Adsorption Of Molecules At Metal Electrodes
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Adsorption Of Molecules At Metal Electrodes
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Author : Jacek Lipkowski
language : en
Publisher: New York : VCH
Release Date : 1992
Adsorption Of Molecules At Metal Electrodes written by Jacek Lipkowski and has been published by New York : VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992 with Science categories.
Summarizes the past ten years in the field with papers by physicists, chemists, experimentalists, and theorists. Subjects covered include molecular models of organic adsorption at metal-water interfaces, adsorption and two-dimensional phase transitions at electrode surfaces, molecular adsorption at
Reactions Of Molecules At Electrodes
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Author : N. S. Hush
language : en
Publisher: John Wiley & Sons
Release Date : 1971
Reactions Of Molecules At Electrodes written by N. S. Hush and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 1971 with Science categories.
Adsorption Of Organic Compounds On Electrodes
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Author : Boris Damaskin
language : en
Publisher: Springer
Release Date : 1971
Adsorption Of Organic Compounds On Electrodes written by Boris Damaskin and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1971 with Science categories.
The systematic study of the adsorption of organic compounds on electrodes began with the comprehensive survey of adsorption on mercury carried out by Gouy in the first decade of this century. His studies with the capillary electrometer are still useful but do not lend themselves to detailed quantitative analysis. A more de tailed study of a few systems by Frumkin in his thesis (1919) led him to propose a quantitative phenomenological theory of organic adsorption (1925, 1926) at almost the same time as Stern proposed the model of the electrical double layer which remains the picture accepted in general terms today. The attempt at a molecular model made by Butler (1929) should be more satisfying but up to the pres ent the formidable difficulties of a molecular theory of interfacial phenomena have prevented the full interpretation of experimental results along these lines. In his work with Proskurnin (1935), Frumkin is also respon sible for the major experimental advance in the demonstration that reliable measurements of the capacity of an electrode-solution interface can be obtained provided that the work is carried out under conditions of scrupulous cleanliness. Even so, preCise mea surements of double layer capacities were not obtained until Grahame (1941) showed how convenient and reliable the dropping mercury electrode was the for these studies. This method and the hanging drop electrode remain the preferred methods for study of adsorp tion on mercury. Solid electrodes present a more difficult problem.
Electrochemistry At Metal And Semiconductor Electrodes
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Author : Norio Sato
language : en
Publisher: Elsevier
Release Date : 1998-10-09
Electrochemistry At Metal And Semiconductor Electrodes written by Norio Sato and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998-10-09 with Science categories.
Electrochemisty at Metal and Semiconductor Electrodes covers the structure of the electrical double layer and charge transfer reactions across the electrode/electrolyte interface. The purpose of the book is to integrate modern electrochemistry and semiconductor physics, thereby, providing a quantitative basis for understanding electrochemistry at metal and semiconductor electrodes. Electrons and ions are the principal particles which play the main role in electrochemistry. This text, therefore, emphasizes the energy level concepts of electrons and ions rather than the phenomenological thermodynamic and kinetic concepts on which most of the classical electrochemistry texts are based. This rationalization of the phenomenological concepts in terms of the physics of semiconductors should enable readers to develop more atomistic and quantitative insights into processes that occur at electrodes. The book incorporates many traditional disciplines of science and engineering such as interfacial chemistry, biochemistry, enzyme chemistry, membrane chemistry, metallurgy, modification of solid interfaces, and materials' corrosion. The text is intended to serve as an introduction for the study of advanced electrochemistry at electrodes and is aimed towards graduates and senior undergraduates studying materials and interfacial chemistry or those beginning research work in the field of electrochemistry.
Electrosorption
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Author : Eliezer Gileadi
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Electrosorption written by Eliezer Gileadi and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
The gradual emergence during the last decade of the study of the mechanism of electrode reactions from the dark ages has given stimulus to a consideration of the double layer at metal-solution interfaces, which extends far outside the classical experimental studies of the capacitance of the mercury solution interface made during the 1950's by D. C. Grahame at Amherst College, Massachusetts. The central aspect of the study of an electrode reaction is the elucidation of its path and rate-determining step. Two fields are, however, prerequisites for such studies. First, it must be known what species are in the bulk of the solution, for these will seldom be simple ones such as H30~ and this study ("complex ions") has been made with both extent and depth. Second, the occupancy of the surface of the electrocatalyst and the associated field gradients must be known as a function of position in the double layer. Such "maps of the double layer" can be given with reasonable certainty up to concentrations of about 1 N for mercury in contact with solutions of inorganic ions. However, this is-or was until very recently-the extent of the know ledge. The problems confronting a fundamental approach to the rational development of, e.g., fuel cell catalysis were therefore considerable.
Modern Aspects Of Electrochemistry
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Author : John O M. Bockris
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-03-09
Modern Aspects Of Electrochemistry written by John O M. Bockris and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-03-09 with Science categories.
The present volume contains five chapters covering areas of contemporary interest in the fields of electrolyte solutions, the state of solvent molecules at electrode surfaces, charged colloid interfaces, surface chemistry of oxide electrodes and electro chemistry, and bioelectrochemistry of charge transfer complexes. The first chapter, by Barthel, Wachter, and Gores, covers the topic of conductance of nonaqueous pro tic and aprotic electro lyte solutions. This field is not only of intrinsic interest in itself, illustrating the important departures of ion-transport behavior in organic solvents from that, more well known, in water, but the information and extensive new data presented in this chapter will be of interest to those working with nonaqueous alkali-metal batteries where the conductivity and ion-association behavior of electrolytes in various solvents other than water is of great importance. The second chapter is devoted to a very fundamental and ubiquitous aspect of electrochemistry of electrodes: the state of solvent molecules, adsorbed and oriented, at their surfaces. The role of solvent adsorption and orientation in double-layer proper ties, it will be recalled, remained poorly understood until the early 1960s. This chapter, by Trasatti, gives a thorough account of the present state of knowledge of solvent orientation at electrode interfaces and of the unsuspected (until recent years) role it plays in properties of the double layer and in determining the potential profile at charged metal surfaces in solution.
In Situ Spectroscopic Studies Of Adsorption At The Electrode And Electrocatalysis
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Author : Shi-Gang Sun
language : en
Publisher: Elsevier
Release Date : 2011-08-11
In Situ Spectroscopic Studies Of Adsorption At The Electrode And Electrocatalysis written by Shi-Gang Sun and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-08-11 with Science categories.
In-Situ Spectroscopic Studies of Adsorption at the Electrode and Electrocatalysis is a new reference on in-situ spectroscopic techniques/applications, fundamentals of electrocatalysis at molecule level, and progresses within electrochemical surface science. Presenting both essential background knowledge at graduate level and original research within the fields of spectroscopy, electrochemistry, and surface science. Featuring 15 chapters by prominent worldwide scholars, based on their recent progress in different aspects of in-situ spectroscopy studies, this book will appeal to a wide audience of scientists. In summary this book is highly suitable for graduates learning basic concepts and advanced applications of in-situ spectroscopy, electrocatalysis and electrode adsorptions. * Written by the most active scientists in the fields of spectroscopy, electrochemistry and surface science* Essential background knowledge for graduate students* A modern reference of cutting-edge scientific research
Structure Of Electrified Interfaces
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Author : Jacek Lipkowski
language : en
Publisher: Wiley-VCH
Release Date : 1993
Structure Of Electrified Interfaces written by Jacek Lipkowski and has been published by Wiley-VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1993 with Science categories.
This second volume in the Frontiers of Electrochemistry series provides a modern description of the metal-solution interface and describes the advances made in interfacial electrochemistry during the past decade. Contributing authors summarize the impact of new ex situ and in situ techniques in studying electrode surfaces, and illustrate the significance of the development of new experimental techniques and the availability of reliable data in the theory of electrified interfaces. The review articles demonstrate how a molecular picture of the interface has emerged from traditional models that treated the solution as a dielectric and metal as an electronic continuum. Annotation copyright by Book News, Inc., Portland, OR
Electrochemical Surface Science
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Author : Manuel P. Soriaga
language : en
Publisher:
Release Date : 1988
Electrochemical Surface Science written by Manuel P. Soriaga and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with Science categories.
Modern Electrochemistry 2a
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Author : John O'M. Bockris
language : en
Publisher: Springer Science & Business Media
Release Date : 2001-01-31
Modern Electrochemistry 2a written by John O'M. Bockris and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001-01-31 with Science categories.
This book had its nucleus in some lectures given by one of us (J. O’M. B. ) in a course on electrochemistry to students of energy conversion at the University of Pennsyl- nia. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all of whom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry which could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importance. Thus, conversion to electrochemically powered transportation systems appears to be an important step by means of which the difficulties of air pollution and the effects of an increasing concentration in the atmosphere of carbon dioxide may be met. Cor- sion is recognized as having an electrochemical basis. The synthesis of nylon now contains an important electrochemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of American organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the United States.