Fluorination
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Aromatic Fluorination
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Author : James H. Clark
language : en
Publisher: CRC Press
Release Date : 2018-01-10
Aromatic Fluorination written by James H. Clark and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-01-10 with Science categories.
Academia and industry join forces in Aromatic Fluorination, as an expert from each domain contributes to this new text on fluorination of carbocyclic and heterocyclic rings. The book begins with a discussion of fluorine's unique combination of properties, including size, electronic effects, and hydrophobicity, as well as the historical development of its product applications. It explains methods for introducing fluorine into an aromatic ring, focusing on nucleophilic fluorine transfer reactions. The role of catalysts, solvents, and other variables are examined, and the scope and limitations of the methods are discussed. Of particular interest to those working in non-specialist laboratories, Aromatic Fluorination includes detailed descriptions of the new electrophilic routes to fluoroaromatics, in addition to traditional routes and alternative methods involving radical chemistry. Because one of the most important fluorine-containing substituent is CF3, the book explains routes to benzotrifluorides (ArCF3), including traditional industrial methods and modern alternatives employing C-1 halofluorocarbons and other fluoroaliphatics. An alternative to CF3 is CF3S, and several methods of synthesizing aromatic CF3S-containing molecules are described. Since the successful development and diverse applications of aromatic fluorine compounds have led to the search for new compounds and novel substituents, the incorporation of other substituents is also explored. Aromatic Fluorination concludes with discussion of the factors responsible for the successful development of pharmaceutical, agrochemical and liquid crystal applications and the potential for applications in high-performance polymers and other areas. This section also describes in detail important industrial aromatic fluorination processes and the relative merits of different process technologies and their costs.
Direct Fluorination Of Polymers
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Author : A. P. Kharitonov
language : en
Publisher: Nova Publishers
Release Date : 2008
Direct Fluorination Of Polymers written by A. P. Kharitonov and has been published by Nova Publishers this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008 with Science categories.
"In this book fundamental features and industrial applications of the direct fluorination of polymers are reviewed. Direct fluorination of polymers (i.e. treatment of a polymer surface with gaseous fluorine and its mixtures) proceeds at room temperature spontaneously and can be considered as a surface modification process."--BOOK JACKET.
Synthetic Aspects Of The Fluorination Of Organic Compounds
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Author : G. G. Furin
language : en
Publisher: Taylor & Francis US
Release Date : 1991
Synthetic Aspects Of The Fluorination Of Organic Compounds written by G. G. Furin and has been published by Taylor & Francis US this book supported file pdf, txt, epub, kindle and other format this book has been release on 1991 with Science categories.
Fluorine In Organic Chemistry
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Author : Richard D. Chambers
language : en
Publisher: CRC Press
Release Date : 2004
Fluorine In Organic Chemistry written by Richard D. Chambers and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004 with Science categories.
The introduction of carbon-fluorine bonds into organic compounds can profoundly influence their chemical and physical properties when compared to their non-fluorine-containing analogues, leading to a range of man-made materials with highly desirable properties. These molecules are of interest across the wide spectrum of industrial and academic organic chemistry, from pharmaceuticals, through fine and specialty chemicals to polymers. From Prozac to Teflon, many of the most important products of the chemical and life-science industries rely on organic fluorine chemistry for their useful properties. This book covers both the preparative methodologies and chemical properties of partially and highly fluorinated organic systems.
Late Stage Fluorination Of Bioactive Molecules And Biologically Relevant Substrates
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Author : Al Postigo
language : en
Publisher: Elsevier
Release Date : 2018-09-05
Late Stage Fluorination Of Bioactive Molecules And Biologically Relevant Substrates written by Al Postigo and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-09-05 with Science categories.
Late-Stage Fluorination of Bioactive Molecules and Biologically-Relevant Substrates reviews how the use of these techniques on compounds with already known and relevant biological activity can provide new pharmaceutical leads with improved medicinal properties. The fluorination strategies discussed take into account both conventional and novel reagents, including nucleophilic, electrophilic, those of a radical nature, and diverse families of organic compounds, such as (hetero) aromatic rings and aliphatic substrates. Drawing on the authors' expert knowledge, this book provides researchers with a broad set of applicable methods to use in their work. Highlights the latest developments in the field in a concise volume Provides details of key fluorinating reagents across diverse families of organic compounds Explores the current applications and future potential of fluorine in drug development
Fluorination
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Author : Jinbo Hu
language : en
Publisher: Springer
Release Date : 2018-03-01
Fluorination written by Jinbo Hu and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-03-01 with Science categories.
This volume reviews the recent advances in formation of C-F bonds and X-F bonds (X = heteroatom) to produce useful fluorinated molecules for pharmaceuticals, materials and more. Reactions and methods associated with fluorination, including monofluorination, difluorination, trifluorination and other polyfluorination that have emerged within the past few years are systematically discussed. With contributions from front-line researchers in this field from both academia and industry, this book provides a valuable resource for scholars, graduate students as well as professionals.
Selective Fluorination In Organic And Bioorganic Chemistry
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Author : John T. Welch
language : en
Publisher:
Release Date : 1991
Selective Fluorination In Organic And Bioorganic Chemistry written by John T. Welch and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1991 with Language Arts & Disciplines categories.
Contains the proceedings of a symposium in Boston, April 1990, which explored the use of organofluorine compounds to alter the molecular properties of biological systems for industrial or research purposes. Covering theory, the synthesis of compounds, and biological compounds, the 14 papers discuss such topics as bond energies in reactive intermediates, perfluorated alkenes and dienes, and stereocontrolled synthesis. Annotation copyrighted by Book News, Inc., Portland, OR
New Fluorinating Agents In Organic Synthesis
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Author : L.A. Alekseeva
language : en
Publisher: Springer
Release Date : 1989-11-02
New Fluorinating Agents In Organic Synthesis written by L.A. Alekseeva and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1989-11-02 with Science categories.
The book summarizes and gives a critical analysis of the literature on the use of reactive covalent fluorides (organic and inorganic) for the synthesis of fluoroorganic compounds. New methods of using SF4 for the fluorination of complex polyfunctional organic compounds are described. The prospects are shown for the selective fluorinations of complex compounds with non-traditional fluorinating agents (halogen fluorides, XeF2, fluorosulphuranes, N-F- and O-F-containing compounds). The book gives recommendations for the practical use of these fluorides, and typical synthetic procedures. It introduces the beginner to modern methods of fluorination and helps qualified scientists and technologists to choose the optimal methods of synthesis. Using the fluorinating agents described in this book, it is possible to synthesize various fluorine-containing substances.
Fluorination With Antimony Pentafluoride
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Author : Latimer R. Evans
language : en
Publisher:
Release Date : 1947
Fluorination With Antimony Pentafluoride written by Latimer R. Evans and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1947 with Antimony categories.
New Fluorinated Carbons Fundamentals And Applications
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Author : Olga V. Boltalina
language : en
Publisher: Academic Press
Release Date : 2016-09-08
New Fluorinated Carbons Fundamentals And Applications written by Olga V. Boltalina and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-09-08 with Science categories.
New Fluorinated Carbons: Fundamentals and Applications is the second volume in Alain Tressaud’s Progress in Fluorine Science series. This volume provides an overview of cutting-edge research and emerging applications using new fluorinated carbon materials such as fullerenes, carbon nanotubes, polycyclic aromatic molecules, carbon nanofibers, and graphenes. Edited by recognized experts Olga Boltalina and Tsuyoshi Nakajima, this book includes valuable chapters on syntheses, structure analyses, and chemical and physical properties of fluorinated carbons written by leaders in each respective field. The work also explores the diverse practical applications of these functional materials—from energy storage and energy conversion devices to molecular electronics and lubricants. Features contributions by leading experts in the field Includes fundamental and current research on synthesis, chemical, and physical properties of fluorinated carbons Explores practical applications in energy, electronics, and lubricants Examines a range of new fluorinated carbon materials