Electrochemistry In Nonaqueous Solutions

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Electrochemistry In Nonaqueous Solutions
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Author : Kosuke Izutsu
language : en
Publisher: John Wiley & Sons
Release Date : 2009-09-22
Electrochemistry In Nonaqueous Solutions written by Kosuke Izutsu and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-09-22 with Science categories.
An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.
Nonaqueous Electrochemistry
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Author : Doron Aurbach
language : en
Publisher: CRC Press
Release Date : 2019-08-30
Nonaqueous Electrochemistry written by Doron Aurbach and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-08-30 with categories.
An examination of applications of electrochemical techniques to many organic and inorganic compounds that are either unstable or insoluble in water. It focuses on the continuing drive toward miniaturization in electronics met by designs for high-energy density batteries (based on nonaqueous systems). It addresses applications to nonaqueous batteries, supercapacitators, highly sensitive reagents, and electroorganic and electroinorganic synthesis.
Electrochemistry In Nonaqueous Solutions
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Author : Kōsuke Izutsu
language : en
Publisher: Wiley-VCH
Release Date : 2002-05-06
Electrochemistry In Nonaqueous Solutions written by Kōsuke Izutsu and has been published by Wiley-VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002-05-06 with Science categories.
Nonaqueous solutions are equally indispensable to electrochemistry. Here, Kosuke Izutsu brilliantly illustrates the numerous aspects of this fascinating topic, whether the focus be on physicochemical processes or analytical methods. The author discusses solvation and solvent effects emphasizing dynamic aspects, important reactions including ionic and supercritical media, as well as advanced techniques in polarography and voltammetry. Throughout, he effortlessly manages to provide a comprehensive overview while also presenting the very latest developments. A number of example applications further enhance the practical value of this book and give it the feel of a reference work. Written for both users and specialists this volume represents a wealth of vital information and belongs on every bookshelf.
Handbook Of Electrochemistry
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Author : Cynthia G. Zoski
language : en
Publisher: Elsevier
Release Date : 2007-02-07
Handbook Of Electrochemistry written by Cynthia G. Zoski and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-02-07 with Science categories.
Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)
A Textbook Of Physical Chemistry Volume 1
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Author : Mandeep Dalal
language : en
Publisher: Dalal Institute
Release Date : 2018-01-01
A Textbook Of Physical Chemistry Volume 1 written by Mandeep Dalal and has been published by Dalal Institute this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-01-01 with Science categories.
An advanced-level textbook of physical chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Physical Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Quantum Mechanics – I: Postulates of quantum mechanics; Derivation of Schrodinger wave equation; Max-Born interpretation of wave functions; The Heisenberg’s uncertainty principle; Quantum mechanical operators and their commutation relations; Hermitian operators (elementary ideas, quantum mechanical operator for linear momentum, angular momentum and energy as Hermition operator); The average value of the square of Hermitian operators; Commuting operators and uncertainty principle(x & p; E & t); Schrodinger wave equation for a particle in one dimensional box; Evaluation of average position, average momentum and determination of uncertainty in position and momentum and hence Heisenberg’s uncertainty principle; Pictorial representation of the wave equation of a particle in one dimensional box and its influence on the kinetic energy of the particle in each successive quantum level; Lowest energy of the particle. Chapter 2. Thermodynamics – I: Brief resume of first and second Law of thermodynamics; Entropy changes in reversible and irreversible processes; Variation of entropy with temperature, pressure and volume; Entropy concept as a measure of unavailable energy and criteria for the spontaneity of reaction; Free energy, enthalpy functions and their significance, criteria for spontaneity of a process; Partial molar quantities (free energy, volume, heat concept); Gibb’s-Duhem equation. Chapter 3. Chemical Dynamics – I: Effect of temperature on reaction rates; Rate law for opposing reactions of Ist order and IInd order; Rate law for consecutive & parallel reactions of Ist order reactions; Collision theory of reaction rates and its limitations; Steric factor; Activated complex theory; Ionic reactions: single and double sphere models; Influence of solvent and ionic strength; The comparison of collision and activated complex theory. Chapter 4. Electrochemistry – I: Ion-Ion Interactions: The Debye-Huckel theory of ion- ion interactions; Potential and excess charge density as a function of distance from the central ion; Debye Huckel reciprocal length; Ionic cloud and its contribution to the total potential; Debye - Huckel limiting law of activity coefficients and its limitations; Ion-size effect on potential; Ion-size parameter and the theoretical mean-activity coefficient in the case of ionic clouds with finite-sized ions; Debye - Huckel-Onsager treatment for aqueous solutions and its limitations; Debye-Huckel-Onsager theory for non-aqueous solutions; The solvent effect on the mobality at infinite dilution; Equivalent conductivity (Λ) vs. concentration c 1/2 as a function of the solvent; Effect of ion association upon conductivity (Debye- Huckel - Bjerrum equation). Chapter 5. Quantum Mechanics – II: Schrodinger wave equation for a particle in a three dimensional box; The concept of degeneracy among energy levels for a particle in three dimensional box; Schrodinger wave equation for a linear harmonic oscillator & its solution by polynomial method; Zero point energy of a particle possessing harmonic motion and its consequence; Schrodinger wave equation for three dimensional Rigid rotator; Energy of rigid rotator; Space quantization; Schrodinger wave equation for hydrogen atom, separation of variable in polar spherical coordinates and its solution; Principle, azimuthal and magnetic quantum numbers and the magnitude of their values; Probability distribution function; Radial distribution function; Shape of atomic orbitals (s,p & d). Chapter 6. Thermodynamics – II: Classius-Clayperon equation; Law of mass action and its thermodynamic derivation; Third law of thermodynamics (Nernest heat theorem, determination of absolute entropy, unattainability of absolute zero) and its limitation; Phase diagram for two completely miscible components systems; Eutectic systems, Calculation of eutectic point; Systems forming solid compounds Ax By with congruent and incongruent melting points; Phase diagram and thermodynamic treatment of solid solutions. Chapter 7. Chemical Dynamics – II: Chain reactions: hydrogen-bromine reaction, pyrolysis of acetaldehyde, decomposition of ethane; Photochemical reactions (hydrogen - bromine & hydrogen -chlorine reactions); General treatment of chain reactions (ortho-para hydrogen conversion and hydrogen - bromine reactions); Apparent activation energy of chain reactions, Chain length; Rice-Herzfeld mechanism of organic molecules decomposition(acetaldehyde); Branching chain reactions and explosions ( H2-O2 reaction); Kinetics of (one intermediate) enzymatic reaction : Michaelis-Menton treatment; Evaluation of Michaelis 's constant for enzyme-substrate binding by Lineweaver-Burk plot and Eadie-Hofstae methods; Competitive and non-competitive inhibition. Chapter 8. Electrochemistry – II: Ion Transport in Solutions: Ionic movement under the influence of an electric field; Mobility of ions; Ionic drift velocity and its relation with current density; Einstein relation between the absolute mobility and diffusion coefficient; The Stokes- Einstein relation; The Nernst -Einstein equation; Walden’s rule; The Rate-process approach to ionic migration; The Rate process equation for equivalent conductivity; Total driving force for ionic transport, Nernst - Planck Flux equation; Ionic drift and diffusion potential; the Onsager phenomenological equations; The basic equation for the diffusion; Planck-Henderson equation for the diffusion potential.
Nonaqueous Electrochemistry
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Author : Doron Aurbach
language : en
Publisher: CRC Press
Release Date : 1999-07-27
Nonaqueous Electrochemistry written by Doron Aurbach and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999-07-27 with Science categories.
An examination of applications of electrochemical techniques to many organic and inorganic compounds that are either unstable or insoluble in water. It focuses on the continuing drive toward miniaturization in electronics met by designs for high-energy density batteries (based on nonaqueous systems). It addresses applications to nonaqueous batteries, supercapacitators, highly sensitive reagents, and electroorganic and electroinorganic synthesis.
Fundamentals Of Electrochemistry
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Author : Vladimir S. Bagotsky
language : en
Publisher: John Wiley & Sons
Release Date : 2005-12-02
Fundamentals Of Electrochemistry written by Vladimir S. Bagotsky and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2005-12-02 with Science categories.
Fundamentals of Electrochemistry provides the basic outline of most topics of theoretical and applied electrochemistry for students not yet familiar with this field, as well as an outline of recent and advanced developments in electrochemistry for people who are already dealing with electrochemical problems. The content of this edition is arranged so that all basic information is contained in the first part of the book, which is now rewritten and simplified in order to make it more accessible and used as a textbook for undergraduate students. More advanced topics, of interest for postgraduate levels, come in the subsequent parts. This updated second edition focuses on experimental techniques, including a comprehensive chapter on physical methods for the investigation of electrode surfaces. New chapters deal with recent trends in electrochemistry, including nano- and micro-electrochemistry, solid-state electrochemistry, and electrocatalysis. In addition, the authors take into account the worldwide renewal of interest for the problem of fuel cells and include chapters on batteries, fuel cells, and double layer capacitors.
Diamond Electrochemistry
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Author : Akira Fujishima
language : en
Publisher: Elsevier
Release Date : 2005
Diamond Electrochemistry written by Akira Fujishima and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2005 with Science categories.
Provides an overview of research in Diamond Electrochemistry, as well as practical applications of diamond electrodes. With chapters written by experts in their respective fields, this book serves as a useful source of information for electrochemists working in physical or analytical chemistry.
An Introduction To Aqueous Electrolyte Solutions
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Author : Margaret Robson Wright
language : en
Publisher: John Wiley & Sons
Release Date : 2007-06-05
An Introduction To Aqueous Electrolyte Solutions written by Margaret Robson Wright and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-06-05 with Science categories.
An Introduction to Aqueous Electrolyte Solutions is a comprehensive coverage of the subject including the development of key concepts and theory that focus on the physical rather than the mathematical aspects. Important links are made between the study of electrolyte solutions and other branches of chemistry, biology, and biochemistry, making it a useful cross-reference tool for students studying this important area of electrochemistry. Carefully developed throughout, each chapter includes intended learning outcomes and worked problems and examples to encourage student understanding of this multidisciplinary subject. * a comprehensive introduction to aqueous electrolyte solutions including the development of key concepts and theories * emphasises the connection between observable macroscopic experimental properties and interpretations made at the molecular level * key developments in concepts and theory explained in a descriptive manner to encourage student understanding * includes worked problems and examples throughout An invaluable text for students taking courses in chemistry and chemical engineering, this book will also be useful for biology, biochemistry and biophysics students required to study electrochemistry.
Computational Electrochemistry
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Author : S. Paddison
language : en
Publisher: The Electrochemical Society
Release Date : 2015-12-28
Computational Electrochemistry written by S. Paddison and has been published by The Electrochemical Society this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-12-28 with Science categories.