Methods For Phase Diagram Determination
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Methods For Phase Diagram Determination
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Author : Ji-Cheng Zhao
language : en
Publisher: Elsevier
Release Date : 2011-05-05
Methods For Phase Diagram Determination written by Ji-Cheng Zhao and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-05-05 with Technology & Engineering categories.
Phase diagrams are "maps" materials scientists often use to design new materials. They define what compounds and solutions are formed and their respective compositions and amounts when several elements are mixed together under a certain temperature and pressure. This monograph is the most comprehensive reference book on experimental methods for phase diagram determination. It covers a wide range of methods that have been used to determine phase diagrams of metals, ceramics, slags, and hydrides.* Extensive discussion on methodologies of experimental measurements and data assessments * Written by experts around the world, covering both traditional and combinatorial methodologies* A must-read for experimental measurements of phase diagrams
Calphad Calculation Of Phase Diagrams A Comprehensive Guide
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Author : N. Saunders
language : en
Publisher: Elsevier
Release Date : 1998-06-09
Calphad Calculation Of Phase Diagrams A Comprehensive Guide written by N. Saunders and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998-06-09 with Technology & Engineering categories.
This monograph acts as a benchmark to current achievements in the field of Computer Coupling of Phase Diagrams and Thermochemistry, often called CALPHAD which is an acronym for Computer CALculation of PHAse Diagrams. It also acts as a guide to both the basic background of the subject area and the cutting edge of the topic, combining comprehensive discussions of the underlying physical principles of the CALPHAD method with detailed descriptions of their application to real complex multi-component materials.Approaches which combine both thermodynamic and kinetic models to interpret non-equilibrium phase transformations are also reviewed.
Phase Diagrams
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Author : Flake C. Campbell
language : en
Publisher: ASM International
Release Date : 2012-01-01
Phase Diagrams written by Flake C. Campbell and has been published by ASM International this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-01-01 with Science categories.
This well-written text is for non-metallurgists and anyone seeking a quick refresher on an essential tool of modern metallurgy. The basic principles, construction, interpretation, and use of alloy phase diagrams are clearly described with ample illustrations for all important liquid and solid reactions. Gas-metal reactions, important in metals processing and in-service corrosion, also are discussed. Get the basics on how phase diagrams help predict and interpret the changes in the structure of alloys.
Phase Equilibria Phase Diagrams And Phase Transformations
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Author : Mats Hillert
language : en
Publisher: Cambridge University Press
Release Date : 2007-11-22
Phase Equilibria Phase Diagrams And Phase Transformations written by Mats Hillert and has been published by Cambridge University Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-11-22 with Technology & Engineering categories.
Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.
Experimental Methods Of Phase Diagram Determination
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Author : J. E. Morral
language : en
Publisher: Tms
Release Date : 1994-01-01
Experimental Methods Of Phase Diagram Determination written by J. E. Morral and has been published by Tms this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994-01-01 with Technology & Engineering categories.
This collection of papers is from Materials Week '93 held in Pittsburgh, Pennsylvania, October 17-21, 1993. Phase diagrams are a construction of phase equilibria data that have applications in both science and technology. The diagrams are available in handbooks for most binary and selected ternary systems and have long been used by materials engineers in alloy and process design. Diagrams for higher order systems are not normally available, which requires engineers to infer the behaviour of complex industrial systems.
Statics And Dynamics Of Alloy Phase Transformations
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Author : Patrice E.A. Turchi
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Statics And Dynamics Of Alloy Phase Transformations written by Patrice E.A. Turchi and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
The study of phase transformations in substitutional alloys, including order disorder phenomena and structural transformations, plays a crucial role in understanding the physical and mechanical properties of materials, and in designing alloys with desired technologically important characteristics. Indeed, most of the physical properties, including equilibrium properties, transport, magnetic, vibrational as well as mechanical properties of alloys are often controlled by and are highly sensitive to the existence of ordered compounds and to the occurrence of structural transformations. Correspondingly, the alloy designer facing the task of processing new high-performance materials with properties that meet specific industrial applications must answer the following question: What is the crystalline structure and the atomic configuration that an alloy may exhibit at given temperature and concentration? Usually the answer is sought in the phase-diagram of a relevant system that is often determined experimentally and does not provide insight to the underlying mechanisms driving phase stability. Because of the rather tedious and highly risky nature of developing new materials through conventional metallurgical techniques, a great deal of effort has been expended in devising methods for understanding the mechanisms contrOlling phase transformations at the microscopic level. These efforts have been bolstered through the development of fully ab initio, accurate theoretical models, coupled with the advent of new experimental methods and of powerful supercomputer capabilities.
A Textbook Of Physical Chemistry Volume 1
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Author : Mandeep Dalal
language : en
Publisher: Dalal Institute
Release Date : 2018-01-01
A Textbook Of Physical Chemistry Volume 1 written by Mandeep Dalal and has been published by Dalal Institute this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-01-01 with Science categories.
An advanced-level textbook of physical chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Physical Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Quantum Mechanics – I: Postulates of quantum mechanics; Derivation of Schrodinger wave equation; Max-Born interpretation of wave functions; The Heisenberg’s uncertainty principle; Quantum mechanical operators and their commutation relations; Hermitian operators (elementary ideas, quantum mechanical operator for linear momentum, angular momentum and energy as Hermition operator); The average value of the square of Hermitian operators; Commuting operators and uncertainty principle(x & p; E & t); Schrodinger wave equation for a particle in one dimensional box; Evaluation of average position, average momentum and determination of uncertainty in position and momentum and hence Heisenberg’s uncertainty principle; Pictorial representation of the wave equation of a particle in one dimensional box and its influence on the kinetic energy of the particle in each successive quantum level; Lowest energy of the particle. Chapter 2. Thermodynamics – I: Brief resume of first and second Law of thermodynamics; Entropy changes in reversible and irreversible processes; Variation of entropy with temperature, pressure and volume; Entropy concept as a measure of unavailable energy and criteria for the spontaneity of reaction; Free energy, enthalpy functions and their significance, criteria for spontaneity of a process; Partial molar quantities (free energy, volume, heat concept); Gibb’s-Duhem equation. Chapter 3. Chemical Dynamics – I: Effect of temperature on reaction rates; Rate law for opposing reactions of Ist order and IInd order; Rate law for consecutive & parallel reactions of Ist order reactions; Collision theory of reaction rates and its limitations; Steric factor; Activated complex theory; Ionic reactions: single and double sphere models; Influence of solvent and ionic strength; The comparison of collision and activated complex theory. Chapter 4. Electrochemistry – I: Ion-Ion Interactions: The Debye-Huckel theory of ion- ion interactions; Potential and excess charge density as a function of distance from the central ion; Debye Huckel reciprocal length; Ionic cloud and its contribution to the total potential; Debye - Huckel limiting law of activity coefficients and its limitations; Ion-size effect on potential; Ion-size parameter and the theoretical mean-activity coefficient in the case of ionic clouds with finite-sized ions; Debye - Huckel-Onsager treatment for aqueous solutions and its limitations; Debye-Huckel-Onsager theory for non-aqueous solutions; The solvent effect on the mobality at infinite dilution; Equivalent conductivity (Λ) vs. concentration c 1/2 as a function of the solvent; Effect of ion association upon conductivity (Debye- Huckel - Bjerrum equation). Chapter 5. Quantum Mechanics – II: Schrodinger wave equation for a particle in a three dimensional box; The concept of degeneracy among energy levels for a particle in three dimensional box; Schrodinger wave equation for a linear harmonic oscillator & its solution by polynomial method; Zero point energy of a particle possessing harmonic motion and its consequence; Schrodinger wave equation for three dimensional Rigid rotator; Energy of rigid rotator; Space quantization; Schrodinger wave equation for hydrogen atom, separation of variable in polar spherical coordinates and its solution; Principle, azimuthal and magnetic quantum numbers and the magnitude of their values; Probability distribution function; Radial distribution function; Shape of atomic orbitals (s,p & d). Chapter 6. Thermodynamics – II: Classius-Clayperon equation; Law of mass action and its thermodynamic derivation; Third law of thermodynamics (Nernest heat theorem, determination of absolute entropy, unattainability of absolute zero) and its limitation; Phase diagram for two completely miscible components systems; Eutectic systems, Calculation of eutectic point; Systems forming solid compounds Ax By with congruent and incongruent melting points; Phase diagram and thermodynamic treatment of solid solutions. Chapter 7. Chemical Dynamics – II: Chain reactions: hydrogen-bromine reaction, pyrolysis of acetaldehyde, decomposition of ethane; Photochemical reactions (hydrogen - bromine & hydrogen -chlorine reactions); General treatment of chain reactions (ortho-para hydrogen conversion and hydrogen - bromine reactions); Apparent activation energy of chain reactions, Chain length; Rice-Herzfeld mechanism of organic molecules decomposition(acetaldehyde); Branching chain reactions and explosions ( H2-O2 reaction); Kinetics of (one intermediate) enzymatic reaction : Michaelis-Menton treatment; Evaluation of Michaelis 's constant for enzyme-substrate binding by Lineweaver-Burk plot and Eadie-Hofstae methods; Competitive and non-competitive inhibition. Chapter 8. Electrochemistry – II: Ion Transport in Solutions: Ionic movement under the influence of an electric field; Mobility of ions; Ionic drift velocity and its relation with current density; Einstein relation between the absolute mobility and diffusion coefficient; The Stokes- Einstein relation; The Nernst -Einstein equation; Walden’s rule; The Rate-process approach to ionic migration; The Rate process equation for equivalent conductivity; Total driving force for ionic transport, Nernst - Planck Flux equation; Ionic drift and diffusion potential; the Onsager phenomenological equations; The basic equation for the diffusion; Planck-Henderson equation for the diffusion potential.
Modern Techniques Of Surface Science
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Author : D. P. Woodruff
language : en
Publisher: Cambridge University Press
Release Date : 1994-03-03
Modern Techniques Of Surface Science written by D. P. Woodruff and has been published by Cambridge University Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994-03-03 with Science categories.
This is a fully revised and expanded edition of a very successful and widely used book. It describes the physical basis of all the principal, and most of the more specialised, techniques currently employed in the study of well-characterised solid surfaces. The coverage of each technique, illustrated with selected examples, is underpinned by discussion of the relevant physical principles, and the complementary aspects of the various methods are also described. Throughout, the emphasis is on understanding the concepts involved, rather than on an exhaustive review of applications. The book will be of great use to final year undergraduate and postgraduate students in physics, chemistry and materials science. It will also be valuable to established researchers in any area of surface science concerned with the acquisition and analysis of experimental data.
Applications Of Phase Diagrams In Metallurgy And Ceramics
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Author : Gesina C. Carter
language : en
Publisher:
Release Date : 1978
Applications Of Phase Diagrams In Metallurgy And Ceramics written by Gesina C. Carter and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1978 with Ceramics categories.
Nbs Special Publication
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Author :
language : en
Publisher:
Release Date : 1968
Nbs Special Publication written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1968 with Weights and measures categories.