adsorption Of Molecules At Metal Electrodes written by Jacek Lipkowski and has been published by New York : VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992 with Science categories.
Summarizes the past ten years in the field with papers by physicists, chemists, experimentalists, and theorists. Subjects covered include molecular models of organic adsorption at metal-water interfaces, adsorption and two-dimensional phase transitions at electrode surfaces, molecular adsorption at
Adsorption Kinetics Of Some Organic Compounds On Bismuth Single Crystal Electrodes
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Author : Gunnar Nurk
language : en
Publisher:
Release Date : 2003
Adsorption Kinetics Of Some Organic Compounds On Bismuth Single Crystal Electrodes written by Gunnar Nurk and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003 with categories.
Catalytic And Kinetic Waves In Polarography
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Author : Stal G. Mairanovskii
language : en
Publisher: Springer
Release Date : 2013-11-11
Catalytic And Kinetic Waves In Polarography written by Stal G. Mairanovskii and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-11 with Science categories.
As our knowledge of the mechanism of electrode processes increases, it becomes more and more apparent that the kinetic currents first observed by R. Brdicka and by K. Wiesner in the 1940's are very widely encountered. Very many electrode pro cesses contain a chemical stage. * This is true primarily of elec trode processes that involve organic compounds. Therefore, to understand the mechanism of electrode processes and, particular ly, to correctly interpret the results of polarographic investiga tions, it is important to know the characteristics and relationships controlling the chemical reactions taking place at the electrode surface. Generally, these reactions are substantially different from ordinary chemical reactions taking place in the bulk of the solution, since the reactions at the electrodes are often affected by the electric field of the electrode and the adsorption of the par ticipating compounds . The fact that hydrogen ions usuallY take part in the electro chemical reduction of organic compounds makes possible the use of electrochemical methods, particularly polarography, for the study of protolytic reactions. These reactions play an important role in organic chemistry: the majority of reactions of organic compounds in solutions go through a stage in which a hydrogen ion is removed or added (see, for example, [1, 2]). Therefore, the polarographic study of protolytic reactions can supply much important information to theoretical organic chemistry.
Electrosorption
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Author : Eliezer Gileadi
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Electrosorption written by Eliezer Gileadi and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
The gradual emergence during the last decade of the study of the mechanism of electrode reactions from the dark ages has given stimulus to a consideration of the double layer at metal-solution interfaces, which extends far outside the classical experimental studies of the capacitance of the mercury solution interface made during the 1950's by D. C. Grahame at Amherst College, Massachusetts. The central aspect of the study of an electrode reaction is the elucidation of its path and rate-determining step. Two fields are, however, prerequisites for such studies. First, it must be known what species are in the bulk of the solution, for these will seldom be simple ones such as H30~ and this study ("complex ions") has been made with both extent and depth. Second, the occupancy of the surface of the electrocatalyst and the associated field gradients must be known as a function of position in the double layer. Such "maps of the double layer" can be given with reasonable certainty up to concentrations of about 1 N for mercury in contact with solutions of inorganic ions. However, this is-or was until very recently-the extent of the know ledge. The problems confronting a fundamental approach to the rational development of, e.g., fuel cell catalysis were therefore considerable.
Thermodynamic Parameters And Adsorption Kinetics Of Organic Compounds Forming The Compact Adsorption Layer At Bi Single Crystal Electrodes
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Author : Heili Kasuk
language : en
Publisher:
Release Date : 2007
Thermodynamic Parameters And Adsorption Kinetics Of Organic Compounds Forming The Compact Adsorption Layer At Bi Single Crystal Electrodes written by Heili Kasuk and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007 with categories.