Molecular Nanowires And Other Quantum Objects

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Molecular Nanowires And Other Quantum Objects

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Author : Alexandre S. Alexandrov
language : en
Publisher: Springer Science & Business Media
Release Date : 2004-04-30

Molecular Nanowires And Other Quantum Objects written by Alexandre S. Alexandrov and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-04-30 with Technology & Engineering categories.

There is a growing understanding that the progress of the conventional silicon technology will reach its physical, engineering and economic limits in near future. This fact, however, does not mean that progress in computing will slow down. What will take us beyond the silicon era are new nano-technologies that are being pursued in university and corporate laboratories around the world. In particular, molecular switching devices and systems that will self-assemble through molecular recognition are being designed and studied. Many labora tories are now testing new types of these and other reversible switches, as well as fabricating nanowires needed to connect circuit elements together. But there are still significant opportunities and demand for invention and discovery be fore nanoelectronics will become a reality. The actual mechanisms of transport through molecular quantum dots and nanowires are of the highest current ex perimental and theoretical interest. In particular, there is growing evidence that both electron-vibron interactions and electron-electron correlations are impor tant. Further progress requires worldwide efforts of trans-disciplinary teams of physicists, quantum chemists, material and computer scientists, and engineers.

Molecular Nanowires And Other Quantum Objects

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Author : A. S. Alexandrov
language : en
Publisher: Springer
Release Date : 2004-06-02

Molecular Nanowires And Other Quantum Objects written by A. S. Alexandrov and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-06-02 with Science categories.

There is a growing understanding that the progress of the conventional silicon technology will reach its physical, engineering and economic limits in about a decade. What will take us beyond 2010 are new molecular and other nanotechnologies that require the efforts of trans-disciplinary teams of physicists, quantum chemists, material and computer scientists, and engineers. This volume represents a unique collection of interdisciplinary review and original papers by experts in molecular nanowires, carbon nanotubes, mesoscopic super- and semiconductors, and theorists in the field of strongly correlated electrons and phonons. Topics include molecular nanojunctions and electronics, mesoscale semiconductors and superconductors, carbon nanotubes, low dimensional conductors, polarons and strongly-correlated electrons in nanoobjects, quantum theory of nanoscale, and new techniques for making nano and mesoscopic sensors and detectors.

Molecular Electronics

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Author : Juan Carlos Cuevas
language : en
Publisher: World Scientific
Release Date : 2010

Molecular Electronics written by Juan Carlos Cuevas and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010 with Science categories.

1. The birth of molecular electronics. 1.1. Why molecular electronics?. 1.2. A brief history of molecular electronics. 1.3. Scope and structure of the book -- 2. Fabrication of metallic atomic-size contacts. 2.1. Introduction. 2.2. Techniques involving the scanning electron microscope (STM). 2.3. Methods using atomic force microscopes (AFM). 2.4. Contacts between macroscopic wires. 2.5. Transmission electron microscope. 2.6. Mechanically controllable break-junctions (MCBJ). 2.7. Electromigration technique. 2.8. Electrochemical methods. 2.9. Recent developments. 2.10. Electronic transport measurements. 2.11. Exercises -- 3. Contacting single molecules: Experimental techniques. 3.1. Introduction. 3.2. Molecules for molecular electronics. 3.3. Deposition of molecules. 3.4. Contacting single molecules. 3.5. Contacting molecular ensembles. 3.6. Exercises -- 4. The scattering approach to phase-coherent transport in nanocontacts. 4.1. Introduction. 4.2. From mesoscopic conductors to atomic-scale junctions. 4.3. Conductance is transmission : heuristic derivation of the Landauer formula. 4.4. Penetration of a potential barrier : tunnel effect. 4.5. The scattering matrix. 4.6. Multichannel Landauer formula. 4.7. Shot noise. 4.8. Thermal transport and thermoelectric phenomena. 4.9. Limitations of the scattering approach. 4.10. Exercises -- 5. Introduction to Green's function techniques for systems in equilibrium. 5.1. The Schrodinger and Heisenberg pictures. 5.2. Green's functions of a noninteracting electron system. 5.3. Application to tight-binding Hamiltonians. 5.4. Green's functions in time domain. 5.5. Exercises -- 6. Green's functions and Feynman diagrams. 6.1. The interaction picture. 6.2. The time-evolution operator. 6.3. Perturbative expansion of causal Green's functions. 6.4. Wick's theorem. 6.5. Feynman diagrams. 6.6. Feynman diagrams in energy space. 6.7. Electronic self-energy and Dyson's equation. 6.8. Self-consistent diagrammatic theory : the Hartree-Fock approximation. 6.9. The Anderson model and the Kondo effect. 6.10. Final remarks. 6.11. Exercises -- 7. Nonequilibrium Green's functions formalism. 7.1. The Keldysh formalism. 7.2. Diagrammatic expansion in the Keldysh formalism. 7.3. Basic relations and equations in the Keldysh formalism. 7.4. Application of Keldysh formalism to simple transport problems. 7.5. Exercises -- 8. Formulas of the electrical current : exploiting the Keldysh formalism. 8.1. Elastic current : microscopic derivation of the Landauer formula. 8.2. Current through an interacting atomic-scale junction. 8.3. Time-dependent transport in nanoscale junctions. 8.4. Exercises -- 9. Electronic structure I: Tight-binding approach. 9.1. Basics of the tight-binding approach. 9.2. The extended Huckel method. 9.3. Matrix elements in solid state approaches. 9.4. Slater-Koster two-center approximation. 9.5. Some illustrative examples. 9.6. The NRL tight-binding method. 9.7. The tight-binding approach in molecular electronics. 9.8. Exercises -- 10. Electronic structure II : density functional theory. 10.1. Elementary quantum mechanics. 10.2. Early density functional theories. 10.3. The Hohenberg-Kohn theorems. 10.4. The Kohn-Sham approach. 10.5. The exchange-correlation functionals. 10.6. The basic machinery of DFT. 10.7. DFT performance. 10.8. DFT in molecular electronics. 10.9. Exercises -- 11. The conductance of a single atom. 11.1. Landauer approach to conductance: brief reminder. 11.2. Conductance of atomic-scale contacts. 11.3. Conductance histograms. 11.4. Determining the conduction channels. 11.5. The chemical nature of the conduction channels of oneatom contacts. 11.6. Some further issues. 11.7. Conductance fluctuations. 11.8. Atomic chains : parity oscillations in the conductance. 11.9. Concluding remarks. 11.10. Exercises -- 12. Spin-dependent transport in ferromagnetic atomic contacts. 12.1. Conductance of ferromagnetic atomic contacts. 12.2. Magnetoresistance of ferromagnetic atomic contacts. 12.3. Anisotropic magnetoresistance in atomic contacts. 12.4. Concluding remarks and open problems -- 13. Coherent transport through molecular junctions I : basic concepts. 13.1. Identifying the transport mechanism in single-molecule junctions. 13.2. Some lessons from the resonant tunneling model. 13.3. A two-level model. 13.4. Length dependence of the conductance. 13.5. Role of conjugation in [symbol]-electron systems. 13.6. Fano resonances. 13.7. Negative differential resistance. 13.8. Final remarks. 13.9. Exercises -- 14. Coherent transport through molecular junctions II : test-bed molecules. 14.1. Coherent transport through some test-bed molecules. 14.2. Metal-molecule contact : the role of anchoring groups. 14.3. Tuning chemically the conductance : the role of side-groups. 14.4. Controlled STM-based single-molecule experiments. 14.5. Conclusions and open problems -- 15. Single-molecule transistors : Coulomb blockade and Kondo physics. 15.1. Introduction. 15.2. Charging effects in transport through nanoscale devices. 15.3. Single-molecule three-terminal devices. 15.4. Coulomb blockade theory : constant interaction model. 15.5. Towards a theory of Coulomb blockade in molecular transistors. 15.6. Intermediate coupling : cotunneling and Kondo effect. 15.7. Single-molecule transistors : experimental results. 15.8. Exercises -- 16. Vibrationally-induced inelastic current I : experiment. 16.1. Introduction. 16.2. Inelastic electron tunneling spectroscopy (IETS). 16.3. Highly conductive junctions : point-contact spectroscopy (PCS). 16.4. Crossover between PCS and IETS. 16.5. Resonant inelastic electron tunneling spectroscopy (RIETS). 16.6. Summary of vibrational signatures -- 17. Vibrationally-induced inelastic current II : theory. 17.1. Weak electron-phonon coupling regime. 17.2. Intermediate electron-phonon coupling regime. 17.3. Strong electron-phonon coupling regime. 17.4. Concluding remarks and open problems. 17.5. Exercises -- 18. The hopping regime and transport through DNA molecules. 18.1. Signatures of the hopping regime. 18.2. Hopping transport in molecular junctions : experimental examples. 18.3. DNA-based molecular junctions. 18.4. Exercises -- 19. Beyond electrical conductance : shot noise and thermal transport. 19.1. Shot noise in atomic and molecular junctions. 19.2. Heating and heat conduction. 19.3. Thermoelectricity in molecular junctions -- 20. Optical properties of current-carrying molecular junctions. 20.1. Surface-enhanced Raman spectroscopy of molecular junctions. 20.2. Transport mechanisms in irradiated molecular junctions. 20.3. Theory of photon-assisted tunneling. 20.4. Experiments on radiation-induced transport in atomic and molecular junctions. 20.5. Resonant current amplification and other transport phenomena in ac driven molecular junctions. 20.6. Fluorescence from current-carrying molecular junctions. 20.7. Molecular optoelectronic devices. 20.8. Final remarks. 20.9. Exercises -- 21. What is missing in this book?

Molecular Electronics An Introduction To Theory And Experiment 2nd Edition

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Author : Elke Scheer
language : en
Publisher: World Scientific
Release Date : 2017-05-19

Molecular Electronics An Introduction To Theory And Experiment 2nd Edition written by Elke Scheer and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-05-19 with Technology & Engineering categories.

Molecular Electronics is self-contained and unified in its presentation. It can be used as a textbook on nanoelectronics by graduate students and advanced undergraduates studying physics and chemistry. In addition, included in this new edition are previously unpublished material that will help researchers gain a deeper understanding into the basic concepts involved in the field of molecular electronics.

Magnetic Quantum Dots In Ii Vi Semiconductor Nanowires

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Author : Pamela Rueda-Fonseca
language : en
Publisher:
Release Date : 2015

Magnetic Quantum Dots In Ii Vi Semiconductor Nanowires written by Pamela Rueda-Fonseca and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015 with categories.

In this PhD work a novel type of magnetic semiconductor object has been developed: Cd(Mn)Te quantum dots embedded in ZnTe/ZnMgTe core-shell nanowires. The goal was to investigate the growth, by molecular beam epitaxy, and the fundamental properties of these complex heterostructures. For that purpose, two main issues were addressed: i) gaining control of the structural, electronic and magnetic properties of these quantum objects by mastering their growth; and ii) obtaining quantitative local knowledge on the chemical composition of those non-homogeneous nanostructures. To tackle these topics, our research was divided into four stages. The first stage was devoted to perform a quantitative study of the formation process of the Au particles that catalyze the growth of nanowires. The second stage involved the analysis of the mechanisms and parameters governing the growth of ZnTe nanowires. In particular, two different types of nanowires were found: cone-shaped nanowires with the zinc-blende crystal structure and cylinder-shaped nanowires with the hexagonal wurtzite structure. A diffusion-driven growth model is employed to fit some of the quantitative results presented in this part. The third stage focused on the insertion of pure CdTe quantum dots containing Mn ions in the core-shell nanowires. An initial study of the relevant parameters influencing the magneto-optical properties of these objects, such as the quantum dot confinement, the Mn incorporation, and the strain anisotropy, was performed. The four and last stage of this work concerned the quantitative interpretation of Energy-Dispersive X-ray spectroscopy measurements performed on single core-multishell nanowires. A geometrical model was proposed to retrieve the shape, the size and the local composition of the quantum dot insertions and of the multiple layers of the heterostructures. This study was coupled to other complementary characterization measurements on the same nanowire, such as cathodo-luminescence, micro-photo-luminescence and magneto-optical spectroscopy.

Superconductivity In Nanowires

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Author : Alexey Bezryadin
language : en
Publisher: John Wiley & Sons
Release Date : 2013-02-19

Superconductivity In Nanowires written by Alexey Bezryadin and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-02-19 with Science categories.

The importance and actuality of nanotechnology is unabated and will be for years to come. A main challenge is to understand the various properties of certain nanostructures, and how to generate structures with specific properties for use in actual applications in Electrical Engineering and Medicine. One of the most important structures are nanowires, in particular superconducting ones. They are highly promising for future electronics, transporting current without resistance and at scales of a few nanometers. To fabricate wires to certain defined standards however, is a major challenge, and so is the investigation and understanding of these properties in the first place. A promising approach is to use carbon nanotubes as well as DNA structures as templates. Many fundamental theoretical questions are still unanswered, e.g. related to the role of quantum fluctuations. This work is tackling them and provides a detailed analysis of the transport properties of such ultrathin wires. It presents an account of theoretical models, charge transport experiments, and also conveys the latest experimental findings regarding fabrication, measurements, and theoretical analysis. In particular, it is the only available resource for the approach of using DNA and carbon nanotubes for nanowire fabrication. It is intended for graduate students and young researchers interested in nanoscale superconductivity. The readers are assumed to have knowledge of the basics of quantum mechanics and superconductivity.

Quantum Transport Nanostructures Molechb

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Author : LAMBERT
language : en
Publisher: IOP Publishing Limited
Release Date : 2021-03-23

Quantum Transport Nanostructures Molechb written by LAMBERT and has been published by IOP Publishing Limited this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-03-23 with Science categories.

This reference text presents a conceptual framework for understanding room-temperature electron and phonon transport through molecules and other quantum objects. The flow of electricity through molecules is explained at the boundary of physics and chemistry, providing an authoritative introduction to molecular electronics for physicists, and quantum transport for chemists. Professor Lambert provides a pedagogical account of the fundamental concepts needed to understand quantum transport and thermoelectricity in molecular-scale and nanoscale structures. The material provides researchers and advanced students with an understanding of how quantum transport relates to other areas of materials modelling, condensed matter and computational chemistry. After reading the book, the reader will be familiar with the basic concepts of molecular-orbital theory and scattering theory, which underpin current theories of quantum transport. Key Features  Introduces molecular electronics for physicists, and quantum transport for chemists. Presents a conceptual framework for understanding room-temperature electron and phonon transport through molecules and other quantum objects. Provides a pedagogical account of quantum-interference-enhanced electrical and thermal properties of single molecules and self-assembled monolayers. Provides readers with an understanding of how quantum transport relates to other areas of materials modelling, condensed matter or computational chemistry. Discusses concepts needed to engineer the properties of molecules and create new functions. Includes MATLAB codes to allow the reader to expand the examples presented in the book.

Carbon Nanotubes And Their Applications

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Author : Qing Zhang
language : en
Publisher: CRC Press
Release Date : 2012-04-23

Carbon Nanotubes And Their Applications written by Qing Zhang and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-04-23 with Science categories.

This book overviews the current status of research and development activities of CNTs in nanodevices, nanomaterials, or nanofabrication. This book presents 15 state-of-the-art review articles that cover CNT synthesis technologies for growing highly orientated CNTs, chirality-pure CNTs and CNTs at a large throughput and low cost, CNT assembly techni

Nanoscale Devices Fundamentals And Applications

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Author : Rudolf Gross
language : en
Publisher: Springer Science & Business Media
Release Date : 2007-05-16

Nanoscale Devices Fundamentals And Applications written by Rudolf Gross and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-05-16 with Technology & Engineering categories.

This book collects papers on the fundamentals and applications of nanoscale devices, first presented at the NATO Advanced Research Workshop on Nanoscale Devices – Fundamentals and Applications held in Kishinev, Moldova, in September 2004. The focus is on the synthesis and characterization of nanoscale magnetic materials; fundamental physics and materials aspects of solid-state nanostructures; development of novel device concepts and design principles for nanoscale devices; and on applications in electronics with emphasis on defence against the threat of terrorism.

Nanophysics Nanoclusters And Nanodevices

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Author : Kimberly S. Gehar
language : en
Publisher: Nova Publishers
Release Date : 2006

Nanophysics Nanoclusters And Nanodevices written by Kimberly S. Gehar and has been published by Nova Publishers this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006 with Science categories.

Nanotechnology is a 'catch-all' description of activities at the level of atoms and molecules that have applications in the real world. A nanometre is a billionth of a metre, about 1/80,000 of the diameter of a human hair, or 10 times the diameter of a hydrogen atom. Nanotechnology is now used in precision engineering, new materials development as well as in electronics; electromechanical systems as well as mainstream biomedical applications in areas such as gene therapy, drug delivery and novel drug discovery techniques. This book presents the latest research in this frontier field.