Possible Scenarios For Homochirality On Earth
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Possible Scenarios For Homochirality On Earth
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Author : Michiya Fujiki
language : en
Publisher: Buy this from MDPI Books
Release Date : 2019-11-14
Possible Scenarios For Homochirality On Earth written by Michiya Fujiki and has been published by Buy this from MDPI Books this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-11-14 with Science categories.
In 1978, Fred Hoyle proposed that interstellar comets carrying several viruses landed on Earth as part of the panspermia hypotheses. With respect to life, the origin of homochirality on Earth has been the greatest mystery because life cannot exist without molecular asymmetry. Many scientists have proposed several possible hypotheses to answer this long-standing L-D question. Previously, Martin Gardner raised the question about mirror symmetry and broken mirror symmetry in terms of the homochirality question in his monographs (1964 and 1990). Possible scenarios for the L-D issue can be categorized into (i) Earth and exoterrestrial origins, (ii) by-chance and necessity mechanisms, and (iii) mirror-symmetrical and non-mirror-symmetrical forces as physical and chemical origins. These scenarios should involve further great amplification mechanisms, enabling a pure L- or D-world.
Possible Scenarios For Homochirality On Earth
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Author : Michiya Fujiki
language : en
Publisher:
Release Date : 2019
Possible Scenarios For Homochirality On Earth written by Michiya Fujiki and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019 with Science (General) categories.
In 1978, Fred Hoyle proposed that interstellar comets carrying several viruses landed on Earth as part of the panspermia hypotheses. With respect to life, the origin of homochirality on Earth has been the greatest mystery because life cannot exist without molecular asymmetry. Many scientists have proposed several possible hypotheses to answer this long-standing L-D question. Previously, Martin Gardner raised the question about mirror symmetry and broken mirror symmetry in terms of the homochirality question in his monographs (1964 and 1990). Possible scenarios for the L-D issue can be categorized into (i) Earth and exoterrestrial origins, (ii) by-chance and necessity mechanisms, and (iii) mirror-symmetrical and non-mirror-symmetrical forces as physical and chemical origins. These scenarios should involve further great amplification mechanisms, enabling a pure L- or D-world.
Comprehensive Chirality
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Author :
language : en
Publisher: Newnes
Release Date : 2012-12-31
Comprehensive Chirality written by and has been published by Newnes this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-31 with Science categories.
Although many books exist on the subject of chiral chemistry, they only briefly cover chiral synthesis and analysis as a minor part of a larger work, to date there are none that pull together the background information and latest advances in one comprehensive reference work. Comprehensive Chirality provides a complete overview of the field, and includes chiral research relevant to synthesis, analytic chemistry, catalysis, and pharmaceuticals. The individual chapters in each of the 9 volumes provide an in depth review and collection of references on definition, technology, applications and a guide/links to the related literature. Whether in an Academic or Corporate setting, these chapters will form an invaluable resource for advanced students/researchers new to an area and those who need further background or answers to a particular problem, particularly in the development of drugs. Chirality research today is a central theme in chemistry and biology and is growing in importance across a number of disciplinary boundaries. These studies do not always share a unique identifying factor or subject themselves to clear and concise definitions. This work unites the different areas of research and allows anyone working or researching in chiral chemistry to navigate through the most essential concepts with ease, saving them time and vastly improving their understanding. The field of chirality counts several journals that are directly and indirectly concerned with the field. There is no reference work that encompasses the entire field and unites the different areas of research through deep foundational reviews. Comprehensive Chirality fills this vacuum, and can be considered the definitive work. It will help users apply context to the diverse journal literature offering and aid them in identifying areas for further research and/or for solving problems. Chief Editors, Hisashi Yamamoto (University of Chicago) and Erick Carreira (ETH Zürich) have assembled an impressive, world-class team of Volume Editors and Contributing Authors. Each chapter has been painstakingly reviewed and checked for consistent high quality. The result is an authoritative overview which ties the literature together and provides the user with a reliable background information and citation resource.
Chiral Recognition In The Gas Phase
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Author : Anne Zehnacker
language : en
Publisher: CRC Press
Release Date : 2010-05-25
Chiral Recognition In The Gas Phase written by Anne Zehnacker and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010-05-25 with Science categories.
Understanding the molecular interactions responsible for chiral recognition is of primary importance in life chemistry. Gas-phase experiments on either neutral or ionic adducts of chiral molecules allow for the study of intrinsic properties of chiral recognition in solvent-free conditions. With contributions from a panel of international experts ex
Asymmetry In Biological Homochirality
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Author : David Hochberg
language : en
Publisher: MDPI
Release Date : 2021-06-04
Asymmetry In Biological Homochirality written by David Hochberg and has been published by MDPI this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-06-04 with Science categories.
Chirality, or handedness, is a fundamental physical characteristic, which spans the length scales ranging from elementary particles to the chiral asymmetry of spiral galaxies. The way in which chirality in chemistry, or molecular handedness, may have emerged in a primitive terrestrial environment, and how it can be triggered, amplified, and transferred, are deeply challenging problems rooted in both fundamental scientific interests and the technological potentials for science and society. Chirality constitutes a unifying feature of the living world and is a prime driving force for molecular selection and genetic evolution in biology. In this book, we offer a selection of five distinct approaches to this problem by leading experts in the field. The selected topics range from protein chirality and its relevance to protein ageing, protein aggregation and neurodegeneration, entropy production associated with chiral symmetry breaking in closed systems, chiral oscillations in polymerization models involving higher-order oligomers, the mirror symmetry breaking in liquids and its implications for the development of homochirality in abiogenesis, the role of chirality in the chemical sciences, and some philosophical implications of chirality.
Progress In Biological Chirality
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Author : Gyula Palyi
language : en
Publisher: Elsevier
Release Date : 2004-12-13
Progress In Biological Chirality written by Gyula Palyi and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-12-13 with Science categories.
Following on from Advances in BioChirality, Progress in Biological Chirality provides a unique summary and review of the most recent developments in the field of biochirality. Living organisms use only one enantiomer of chiral molecules in the majority of biologically important processes. The exact origin and mechanisms for this surprising selectivity are not yet known. This book discusses current research aimed at identifying the scientific reasons that may contribute to this phenomenon. Progress in Biological Chirality takes an interdisciplinary approach to this exciting field, covering a wide range of topics, such as, theory, palaeontology and food technology, to name but a few. This book presents findings via a broad spectrum of scientific approaches making it an excellent overview of Biological Chirality, suitable for postgraduate students, practitioners and researchers in the field of chemistry, biochemistry, biology, palaeontology, and food science with an interest in Chirality. - This book contains 32 chapters written by Authors, who are leading authorities in the field - Presents the most recent research taking place in this highly challenging field - Contains both reference material for the specialist and provides an overview for those who are interested in the fundamental problems of biology and chemistry
On Chirality And The Universal Asymmetry
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Author : Georges H. Wagnière
language : en
Publisher: John Wiley & Sons
Release Date : 2008-09-26
On Chirality And The Universal Asymmetry written by Georges H. Wagnière and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-09-26 with Science categories.
Until half a century ago, it was assumed that the forces of nature were symmetric and that they did not distinguish between right and left, between image and mirror image. The discovery of the violation of parity in 1956 was more than a sensation, for some it was a shock. It implied that the universe displays handedness, or chirality, and that it is fundamentally asymmetric. Remarkably, a most striking asymmetry is encountered in the realm of biology. Living organisms contain proteins built almost exclusively from L-amino acids, and nucleic acids derived from D-sugars only. Yet a mirror-image biochemistry, based on D-amino acids and L-sugars is, from a purely chemical standpoint, entirely conceivable. Where, then, does this extraordinary natural selectivity come from? Is it directly, or indirectly, connected to the universal violation of parity? This book is meant as a brief review of the various manifestations of handedness, or chirality, in the universe. It does not attempt to present a solution to basic questions which perhaps will never be unambiguously and conclusively answered. Rather, it is an excursion through nature, to observe and recognize how the chirality manifests itself at different structural levels. The excursion starts in the chemistry and physics laboratory. Then a journey into outer space and back in time is undertaken. After a return to our planet Earth, the focus is on the development of living organisms. The text should be accessible to anyone having the equivalent of a first-year university instruction in physics and chemistry. It is also hoped that a layperson with a more modest scientific formation may gain a general impression of the basic asymmetry in nature and of the fundamental significance of chirality. Mathematical expressions, wherever they occur, may then be overlooked. Some more difficult sections may be skipped. A Glossary preceding the Subject Index should be helpful.
Fundamentals Of Supramolecular Chirality
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Author : Roberto Purrello
language : en
Publisher: World Scientific
Release Date : 2021-10-18
Fundamentals Of Supramolecular Chirality written by Roberto Purrello and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-10-18 with Science categories.
Fundamentals of Supramolecular Chirality is a critical description of the start and advancement of supramolecular chirality. This book focuses on the noncovalent approach with some supplementary examples of covalent supramolecular chirality.This contribution to supramolecular chirality is not intended to be a mere catalogue and description of the work done. It also traces a philosophical path following the development and possible perspectives of this topic, providing not a review but a critical examination of the field.
Origins Of Life Volume Ii
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Author : Vladivoj Valkovic
language : en
Publisher: CRC Press
Release Date : 2024-09-27
Origins Of Life Volume Ii written by Vladivoj Valkovic and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-09-27 with Science categories.
In Origins of Life Volume II, life and its origin are inspected from traditional and unexpected points of view. The book takes an interdisciplinary approach, discussing astrobiology; chemical evolution; and how the Universe accommodates life, molecular biology, and philosophy. It is an open-minded approach, fully referenced throughout, and each chapter includes a further reading section for anyone wishing to learn more about that perspective on the origins of life. First, everything started, with the Big Bang, from nothing. It appears now that everything was aiming toward our existence, some 13.75 × 109 years later, being capable of understanding it all. We did it using powerful tools: science, philosophy, and religion. Although we appreciate the contributions made by philosophy and religion, our contemplations and doubts are based on the plentiful scientific evidence provided. The reader will be guided from make-up of the "life stage" (Universe), tools and materials needed for the living matter to be formed in the small part of the Universe, which one could call Human Neighborhood, or the Local Universe. It contains galaxies, galaxy clusters, and voids, and the Milky Way and its satellites influencing each other during this time span. The book is easy to read, accompanied by numerous references; it could be of use to the expert in the field as well as for curious minds with a scientific, philosophical, or religious background.
Origin Of Chirality In The Molecules Of Life
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Author : Albert Guijarro
language : en
Publisher: Royal Society of Chemistry
Release Date : 2022-06-10
Origin Of Chirality In The Molecules Of Life written by Albert Guijarro and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-06-10 with Science categories.
This book provides an interdisciplinary review of one of the great unsolved mysteries that has fascinated scientists for over 150 years: the origin of chirality in biomolecules. Current advances in fields as diverse as space exploration, prebiotic chemistry and high-energy physics may help to provide an answer. Important pieces of information will come from observations at the two frontiers of science: outer space and the subatomic world. Observation of distant planets, galaxies, and even actual sampling of celestial objects from beyond the solar system are projects currently underway. At the other end of the spectrum, there are experiments that study the elemental properties of matter, such as symmetry, and interactions with the fundamental forces. Completely revised and updated this new edition once again unifies all the theories of the origin of biomolecular homochirality together in a single source. This complete, interdisciplinary review of an intriguing subject condenses a large and disparate range of contributions from journals in almost every scientific field. The various theories have been organized, interrelated and explained in a unified way. It is fundamental, comprehensive and structured to be accessible for educational purposes.