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Far From Equilibrium Dynamics Of Chemical Systems


Far From Equilibrium Dynamics Of Chemical Systems
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Thermodynamics And Fluctuations Far From Equilibrium


Thermodynamics And Fluctuations Far From Equilibrium
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Author : John Ross
language : en
Publisher: Springer Science & Business Media
Release Date : 2008-08-06

Thermodynamics And Fluctuations Far From Equilibrium written by John Ross and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-08-06 with Science categories.


Thermodynamics is one of the foundations of science. The subject has been developed for systems at equilibrium for the past 150 years. The story is di?erent for systems not at equilibrium, either time-dependent systems or systems in non-equilibrium stationary states; here much less has been done, even though the need for this subject has much wider applicability. We have been interested in, and studied, systems far from equilibrium for 40 years and present here some aspects of theory and experiments on three topics: Part I deals with formulation of thermodynamics of systems far from equilibrium, including connections to ?uctuations, with applications to n- equilibrium stationary states and approaches to such states, systems with multiple stationary states, reaction di?usion systems, transport properties, andelectrochemicalsystems. Experimentsto substantiatethe formulationare also given. In Part II, dissipation and e?ciency in autonomous and externally forced reactions, including several biochemical systems, are explained. Part III explains stochastic theory and ?uctuations in systems far from equilibrium, ?uctuation–dissipation relations, including disordered systems. We concentrate on a coherent presentation of our work and make conn- tions to related or alternative approaches by other investigators. There is no attempt of a literature survey of this ?eld. We hope that this book will help and interest chemists, physicists, b- chemists, and chemical and mechanical engineers. Sooner or later, we expect this book to be introduced into graduate studies and then into undergraduate studies, and hope that the book will serve the purpose.



Far From Equilibrium Dynamics Of Chemical Systems Proceedings Of The Third International Symposium


Far From Equilibrium Dynamics Of Chemical Systems Proceedings Of The Third International Symposium
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Author : Jerzy Gorecki
language : en
Publisher: World Scientific
Release Date : 1994-10-25

Far From Equilibrium Dynamics Of Chemical Systems Proceedings Of The Third International Symposium written by Jerzy Gorecki and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994-10-25 with categories.


This volume contains invited lectures and selected participants' contributions. The conference was organized by the Institute of Physical Chemistry of the Polish Academy of Sciences.



Non Equilibrium Dynamics In Chemical Systems


Non Equilibrium Dynamics In Chemical Systems
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Author : C. Vidal
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Non Equilibrium Dynamics In Chemical Systems written by C. Vidal and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


Markedly apart from elementary particle physics, another current has been building up and cont i nuous ly growi ng within contemporary phys i cs for severa 1 decades, and even expanding into many other disciplines, especially chemistry, biology and, quite recently, economics. Several reasons account for this: presumably the most impor tant one lies in the fact that, whatever the specific problem, model or material concerned, the same basic mathematical features are always involved. In this way, a general phenomenology has emerged which, unlike thermodynamics, is no longer depen dent upon the details or specifics: what largely prevails is the nonlinear charac ter of the underlying dynamics. Perhaps we are witnessing the emergence of a "non linear physics"--In a way similar to the birth of "quantum physics" in the twen ties - a physics which deals with the general behaviour of systems, whatever they are or may be. Over the past fifteen years, chemical systems evolving sufficiently far from equilibrium have proved to be particularly well fitted to experimental research on nonlinear behaviour: oscillation, multistability, birhythmicity, chaotic evolution, spatial self-organization and hysteresis are displayed by chemical reactions whose number is growing each year. In this volume are collected the lectures, communica tions and posters (abstracts) presented at an international meeting entitled: "Non-Equilibrium Dynamics in Chemical Systems", held in Bordeaux (France), Septem ber 3 rd-lth, 1984.



Far From Equilibrium Dynamics Of Chemical Systems Proceedings Of The Second International Symposium


Far From Equilibrium Dynamics Of Chemical Systems Proceedings Of The Second International Symposium
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Author : J Popielawski
language : en
Publisher: World Scientific
Release Date : 1991-03-29

Far From Equilibrium Dynamics Of Chemical Systems Proceedings Of The Second International Symposium written by J Popielawski and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 1991-03-29 with categories.


The proceedings discuss the theoretical methods used to describe a chemical system which is far from the equilibrium state, and this is illustrated by selected applications. Special attention is paid to very fast chemical reactions and systems in which external or internal noise is present. In particular, the following topics are covered:-the generalized Boltzmann/ Enskog equation for nonequilibrium systems,-stochastic methods for description of noise in chemical systems,-numerical simulations of systems far from equilibrium.



Far From Equilibrium Dynamics Of Chemical Systems


Far From Equilibrium Dynamics Of Chemical Systems
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Author : J. Popielawski
language : en
Publisher:
Release Date : 1991

Far From Equilibrium Dynamics Of Chemical Systems written by J. Popielawski and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1991 with SCIENCE categories.




Statistical Thermodynamics Of Nonequilibrium Processes


Statistical Thermodynamics Of Nonequilibrium Processes
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Author : Joel Keizer
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Statistical Thermodynamics Of Nonequilibrium Processes written by Joel Keizer and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail.



Introduction To Non Equilibrium Physical Chemistry


Introduction To Non Equilibrium Physical Chemistry
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Author : R. P. Rastogi
language : en
Publisher: Elsevier
Release Date : 2007-10-16

Introduction To Non Equilibrium Physical Chemistry written by R. P. Rastogi and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-10-16 with Technology & Engineering categories.


Introduction to Non-equilibrium Physical Chemistry presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems. Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis,Electroosmotic ) and in continuous systems (Thermal diffusion,Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics ,which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix. Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies. Part IV deals with analogous non-equilibrium phenomena occurring in the real systems (Socio-political, Finance and Living systems etc.) for which physico-chemical systems discussed in earlier chapters provide a useful model for development of theories based on non-linear science and science of complexity. - The book provides a critical account of theoretical studies on non-equilibrium phenomenon from region close to equilibrium to far equilibrium - Experimental studies have been reported which provide test of the theories and their limitations - Impacts of the concepts developed in non-equilibrium Physical Chemistry in sociology, economics and other social science and living systems has been discussed



Dynamics Of Hierarchical Systems


Dynamics Of Hierarchical Systems
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Author : John S. Nicolis
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Dynamics Of Hierarchical Systems written by John S. Nicolis and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


The main aim of these lectures is to tri gger the interest of the restless under graduate student of physical, mathematical, engineering, or biological sciences in the new and exciting multidisciplinary area of the evolution of "large-scale" dynamical systems. This text grew out of a synthesis of rather heterogeneous mate rial that I presented on various occasions and in different contexts. For example, from lectures given since 1972 to first- and final-year undergraduate and first year graduate students at the School of Engineering of the University of Patras and from informal seminars offered to an international group of graduate and post doctoral students and faculty members at the University of Stuttgart in the aca demic year 1982-1983. Those who search for rigor or even formality in this book are bound to be rather disappointed. My intention is to start from "scratch" if possible, keeping the rea soning heuristic and tied as closely as possible to physical intuition; I assume as prerequisites just basic knowledge of (classical) physics (at the level of the Berkeley series or the Feynman lectures), calculus, and some elements of probabil ity theory. This does not mean that I intended to write an easy book, but rather to eliminate any difficulty for an eager reader who, in spite of incomplete for malistic training, would like to become acquainted with the physical ideas and con cepts underlying the evolution and dynamics of complex systems.



Dynamical Problems In Soliton Systems


Dynamical Problems In Soliton Systems
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Author : Shozo Takeno
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-03-14

Dynamical Problems In Soliton Systems written by Shozo Takeno and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-03-14 with Social Science categories.


This volume contains most of the papers presented in the oral session of the 7th Kyoto Summer Institute (KSI) . on Dynamical Problems in Soliton Systems, held in Kyoto from August 27 to 31, 1984. Furthermore, it contains contributions of R.K. Bullough, H.H. Chen, A.S. Davydov, and N. Sanchez, who unfortunately could not attend. Thirty-six papers were presented in the oral session and 17 papers in the poster session. The meeting brought together 109 physicists and mathematicians, of which 22 were from abroad (see group photograph). The KSI is an international meeting organized by the Research Institute for Fundamental Physics (RIFP), Kyoto University to discuss various cur re nt problems of fundamental importance in theoretical physics. The 7th KSI was the first international meeting on solitons in Japan. Early in 1983, it was feit in the RIFP that the time was ripe for a conference dealing with problems concerning solitons. The RIFP asked us to organize the confer ence. The Organizing Committee consisted of: R. Hirota (Hiroshima) T. Taniuti (Nagoya) Y.H. Ichikawa (Nagoya) M. Toda (Tokyo) Z. Maki (Kyoto) M. Wadati (Tokyo) N. Yajima (Fukuoka) S. Takeno (Kyoto) Since its discovery, the study of the soliton as a stable particle-like state of nonlinear systems has caught the imagination of physicists and mathemati cians.



Dimensions And Entropies In Chaotic Systems


Dimensions And Entropies In Chaotic Systems
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Author : Gottfried Mayer-Kress
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Dimensions And Entropies In Chaotic Systems written by Gottfried Mayer-Kress and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


These proceedings contain the papers contributed to the International Work shop on "Dimensions and Entropies in Chaotic Systems" at the Pecos River Conference Center on the Pecos River Ranch in Spetember 1985. The work shop was held by the Center for Nonlinear Studies of the Los Alamos National Laboratory. At the Center for Nonlinear Studies the investigation of chaotic dynamics and especially the quantification of complex behavior has a long tradition. In spite of some remarkable successes, there are fundamental, as well as nu merical, problems involved in the practical realization of these algorithms. This has led to a series of publications in which modifications and improve ments of the original methods have been proposed. At present there exists a growing number of competing dimension algorithms but no comprehensive review explaining how they are related. Further, in actual experimental ap plications, rather than a precise algorithm, one finds frequent use of "rules of thumb" together with error estimates which, in many cases, appear to be far too optimistic. Also it seems that questions like "What is the maximal dimension of an attractor that one can measure with a given number of data points and a given experimental resolution?" have still not been answered in a satisfactory manner for general cases.