Lewis Base Catalysis In Organic Synthesis
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Lewis Base Catalysis In Organic Synthesis 3 Volume Set
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Author : Edwin Vedejs
language : en
Publisher: John Wiley & Sons
Release Date : 2016-10-10
Lewis Base Catalysis In Organic Synthesis 3 Volume Set written by Edwin Vedejs and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-10-10 with Science categories.
This three-volume set represents the first comprehensive coverage of the rapidly expanding field of Lewis base catalysis that has attracted enormous attention in recent years. Lewis base catalysis is a conceptually novel paradigm that encompasses an extremely wide variety of preparatively useful transformations and is particularly effective for enantioselectively constructing new stereogenic centers. As electron-pair donors, Lewis bases can influence the rate and stereochemical course of myriad synthetic organic reactions. The book presents the conceptual/mechanistic principles that underlie Lewis base catalysis, and then builds upon that foundation with a thorough presentation of many different reaction types. And last but not least, the editors, Prof. Edwin Vedejs and Prof. Scott E. Denmark, are without doubt the leaders in this emerging field and have compiled high quality contributions from an impressive collection of international experts.
Lewis Base Catalysis In Organic Synthesis
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Author : Edwin Vedejs
language : en
Publisher: John Wiley & Sons
Release Date : 2016-08-03
Lewis Base Catalysis In Organic Synthesis written by Edwin Vedejs and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-08-03 with Science categories.
This three-volume set represents the first comprehensive coverage of the rapidly expanding field of Lewis base catalysis that has attracted enormous attention in recent years. Lewis base catalysis is a conceptually novel paradigm that encompasses an extremely wide variety of preparatively useful transformations and is particularly effective for enantioselectively constructing new stereogenic centers. As electron-pair donors, Lewis bases can influence the rate and stereochemical course of myriad synthetic organic reactions. The book presents the conceptual/mechanistic principles that underlie Lewis base catalysis, and then builds upon that foundation with a thorough presentation of many different reaction types. And last but not least, the editors, Prof. Edwin Vedejs and Prof. Scott E. Denmark, are without doubt the leaders in this emerging field and have compiled high quality contributions from an impressive collection of international experts.
Inventing Reactions
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Author : Lukas J. Gooßen
language : en
Publisher: Springer
Release Date : 2012-10-30
Inventing Reactions written by Lukas J. Gooßen and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-10-30 with Science categories.
Barry Trost: Transition metal catalyzed allylic alkylation.- Jeffrey W. Bode: Reinventing Amide Bond Formation.- Naoto Chatani and Mamoru Tobisu: Catalytic Transformations Involving the Cleavage of C-OMe Bonds.- Gregory L. Beutner and Scott E. Denmark: The Interplay of Invention, Observation and Discovery in the Development of Lewis Base Activation of Lewis Acids for Catalytic Enantioselective Synthesis.- David R. Stuart and Keith Fagnou: The Discovery and Development of a Palladium(II)-Catalyzed Oxidative Cross-Coupling of Two Unactivated Arenes.- Lukas Gooßen and Käthe Gooßen: Decarboxylative Cross-Coupling Reactions.- A. Stephen K. Hashmi: Gold-Catalyzed Organic Reactions.- Ben List: Developing Catalytic Asymmetric Acetalizations.- Steven M. Bischof, Brian G. Hashiguchi, Michael M. Konnick, and Roy A. Periana: The De NovoDesign of CH Bond Hydroxylation Catalysts.- Benoit Cardinal-David, Karl A. Scheidt: Carbene Catalysis: Beyond the Benzoin and Stetter Reactions.- Kenso Soai and Tsuneomi Kawasaki: Asymmetric autocatalysis of pyrimidyl alkanol.- Douglas C. Behenna and Brian M. Stoltz: Natural Products as Inspiration for Reaction Development: Catalytic Enantioselective Decarboxylative Reactions of Prochiral Enolate Equivalents. Hisashi Yamamoto: Acid Catalysis in Organic Synthesis.
Pd H Lewis Base Cooperative Catalysis Confers Asymmetric Allylic Alkylation Of Esters Atom Economy And Stereodivergence
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Author : Mostafa Sayed
language : en
Publisher: OAE Publishing Inc.
Release Date : 2023-04-20
Pd H Lewis Base Cooperative Catalysis Confers Asymmetric Allylic Alkylation Of Esters Atom Economy And Stereodivergence written by Mostafa Sayed and has been published by OAE Publishing Inc. this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-04-20 with Science categories.
The construction of Csp3-Csp3 with high stereoselectivity, even in a stereodivergent way, has been a long-standing theme in organic synthesis. As an atom- and step-economic transformation, transition metal hydride-mediated allylic alkylation of enolizable carbonyl compounds with readily available allenes, alkynes or 1,3-dienes as the unconventional allylating reagents has recently emerged as a promising protocol for the stereoselective construction of Csp3-Csp3 bonds with high efficiency. Due to their less enolizability and weak nucleophilicity, simple esters remain challenging substrates for these coupling reactions. On the other hand, the strategy of metal/organo combined catalysis has recently emerged as one of the wide-ranging disciplines and powerful tools in asymmetric synthesis. Considering the recent achievements of chiral Lewis base catalysis in catalytic asymmetric α-functionalization of esters through a “rebound” mechanism, the cooperative combination of chiral Lewis bases and metal hydride catalysis may offer great opportunities to the aforementioned chemistry. Recently, the groups of Snaddon and Zi have made remarkable progresses in this area through palladium and chiral Lewis base cooperative catalysis.
Asymmetric Organocatalysis
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Author : Benjamin List
language : en
Publisher: Thieme Chemistry
Release Date : 2012
Asymmetric Organocatalysis written by Benjamin List and has been published by Thieme Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012 with Science categories.
Authoritative, broad overview of the field, compiled by 36 experts Critical presentation of the best organocatalytic and related methodologies available today for practical asymmetric synthesis Provides alternative, greener syntheses with simple and easily used catalysts helping avoid the use of expensive and/or toxic metals Asymmetric Organocatalysis 1 comprehensively covers all the catalysts and reactions within the activation modes Lewis base catalysis and Lewis acid catalysis. Typical or general experimental procedures as well as mechanistic, technical and theoretical aspects are included, allowing the reader to clearly see how simple, clean and efficient this chemistry is. This volume is part of a 2-volume set: Science of Synthesis Asymmetric Organocatalysis Workbench Edition Further information about Asymmetric Organocatalysis (including sample pages and the table of contents) General information about Science of Synthesis
Cooperative Catalysis
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Author : René Peters
language : en
Publisher: John Wiley & Sons
Release Date : 2015-04-27
Cooperative Catalysis written by René Peters and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-04-27 with Technology & Engineering categories.
Written by experts in the field, this is a much-needed overview of the rapidly emerging field of cooperative catalysis. The authors focus on the design and development of novel high-performance catalysts for applications in organic synthesis (particularly asymmetric synthesis), covering a broad range of topics, from the latest progress in Lewis acid / Br?nsted base catalysis to e.g. metal-assisted organo catalysis, cooperative metal/enzyme catalysis, and cooperative catalysis in polymerization reactions and on solid surfaces. The chapters are classified according to the type of cooperating activating groups, and describe in detail the different strategies of cooperative activation, highlighting their respective advantages and pitfalls. As a result, readers will learn about the different concepts of cooperative catalysis, their corresponding modes of operation and their applications, thus helping to find a solution to a specific synthetic catalysis problem.
Asymmetric Organocatalysis
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Author : T. D. Beeson
language : en
Publisher:
Release Date : 2012
Asymmetric Organocatalysis written by T. D. Beeson and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012 with Asymmetric synthesis categories.
Cooperative Catalysis
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Author : René Peters
language : en
Publisher: John Wiley & Sons
Release Date : 2015-01-30
Cooperative Catalysis written by René Peters and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-01-30 with Technology & Engineering categories.
Written by experts in the field, this is a much-needed overview of the rapidly emerging field of cooperative catalysis. The authors focus on the design and development of novel high-performance catalysts for applications in organic synthesis (particularly asymmetric synthesis), covering a broad range of topics, from the latest progress in Lewis acid / Brønsted base catalysis to e.g. metal-assisted organo catalysis, cooperative metal/enzyme catalysis, and cooperative catalysis in polymerization reactions and on solid surfaces. The chapters are classified according to the type of cooperating activating groups, and describe in detail the different strategies of cooperative activation, highlighting their respective advantages and pitfalls. As a result, readers will learn about the different concepts of cooperative catalysis, their corresponding modes of operation and their applications, thus helping to find a solution to a specific synthetic catalysis problem.
Asymmetric Organocatalysis Workbench Edition
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Author : Benjamin List
language : en
Publisher: Thieme Chemistry
Release Date : 2012-05-23
Asymmetric Organocatalysis Workbench Edition written by Benjamin List and has been published by Thieme Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-05-23 with Asymmetric synthesis categories.
Authoritative, broad overview of the field, compiled by 74 experts Critical presentation of the best organocatalytic and related methodologies available today for practical asymmetric synthesis Provides alternative, greener syntheses with simple and easily used catalysts helping avoid the use of expensive and/or toxic metals Asymmetric Organocatalysis is the first reference work giving an overview of this dynamic, young field that is rapidly gaining significance for economical and environmentally friendly organic synthesis. It comprehensively covers all the catalysts and reactions within the four distinct activation modes: Bronsted base catalysis, Bronsted acid catalysis, Lewis base catalysis and Lewis acid catalysis. Typical or general experimental procedures as well as mechanistic, technical and theoretical aspects are included, allowing the reader to clearly see how simple, clean and efficient this chemistry is. This 2-volume set consists of: Asymmetric Organocatalysis 1: Lewis Base and Acid Catalysts Asymmetric Organocatalysis 2: Bronsted Base and Acid Catalysts, and Additional Topics Both volumes are also available separately. Further information about Asymmetric Organocatalysis (including sample pages and the table of contents) General information about Science of Synthesis
Frustrated Lewis Pairs
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Author : J. Chris Slootweg
language : en
Publisher: Springer Nature
Release Date : 2020-11-22
Frustrated Lewis Pairs written by J. Chris Slootweg and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-11-22 with Science categories.
This volume highlights the latest research in frustrated Lewis pair (FLP) chemistry and its applications. The contributions present the recent developments of the use of FLPs in asymmetric catalysis, polymer synthesis, homogeneous and heterogeneous catalysis, as well as demonstrating their use as a pedagogical tool. The book will be of interest to researchers in academia and industry alike.