Fourier Transform Techniques In Chemistry
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Transform Techniques In Chemistry
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Author : P. Griffiths
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Transform Techniques In Chemistry written by P. Griffiths and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
The application of the Fourier transform is being seen to an increasing extent in all branches of chemistry, but it is in the area of chemical analysis that the greatest activity is taking place. Fourier transform infrared and nuclear magnetic resonance spectrometry are already routine methods for obtaining high-sensitivity IR and NMR spectra. Analogous methods are now being developed for mass spectrometry (Fourier transform ion cyclo tron resonance spectrometry) and microwave spectroscopy, and Fourier transform techniques have been successfully applied in several areas of electrochemistry. In addition the fast Fourier transform algorithm has been used for smoothing, interpolation, and more efficient storage of data, and has been studied as a potential method for more efficient identification of samples using pattern recognition techniques. Linear transforms have also been shown to be useful in analytical chemistry. Probably the most important of these is the Hadamard transform, which has been applied in alternative methods for obtaining IR and NMR data at high sensitivity. Even though measurements involving this algorithm will probably not be applied as universally as their Fourier transform ana logs, in the area of pattern recognition application of the Hadamard trans form will in all probability prove more important than application of the Fourier transform.
Fourier Hadamard And Hilbert Transforms In Chemistry
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Author : Alan Marshall
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-06-29
Fourier Hadamard And Hilbert Transforms In Chemistry written by Alan Marshall and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-06-29 with Science categories.
In virtually all types of experiments in which a response is analyzed as a function of frequency (e. g. , a spectrum), transform techniques can significantly improve data acquisition and/or data reduct ion. Research-level nuclear magnet ic resonance and infra-red spectra are already obtained almost exclusively by Fourier transform methods, because Fourier transform NMR and IR spectrometers have been commercially available since the late 1960·s. Similar transform techniques are equally valuable (but less well-known) for a wide range of other chemical applications for which commercial instruments are only now becoming available: for example, the first corrmercial Fourier transform mass spectrometer was introduced this year (1981) by Nicolet Instrument Corporation. The purpose of this volume is to acquaint practicing chemists with the basis, advantages, and applica of Fourier, Hadamard, and Hilbert transforms in chemistry. For tions almost all chapters, the author is the investigator who was the first to apply such methods in that field. The basis and advantages of transform techniques are described in Chapter 1. Many of these aspects were understood and first applied by infrared astronomers in the 1950·s, in order to improve the otherwise unacceptably poor signal-to-noise ratio of their spec tra. However, the computations required to reduce the data were painfully slow, and required a 1 arge computer.
Fourier Transform Techniques In Chemistry
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Author : Royal Society of Chemistry. Analytical Division
language : en
Publisher:
Release Date : 1988
Fourier Transform Techniques In Chemistry written by Royal Society of Chemistry. Analytical Division and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with categories.
Fourier Techniques And Applications
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Author : John F. Price
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Fourier Techniques And Applications written by John F. Price and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Mathematics categories.
The first systematic methods of Fourier analysis date from the early eighteenth century with the work of Joseph Fourier on the problem of the flow of heat. (A brief history is contained in the first paper.) Given the initial tempera ture at all points of a region, the problem was to determine the changes in the temperature distribution over time. Understanding and predicting these changes was important in such areas as the handling of metals and the determination of geological and atmospheric temperatures. Briefly, Fourier noticed that the solution of the heat diffusion problem was simple if the initial temperature dis tribution was sinusoidal. He then asserted that any distri bution can be decomposed into a sum of sinusoids, these being the harmonics of the original function. This meant that the general solution could now be obtained by summing the solu tions of the component sinusoidal problems. This remarkable ability of the series of sinusoids to describe all "reasonable" functions, the sine qua non of Fourier analysis and synthesis, has led to the routine use of the methods originating with Fourier in a great diversity of areas - astrophysics, computing, economics, electrical engineering, geophysics, information theory, medical engineering, optics, petroleum and mineral exploration, quan tum physics and spectroscopy, to name a few.
Fourier Transform Infrared Spectrometry
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Author : Peter R. Griffiths
language : en
Publisher: John Wiley & Sons
Release Date : 2007-03-16
Fourier Transform Infrared Spectrometry written by Peter R. Griffiths and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-03-16 with Science categories.
A bestselling classic reference, now expanded and updated to cover the latest instrumentation, methods, and applications The Second Edition of Fourier Transform Infrared Spectrometry brings this core reference up to date on the uses of FT-IR spectrometers today. The book starts with an in-depth description of the theory and current instrumentation of FT-IR spectrometry, with full chapters devoted to signal-to-noise ratio and photometric accuracy. Many diverse types of sampling techniques and data processing routines, most of which can be performed on even the less expensive instruments, are then described. Extensively updated, the Second Edition: * Discusses improvements in optical components * Features a full chapter on FT Raman Spectrometry * Contains new chapters that focus on different ways of measuring spectra by FT-IR spectrometry, including fourteen chapters on such techniques as microspectroscopy, internal and external reflection, and emission and photoacoustic spectrometry * Includes a new chapter introducing the theory of vibrational spectrometry * Organizes material according to sampling techniques Designed to help practitioners using FT-IR capitalize on the plethora of techniques for modern FT-IR spectrometry and plan their experimental procedures correctly, this is a practical, hands-on reference for chemists and analysts. It's also a great resource for students who need to understand the theory, instrumentation, and applications of FT-IR.
Fourier Transforms In Nmr Optical And Mass Spectrometry
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Author : A.G. Marshall
language : en
Publisher: Elsevier
Release Date : 2016-02-25
Fourier Transforms In Nmr Optical And Mass Spectrometry written by A.G. Marshall and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-02-25 with Science categories.
Written by spectroscopists for spectroscopists, here is a book which is not only a valuable handbook and reference work, but also an ideal teaching text for Fourier transform methods as they are applied in spectroscopy. It offers the first unified treatment of the three most popular types of FT/spectroscopy, with uniform notation and complete indexing of specialized terms. All mathematics is self-contained, and requires only a knowledge of simple calculus. The main emphasis is on pictures and physical analogs rather than detailed algebra. Instructive problems, presented at the end of each chapter, offer extensions of the basic treatment. Solutions are given or outlined for all problems. The book offers a wealth of practical information to spectroscopists. Non-ideal effects are treated in detail: noise (source- and detector-limited); non-linear response; limits to spectrometer performance based on finite detection period, finite data size, mis-phasing, etc. Common puzzles and paradoxes are explained: e.g. use of mathematically complex variables to represent physically real quantities; interpretation of negative frequency signals; on-resonance vs. off-resonance response; interpolation (when it helps and when it doesn't); ultimate accuracy of the data; differences between linearly- and circularly-polarized radiation; multiplex advantage or disadvantage, etc. Chapter 1 introduces the fundamental line shapes encountered in spectroscopy, from a simple classical mass-on-a-spring model. The Fourier transform relationship between the time-domain response to a sudden impulse and the steady-state frequency-domain response (absorption and dispersion spectra) to a continuous oscillation is established and illustrated. Chapters 2 and 3 summarize the basic mathematics (definitions, formulas, theorems, and examples) for continuous (analog) and discrete (digital) Fourier transforms, and their practical implications. Experimental aspects which are common to the signal (Chapter 4) and noise (Chapter 5) in all forms of Fourier transform spectrometry are followed by separate chapters for treatment of those features which are unique to FT/MS, FT/optical, FT/NMR, and other types of FT/spectroscopy. The list of references includes both historical and comprehensive reviews and monographs, along with articles describing several key developments. The appendices provide instant access to FT integrals and fast algorithms as well as a pictorial library of common Fourier transform function pairs. The comprehensive index is designed to enable the reader to locate particular key words, including those with more than one name.
Fourier Transform Infrared Spectroscopy
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Author : Oliver J. Rees
language : en
Publisher:
Release Date : 2010
Fourier Transform Infrared Spectroscopy written by Oliver J. Rees and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010 with Fourier transform infrared spectroscopy categories.
Fourier Transform Infrared Spectroscopy (FTIR) is a powerful tool for identifying types of chemical bonds in a molecule by producing an infrared absorption spectrum that is like a molecular "fingerprint". FTIR is most useful for identifying chemicals that are either organic or inorganic. It can be utilised to quantitate some components of an unknown mixture, as well as to the analysis of solids, liquids, and gasses. This book presents topical research in the field of FTIR including an overview of recent applications of FTIR spectroscopy in combination with chemometrics in the analysis of various quality parameters of fats and oils, a modified FTIR method for the analysis of various structural dynamic problems and energetic materials on surfaces.
Fourier Transform
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Author : Salih Salih
language : en
Publisher: BoD – Books on Demand
Release Date : 2012-05-23
Fourier Transform written by Salih Salih and has been published by BoD – Books on Demand this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-05-23 with Computers categories.
The field of material analysis has seen explosive growth during the past decades. Almost all the textbooks on materials analysis have a section devoted to the Fourier transform theory. For this reason, the book focuses on the material analysis based on Fourier transform theory. The book chapters are related to FTIR and the other methods used for analyzing different types of materials. It is hoped that this book will provide the background, reference and incentive to encourage further research and results in this area as well as provide tools for practical applications. It provides an applications-oriented approach to materials analysis written primarily for physicist, Chemists, Agriculturalists, Electrical Engineers, Mechanical Engineers, Signal Processing Engineers, and the Academic Researchers and for the Graduate Students who will also find it useful as a reference for their research activities.
Pulse And Fourier Transform Nmr
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Author : Thomas Clark Farrar
language : en
Publisher: Academic Press
Release Date : 1971-08-28
Pulse And Fourier Transform Nmr written by Thomas Clark Farrar and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1971-08-28 with Mathematics categories.
Pulse and Fourier Transform NMR: Introduction to Theory and Methods presents the different types of pulse experiments that are commonly used and provides the theoretical background necessary for understanding these techniques. This book evaluates the practical application of pulse methods and the necessary instrumentation. Organized into seven chapters, this book begins with an overview of the NMR fundamentals and the basic pulse methods. This text then summarizes the important features of pulse spectrometers. Other chapters consider the rationale, the advantages, and the limitations of Fourier transform NMR methods. This book discusses as well how the idea of the rotating frame can be utilized to understand certain experiments that extend the range of application of pulse methods. The final chapter deals with a few significant special uses of pulse techniques. This book is a valuable resource for chemists and readers who are familiar with high resolution NMR but with no background in pulse methods.
Fourier Transform N M R Spectroscopy
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Author : Derek Shaw
language : en
Publisher: Elsevier Publishing Company
Release Date : 1984
Fourier Transform N M R Spectroscopy written by Derek Shaw and has been published by Elsevier Publishing Company this book supported file pdf, txt, epub, kindle and other format this book has been release on 1984 with Fourier transform spectroscopy categories.
Now reprinted and available in paperback, this book is a comprehensive guide to the theory and practice of NMR spectroscopy in its many forms. It presents the whole range of Fourier Transform NMR techniques, including 2D NMR and NMR imaging. The first three chapters cover the basic physics of magnetic resonance and the mathematical background to Fourier techniques. The following chapters concentrate on pulsed NMR spectroscopy, including the new multipulse sequences, from a theoretical and practical approach. The final chapters deal with the important topic of nuclear relaxation and the novel technique of 2D NMR. The principles of NMR imaging are discussed in detail including medical applications. Containing a wealth of information on techniques and methods, the book provides the reader with a sound base from which to apply Fourier NMR techniques to the many areas of science where they are proving of most value. It is a must for undergraduate and postgraduate students in chemistry and physics, medical students involved in imaging and radiology, NMR spectrometer and NMR imaging manufacturers, and NMR research scientists.