Industrial Applications Of Homogeneous Catalysis
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Industrial Applications Of Homogeneous Catalysis
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Author : A. Mortreux
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Industrial Applications Of Homogeneous Catalysis written by A. Mortreux and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Catalysts are now widely used in both laboratory and industrial-scale chemistry. Indeed, it is hard to find any complex synthesis or industrial process that does not, at some stage, utilize a catalytic reaction. The development of homogeneous transition metal catalysts on the laboratory scale has demonstrated that these systems can be far superior to the equivalent heterogeneous systems, at least in terms of selectivity. is an increasing interest in this field of research from both an Thus, there academic and industrial point of view. In connection with the rapid developments in this area, four universities from the E.E.C (Aachen, FRG; Liege, Belgium; Milan, Italy; and Lille, France) have collaborated to organise a series of seminars for high-level students and researchers. These meetings have been sponsored by the Commission of the E.E.C and state organizations. The most recent of these meetings was held in Lille in September 1985 and this book contains updated and expanded presentations of most of the lectures given there. These lectures are concerned with the field of homogeneous transition metal catalysis and its application to the synthesis of organic intermediates and fine chemicals from an academic and industrial viewpoint. The continuing petroleum crisis which began in the early 1970s has given rise to the need to develop new feedstocks for the chemical industry.
Homogeneous Catalysis
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Author : Sumit Bhaduri
language : en
Publisher: John Wiley & Sons
Release Date : 2014-09-11
Homogeneous Catalysis written by Sumit Bhaduri and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-09-11 with Science categories.
Over the last decade, the area of homogeneous catalysis withtransition metal has grown in great scientific interest andtechnological promise, with research in this area earning threeNobel Prizes and filing thousands of patents relating tometallocene and non-metallocene single site catalysts, asymmetriccatalysis, carbon-carbon bond forming metathesis and cross couplingreactions. This text explains these new developments in a unified, cogent, andcomprehensible manner while also detailing earlier discoveries andthe fundamentals of homogeneous catalysis. Serving as a self-studyguide for students and all chemists seeking to gain entry into thisfield, it can also be used by experienced researchers from bothacademia and industry for referring to leading state of the artreview articles and patents, and also as a quick self-study manualin an area that is outside their immediate expertise. The bookfeatures: • Topics including renewable feed stocks (biofuel,glycerol), carbon dioxide based processes (polycarbonates),fluorous solvents, ionic liquid, hydroformylation, polymerization,oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry,homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (casestudies), and examples from proven industrial processes with cleardiscussions on environmental and techno-commercial issues • Extensive references to cutting edge research withapplication potential and leading patents • Tables and illustrations to help explain difficultconcepts
Catalysis
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Author : J.A. Moulijn
language : en
Publisher: Elsevier
Release Date : 1993-09-09
Catalysis written by J.A. Moulijn and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1993-09-09 with Technology & Engineering categories.
Catalysis is a multidisciplinary activity which is reflected in this book. The editors have chosen a novel combination of basic disciplines - homogeneous catalysis by metal complexes is treated jointly with heterogeneous catalysis with metallic and non-metallic solids. The main theme of the book is the molecular approach to industrial catalysis. In the introductory section Chapter 1 presents a brief survey of the history of industrial heterogeneous and homogeneous catalysis. Subsequently, a selection of current industrial catalytic processes is described (Chapter 2). A broad spectrum of important catalytic applications is presented, including the basic chemistry, some engineering aspects, feedstock sources and product utilisation. In Chapter 3, kinetic principles are treated. The section on fundamental catalysis begins with a description of the bonding in complexes and to surfaces (Chapter 4). The elementary steps on complexes and surfaces are described. The chapter on heterogeneous catalysis (5) deals with the mechanistic aspects of three groups of important reactions: syn-gas conversion, hydrogenation, and oxidation. The main principles of metal and metal oxide catalysis are presented. Likewise, the chapter on homogeneous catalysis (6) concentrates on three reactions representing examples from three areas: carbonylation, polymerization, and asymmetric catalysis. Identification by in situ techniques has been included. Many constraints to the industrial use of a catalyst have a macroscopic origin. In applied catalysis it is shown how catalytic reaction engineering deals with such macroscopic considerations in heterogeneous as well as homogeneous catalysis (Chapter 7). The transport and kinetic phenomena in both model reactors and industrial reactors are outlined. The section on catalyst preparation (Chapters 8 and 9) is concerned with the preparation of catalyst supports, zeolites, and supported catalysts, with an emphasis on general principles and mechanistic aspects. For the supported catalysts the relation between the preparative method and the surface chemistry of the support is highlighted. The molecular approach is maintained throughout. The first chapter (10) in the section on catalyst characterization summarizes the most common spectroscopic techniques used for the characterisation of heterogeneous catalysts such as XPS, Auger, EXAFS, etc. Temperature programmed techniques, which have found widespread application in heterogeneous catalysis both in catalyst characterization and simulation of pretreatment procedures, are discussed in Chapter 11. A discussion of texture measurement, theory and application, concludes this section (12). The final chapter (13) gives an outline of current trends in catalysis. Two points of view are adopted: the first one focusses on developments in process engineering. Most often these have their origin in demands by society for better processes. The second point of view draws attention to the autonomous developments in catalysis, which is becoming one of the frontier sciences of physics and chemistry. In this book emphasis is on those reactions catalyzed by heterogeneous and homogeneous catalysts of industrial relevance. The integrative treatment of the subject matter involves many disciplines, consequently, the writing of the book has been a multi-author task. The editors have carefully planned and harmonized the contents of the chapters.
Homogeneous Catalysis
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Author : American Chemical Society
language : en
Publisher:
Release Date : 1968
Homogeneous Catalysis written by American Chemical Society and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1968 with categories.
Homogeneous Catalysis
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Author : George W. Parshall
language : en
Publisher: Wiley-Interscience
Release Date : 1992-08-07
Homogeneous Catalysis written by George W. Parshall and has been published by Wiley-Interscience this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992-08-07 with Science categories.
The broadening technical advances in the production of pharmaceuticals, flavors, and fragrances have more than doubled the industrial applications of soluble transition metal catalysts. Indeed, transition metal catalysts have become an ascendant feature of a heightened academic interest in organometallic chemistry. This Second Edition of the landmark text offers a clear, systematic look at the state-of-the-science of homogeneous catalytic reactions. Focusing on specific processes, rather than principles of coordination or organometallic chemistry, this updated edition is an A-to-Z compilation of the homogeneous catalytic reactions commonly used in industry or that have broad application in the organic synthesis laboratory. Documenting examples of homogeneous catalytic reactions used in current commercial processes, this newest edition features Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol processes for dimerizing propylene as well as Du Pont's hydrocyanation process. Detailed coverage also includes isomerization of simple olefins, mechanism of olefin hydrogenation, oligomerization of olefins, chain transfer catalysis, reactions of carbon monoxide, specialty chemicals, reactions of acetylenes, esterification, polycondensation, and related processes. Featuring the latest findings in its existing coverage on pharmaceuticals, agricultural chemicals, flavors, fragrances, and electronic chemicals, this Second Edition clearly details the science's growing influence and practicality in industry and the lab. Organic and inorganic chemists, instructors, and students will find Homogeneous Catalysis, Second Edition a clear, up-to-date compendium of the catalytic reactionssharpening chemistry's cutting edge.
Homogeneous Catalysis Industrial Applications And Implications
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Author :
language : en
Publisher:
Release Date : 1968
Homogeneous Catalysis Industrial Applications And Implications written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1968 with Catalysis categories.
Catalysis
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Author : Gadi Rothenberg
language : en
Publisher: John Wiley & Sons
Release Date : 2017-09-06
Catalysis written by Gadi Rothenberg and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-09-06 with Science categories.
After the great success now in its 2nd Edition: This textbook covers all aspects of catalysis, including computational methods, industrial applications and green chemistry
Homogeneous Catalysts
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Author : John C. Chadwick
language : en
Publisher: John Wiley & Sons
Release Date : 2011-06-09
Homogeneous Catalysts written by John C. Chadwick and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-06-09 with Science categories.
This first book to illuminate this important aspect of chemical synthesis improves the lifetime of catalysts, thus reducing material and saving energy, costs and waste. The international panel of expert authors describes the studies that have been conducted concerning the way homogeneous catalysts decompose, and the differences between homogeneous and heterogeneous catalysts. The result is a ready reference for organic, catalytic, polymer and complex chemists, as well as those working in industry and with/on organometallics.
Homogeneous Catalysis
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Author : George William Parshall
language : en
Publisher: John Wiley & Sons
Release Date : 1980
Homogeneous Catalysis written by George William Parshall and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 1980 with Science categories.
Contains a balanced discussion of homogeneous catalytic reactions that are used in industry, featuring every documented example employed in a current commercial process, or that have a broad application in the organic synthesis laboratory. Incorporates synthesis with chiral catalysts in chapters on hydrogenation, CO chemistry and olefin oxidation. New additions include Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol process for dimerizing propylene as well as major changes in the areas on pharmaceuticals, flavors, fragrances, agricultural and electronic chemicals.
Homogeneous Catalysis
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Author : Piet W.N.M. van Leeuwen
language : en
Publisher: Springer Science & Business Media
Release Date : 2006-08-02
Homogeneous Catalysis written by Piet W.N.M. van Leeuwen and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-08-02 with Science categories.
No available as softcover No other book available that gives insight into so many reactions of importance, while the field of homogeneous catalysis is becoming more and more important to organic chemists, industrial chemists, and academia. Gives real insight in the many new and old reactions of importance, based on the author's extensive experience in both teaching and industrial practice. Provide background to chemists trained in a different discipline and graduate and masters students who take catalysis as a main or secondary topic.