Metal Clusters
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The Chemistry Of Metal Cluster Complexes
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Author : Duward F. Shriver
language : en
Publisher: Wiley-VCH
Release Date : 1990
The Chemistry Of Metal Cluster Complexes written by Duward F. Shriver and has been published by Wiley-VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990 with Science categories.
Seven chapters summarize the current status of organometallic cluster chemistry from the viewpoints of synthesis, structure and bonding, ligand substitution reactions, ligand transformations, polyhedral rearrangement, cluster fragmentation reactions, and metal clusters as homogeneous catalysts. An eighth provides an extensive bibliography of reviews for the period from 1965 to 1988. Annotation copyrighted by Book News, Inc., Portland, OR
Metal Clusters And Their Reactivity
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Author : Zhixun Luo
language : en
Publisher: Springer Nature
Release Date : 2020-10-31
Metal Clusters And Their Reactivity written by Zhixun Luo and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-10-31 with Science categories.
This book discusses current techniques and instrumentation for cluster chemistry. It addresses both the experimental and theoretical aspects of gas-phase metal cluster reactivities, especially those pertaining to pollution removal, energetic reactions and corrosion and anticorrosion. These metal cluster systems have attracted enormous interest as they display a completely new class of physical, chemical, electronic, magnetic and catalytic properties. As these properties change with size and composition, it can thus be understood how their nature evolves from atoms to bulk solids. The book offers readers a basic understanding of the structural chemistry and reactivity of metal clusters in both gas-phase and wet chemistry. Further, the lessons they learn here regarding metal cluster chemistry will prepare researchers for the study of condensed phase dynamics that pertain to wet chemical synthesis, soft-landing deposition and cluster assembly.
Protected Metal Clusters From Fundamentals To Applications
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Author :
language : en
Publisher: Elsevier
Release Date : 2015-09-06
Protected Metal Clusters From Fundamentals To Applications written by and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-09-06 with Technology & Engineering categories.
Protected Metal Clusters: From Fundamentals to Applications surveys the fundamental concepts and potential applications of atomically precise metal clusters protected by organic ligands. As this class of materials is now emerging as a result of breakthroughs in synthesis and characterization that have taken place over the last few years, the book provides the first reference with a focus on these exciting novel nanomaterials, explaining their formation, and how, and why, they play an important role in the future of molecular electronics, catalysis, sensing, biological imaging, and medical diagnosis and therapy. Surveys the fundamental concepts and potential applications of atomically precise metal clusters protected by organic ligands. Provides well-organized, tutorial style chapters that are ideal for teaching and self-study In-depth descriptions by top scientists in the field Presents the state-of-the art of protected metal clusters and their future prospects
Metal Clusters At Surfaces
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Author : Karl-Heinz Meiwes-Broer
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Metal Clusters At Surfaces written by Karl-Heinz Meiwes-Broer and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Due to the interaction with the contact medium, the properties of clusters may change or even disappear. Thus the physics of cluster-on-surface systems -- the main subject of this book -- is of fundamental importance. The book addresses a wide audience, from the newcomer to the expert. Starting from fundamental concepts of adsorbate-surface interactions, the modification of electronic properties through electron confinement, and concepts of cluster production, it elucidates the distinct properties of the new metallic nanostructures.
Metal Clusters
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Author : Frank Träger
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Metal Clusters written by Frank Träger and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
This volume contains papers which have been presented at the International Sym posium on Metal Clusters in Heidelberg from April 7-11, 1986. Clusters, and in particular metal clusters, have been the topic of fa~t growing scientific interest. Indeed, clusters constitute a field of interdisciplinary nature where both physical and chemical questions have to be addressed. Clusters are offundamental importance for the deeper understanding of the transition from atoms via molecules and larger aggregates of particles to the properties of solid materials. Moreover, metal clusters and their character istics are of vital significance for such applied topics as catalysis or photography. Experimentally, the field exhibited rapid progress in the last years. Different sources for clusters have been developed. Intense beams made possible the investigation of free neutral clusters and cluster ions as well. Even though a number of issues concerning metal clusters is still discussed controversially, the present volume tries to give an overview of current work in this field and to illustrate the large variety of experiments as well as the advances made possible by modern theoretical methods. Looking at the many interesting questions still to be addressed it is fair to propose a rapid further growth of this field.
Metal Clusters In Catalysis
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Author : Bruce C. Gates
language : en
Publisher: Elsevier Publishing Company
Release Date : 1986
Metal Clusters In Catalysis written by Bruce C. Gates and has been published by Elsevier Publishing Company this book supported file pdf, txt, epub, kindle and other format this book has been release on 1986 with Science categories.
Research on metal clusters (compounds with metal-metal bonds) has undergone explosive growth and the subject is now perhaps one of the hottest'' topics in organometallic chemistry. The prospect of catalytic applications has motivated a large part of the research mentioned in this book - the long term goal being to exploit the unique properties of metal clusters to prepare catalysts with new activities and selectivities. This is the first book to address the role of metal clusters in catalysis. The coverage is up-to-date and is particularly comprehensive, ranging from molecular chemistry of clusters (synthesis, structure, thermochemistry, reactivity, and homogeneous catalysis) to supported clusters (molecular analogues on polymers, and metal oxides and metals in zeolite cages). Preparation by methods of organometallic surface chemistry and metal atom chemistry and characterization of surface structures by physical methods are highlighted. Concepts unifying metal cluster chemistry and the chemistry of metal surfaces are elucidated. Of particular value to the user will be the cluster and subject indexes. The cluster index is organized in alphabetical order according to the metal.
Clusters And Colloids
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Author : Günter Schmid
language : en
Publisher: John Wiley & Sons
Release Date : 2008-07-11
Clusters And Colloids written by Günter Schmid and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-07-11 with Science categories.
This book offers a comprehensive overview of the rapidly developing field of cluster science. In an interdisciplinary approach, basic concepts as well as recent developments in research and practical applications are authoritatively discussed by leading authors. Topics covered include 'naked' metal clusters, clusters stabilized by ligands, clusters in solids, and colloids. The reader will find answers to questions like: * How many metal atoms must a particle have to exhibit metallic properties? * How can the large specific surface of clusters and colloids be employed in catalysts? * How can metal clusters be introduced into solid hosts? * Which effects are responsible for the transition from isolated to condensed clusters? The editor has succeeded in bringing the contributions of various authors together into a homogeneous, readable book, which will be useful for the academic and industrial reader alike.
Transition Metal Carbonyl Cluster Chemistry
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Author : Paul J. Dyson
language : en
Publisher: CRC Press
Release Date : 2018-10-03
Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-10-03 with Science categories.
Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Ligated Transition Metal Clusters In Solid State Chemistry
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Author : Jean-François Halet
language : en
Publisher: Springer Nature
Release Date : 2019-08-29
Ligated Transition Metal Clusters In Solid State Chemistry written by Jean-François Halet and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-08-29 with Science categories.
This volume dedicated to the memory of Marcel Sergent who was a leader in this field for many years, addresses past achievements and recent developments in this vibrant area of research. Large classes of ligated transition metal clusters are produced either exclusively or most reliably by means of high-temperature solid-state reactions. Among them, the Chevrel-Sergent phases and related materials have generated enormous interest since their discovery in 1971. Today, these materials and their numerous derivatives still constitute a vivid area of research finding some applications not only in superconductivity, but also in catalysis, optics or thermoelectricity to mention a few.
Introduction To Cluster Chemistry
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Author : D. M. P. Mingos
language : en
Publisher:
Release Date : 1990
Introduction To Cluster Chemistry written by D. M. P. Mingos and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990 with Science categories.