Oxygen Atom Transfer Reactions
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Oxygen Atom Transfer Reactions
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Author : Robert Bakhtchadjian
language : en
Publisher: Bentham Science Publishers
Release Date : 2023-01-11
Oxygen Atom Transfer Reactions written by Robert Bakhtchadjian and has been published by Bentham Science Publishers this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-01-11 with Science categories.
This book introduces readers to the fundamentals of oxygen atom transfer reactions. It also gives mechanistic insights into the redox processes occurring through the oxygen atom transfer reactions. It also includes information about catalytic activation of oxygen through enzymes and oxo-metallic complexes. All topics are explored in separate chapters. Key features: - reviews the basic mechanisms in redox processes involving oxo-atom transfer reactions. - presents progress in the biomimetic activation of dioxygen related to the catalytic oxidations by synthetic metal organic complexes. - covers an important class of metal-organic compounds - nickel-oxygen species - generated in catalytic oxidation processes as oxygen atom transfer agents. - explains the mechanistic aspects of the heterogeneous photochemical redox processes via oxo-atom transfer reactions - provides references for further reading It is a reference for both professional scientists in the fields of chemistry, biology and applied sciences, and for graduate and undergraduate students interested in understanding reaction mechanisms involving oxygen.
Oxygen Atom Transfer Reactions
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Author : Robert Bakhtchadjian
language : en
Publisher: Chemical Reaction Mechanisms
Release Date : 2023-01-11
Oxygen Atom Transfer Reactions written by Robert Bakhtchadjian and has been published by Chemical Reaction Mechanisms this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-01-11 with Science categories.
This book introduces readers to the fundamentals of oxygen atom transfer reactions. It also gives mechanistic insights into the redox processes occurring through the oxygen atom transfer reactions. It also includes information about catalytic activation of oxygen through enzymes and oxo-metallic complexes. All topics are explored in separate chapters. Key features: - reviews the basic mechanisms in redox processes involving oxo-atom transfer reactions. - presents progress in the biomimetic activation of dioxygen related to the catalytic oxidations by synthetic metal organic complexes. - covers an important class of metal-organic compounds - nickel-oxygen species - generated in catalytic oxidation processes as oxygen atom transfer agents. - explains the mechanistic aspects of the heterogeneous photochemical redox processes via oxo-atom transfer reactions - provides references for further reading It is a reference for both professional scientists in the fields of chemistry, biology and applied sciences, and for graduate and undergraduate students interested in understanding reaction mechanisms involving oxygen.
Photo Initiated Oxygen Atom Transfer Reaction From Nitrogen Dioxide To Acetylene And Methyl Acetylene Under Matrix Isolation Conditions
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Author : James Andrew Harrison
language : en
Publisher:
Release Date : 1991
Photo Initiated Oxygen Atom Transfer Reaction From Nitrogen Dioxide To Acetylene And Methyl Acetylene Under Matrix Isolation Conditions written by James Andrew Harrison and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1991 with categories.
Biomimetic Oxidations Catalyzed By Transition Metal Complexes
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Author : Bernard Meunier
language : en
Publisher: World Scientific
Release Date : 2000-03-08
Biomimetic Oxidations Catalyzed By Transition Metal Complexes written by Bernard Meunier and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-03-08 with Science categories.
Since the classic work Metal-Catalyzed Oxidations of Organic Compounds (edited by R A Sheldon and J K Kochi, 1991), no book has been devoted to advances in the field of biomimetic oxidations, which was created nearly 18 years ago. This expanding research field is covered in this volume. All the different aspects of the modeling of oxidations catalyzed by metalloenzymes are dealt with. This invaluable book will be useful to postgraduates as well as researchers in academia and industry, and will also benefit second year university students. Contents:Thermodynamic Influences of C–H Bond Oxidation (J M Mayer)Distinguishing Biomimetic Oxidations from Oxidations Mediated by Freely Diffusing Radicals (K U Ingold & P A MacFaul)Biomimetic Oxygenations Related to Cytochrome P450: Metal-Oxo and Metal-Peroxo Intermediates (J L McLain et al.)Models of Heme Peroxidases and Catalases (B Meunier)Non-Heme Peroxidases and Catalases: Mechanistic Implications from the Studies of Manganese and Vanadium Model Compounds (C Slebodnick et al.)Methane Monooxygenase Models (Z-B Hu & S M Gorun)Models of Copper Enzymes and Heme-Copper Oxidases (M A Kopf & K D Karlin)Iron-Containing Models of Catechol Dioxygenases (H-J Krüger)Biomimetic Chemistry of Molybdenum (C G Young)Models of Superoxide Dismutases (D E Cabelli et al.)Modeling the Oxygen-Evolving Complex in Photosystem II (J Limburg et al.)Asymmetric Biomimetic Oxidations (A Robert & B Meunier)Bioinspired Oxidations Catalyzed by Ruthenium Complexes (S-I Murahashi & N Komiya)Biocatalytic and Biomimetic Oxidations from an Industrial Perspective (R A Sheldon) Readership: Postgraduate students and researchers in biochemistry and chemistry. Keywords:EPR Spectroscopy;Functional Model Chemistry;Isotope Labeling;Manganese Complexes;Mechanism;Oxygen Evolution;Photosystem II;Redox Chemistry;Water Splitting Chemistry;X-Ray Spectroscopy;Oxidation;Oxygenation;Transition Metal Complexes;Asymmetric Oxidation;Oxidase;Oxygenase;Metal-Oxo;Peroxide, Peroxo;Metalloporphyrin;MMO Models;P450 Models
Molybdenum And Tungsten Enzymes
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Author : Russ Hille
language : en
Publisher: Royal Society of Chemistry
Release Date : 2016-09-29
Molybdenum And Tungsten Enzymes written by Russ Hille and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-09-29 with Science categories.
There has been enormous progress in our understanding of molybdenum and tungsten enzymes and relevant inorganic complexes of molybdenum and tungsten over the past twenty years. This set of three books provides a timely and comprehensive overview of the field and documents the latest research. Building on the first volume that focussed on biochemistry aspects, the second volume in the set focusses on the inorganic complexes that model the structures and reactivity of the active sites of each major group of molybdenum and tungsten enzymes. Special attention is given to synthetic strategies, reaction mechanism and chemical kinetics of these systems. The introductory chapter provides a useful overview and places the topic of the book into a wider context. This text will be a valuable reference to workers both inside and outside the field, including graduate students and young investigators interested in developing new research programs in this area.
Vanadium In Biological Systems
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Author : N.D. Chasteen
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Vanadium In Biological Systems written by N.D. Chasteen and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Over the past several decades, vanadium has increasingly attracted the interest of biologists and chemists. The discovery by Henze in 1911 that certain marine ascidians accumulate the metal in their blood cells in unusually large quantities has done much to stimulate research on the role of vanadium in biology. In the intervening years, a large number of studies have been carried out to investigate the toxicity of vanadium in higher animals and to determine whether it is an essential trace element. That vanadium is a required element for a few selected organisms is now well established. Whether vanadium is essential for humans remains unclear although evidence increasingly suggests that it probably is. The discovery by Cantley in 1977 that vanadate is a potent inhibitor of ATPases lead to numerous studies of the inhibitory and stimulatory effects of vanadium on phosphate metabolizing enzymes. As a consequence vanadates are now routinely used as probes to investigate the mechanisms of such enzymes. Our understanding of vanadium in these systems has been further enhanced by the work of Tracy and Gresser which has shown striking parallels between the chemistry of vanadates and phosphates and their biological compounds. The observation by Shechter and Karlish, and Dubyak and Kleinzeller in 1980 that vanadate is an insulin mimetic agent has opened a new area of research dealing with the hormonal effects of vanadium. The first vanadium containing enzyme, a bromoperoxidase from the marine alga Ascophyllum nodosum, was isolated in 1984 by Viltner.
Molybdenum Enzymes
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Author : Thomas G. Spiro
language : en
Publisher: Wiley-Interscience
Release Date : 1985-11-14
Molybdenum Enzymes written by Thomas G. Spiro and has been published by Wiley-Interscience this book supported file pdf, txt, epub, kindle and other format this book has been release on 1985-11-14 with Science categories.
Volume 7 in the Metal Ions in Biology Series, divided into two parts, covers the nitrogenase enzyme complex and the molybdenum redox enzymes. Part one covers the chemistry of Mo-Fe-S clusters and their relationship to nitrogenase, cofactor chemistry and biochemistry of nitrogenase, spectroscopic and electrochemical studies of the Fe-Mo cofactor and Fe-S clusters, and more. Part Two surveys oxo-molybdenum chemistry, discusses the nature of the molybdo-pterin complex, and describes the characteristics of several of the Mo redox enzymes.
Physical Inorganic Chemistry
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Author : Andreja Bakac
language : en
Publisher: John Wiley & Sons
Release Date : 2010-04-22
Physical Inorganic Chemistry written by Andreja Bakac and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010-04-22 with Science categories.
This go-to text provides information and insight into physical inorganic chemistry essential to our understanding of chemical reactions on the molecular level. One of the only books in the field of inorganic physical chemistry with an emphasis on mechanisms, it features contributors at the forefront of research in their particular fields. This essential text discusses the latest developments in a number of topics currently among the most debated and researched in the world of chemistry, related to the future of solar energy, hydrogen energy, biorenewables, catalysis, environment, atmosphere, and human health.
Nickel Catalysis In Organic Synthesis
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Author : Sensuke Ogoshi
language : en
Publisher: John Wiley & Sons
Release Date : 2020-03-09
Nickel Catalysis In Organic Synthesis written by Sensuke Ogoshi and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-03-09 with Science categories.
A comprehensive reference to nickel chemistry for every scientist working with organometallic catalysts Written by one of the world?s leading reseachers in the field, Nickel Catalysis in Organic Synthesis presents a comprehensive review of the high potential of modern nickel catalysis and its application in synthesis. Structured in a clear and assessible manner, the book offers a collection of various reaction types, such as cross-coupling reactions, reactions for the activation of unreactive bonds, carbon dioxide fixation, and many more. Nickel has been recognized as one of the most interesting transition metals for homogeneous catalysis. This book offers an overview to the recently developed new ligands, new reaction conditions, and new apparatus to control the reactivity of nickel catalysts, allowing scientists to apply nickel catalysts to a variety of bond-forming reactions. A must-read for anyone working with organometallic compounds and their application in organic synthesis, this important guide: -Reviews the numerous applications of nickel catalysis in synthesis -Explores the use of nickel as a relatively cheap and earth-abundant metal -Examines the versatility of nickel catalysis in reactions like cross-coupling reactions and CH activations -Offers a resource for academics and industry professionals Written for catalytic chemists, organic chemists, inorganic chemists, structural chemists, and chemists in industry, Nickel Catalysis in Organic Synthesis provides a much-needed overview of the most recent developments in modern nickel catalysis and its application in synthesis.
Principles Of Bioinorganic Chemistry
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Author : Stephen J. Lippard
language : en
Publisher: University Science Books
Release Date : 1994
Principles Of Bioinorganic Chemistry written by Stephen J. Lippard and has been published by University Science Books this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994 with Medical categories.
The use of unnatural metals - which have been introduced into human biology as diagnostic probes and drugs - is another active area of tremendous medical significance.