Stereodirected Synthesis With Organoboranes
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Stereodirected Synthesis With Organoboranes
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Author : Donald S. Matteson
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Stereodirected Synthesis With Organoboranes written by Donald S. Matteson and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
This monograph has been written to demonstrate to organic chemists and graduate students the strategies for controlling stereochemistry in carbon-carbon bond formations with borane intermediates. The boranes were initially found to be useful reagents by Nobel Laureate H.C. Brown. Their precursors are commercially available and derivatization is fast, clean and simple.
Organoboranes In Organic Synthesis
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Author : Gordon M. L. Cragg
language : en
Publisher:
Release Date : 1973
Organoboranes In Organic Synthesis written by Gordon M. L. Cragg and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1973 with Science categories.
Organoboranes For Syntheses
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Author : P. Veeraraghavan Ramachandran
language : en
Publisher:
Release Date : 2001
Organoboranes For Syntheses written by P. Veeraraghavan Ramachandran and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001 with Medical categories.
This book examines the recent advances in the art of organic synthesis via organoboranes. The volume includes a wide range of topics in asymmetric synthesis, such as reduction, aldol reaction, allyboration, homologation, and cyclopropanation. Additional subjects include Suzuki coupling, amino acid synthesis, fluoro-organic synthesis, boron catalysts for stereoselective transformations, heterocyclic synthesis and novel borohydride reagents.
Synthesis Of Functionalized Organoboron Compounds Through Copper I Catalysis
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Author : Koji Kubota
language : en
Publisher: Springer
Release Date : 2017-06-27
Synthesis Of Functionalized Organoboron Compounds Through Copper I Catalysis written by Koji Kubota and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-06-27 with Science categories.
This book describes state-of-the-art borylation chemistry using copper(I) catalysis. Enantioselective reactions are included to afford a variety of functionalized, complex organoboronate esters, which will find wide application in asymmetric synthesis, drug discovery, and material science. Organoboron compounds are recognized as useful reagents in organic synthesis; therefore, great effort has been devoted to the development of a simple, mild, and efficient method for their preparation in the past several years. However, the synthesis of functionalized organoboron compounds remains a challenging issue because known reactions often require the use of highly reactive organometallic carbon nucleophiles. This book focuses on conceptually new, formal nucleophilic copper(I)-catalyzed borylation reactions with diboron compounds that show high selectivity and excellent functional group compatibility. Theoretical studies based on density functional theory calculations to understand the reaction mechanisms have also been described. Advances in this novel borylation chemistry will allow the rapid and efficient synthesis of complex molecules with potentially interesting properties in combination with the boron functionalization process.
Modern Organic Synthesis
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Author : George S. Zweifel
language : en
Publisher: John Wiley & Sons
Release Date : 2017-03-09
Modern Organic Synthesis written by George S. Zweifel and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-03-09 with Science categories.
This book bridges the gap between sophomore and advanced / graduate level organic chemistry courses, providing students with a necessary background to begin research in either an industry or academic environment. • Covers key concepts that include retrosynthesis, conformational analysis, and functional group transformations as well as presents the latest developments in organometallic chemistry and C–C bond formation • Uses a concise and easy-to-read style, with many illustrated examples • Updates material, examples, and references from the first edition • Adds coverage of organocatalysts and organometallic reagents
Part B Reactions And Synthesis
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Author : Francis A. Carey
language : en
Publisher: Springer
Release Date : 2013-11-27
Part B Reactions And Synthesis written by Francis A. Carey and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-27 with Science categories.
Copper Catalyzed Asymmetric Synthesis
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Author : Alexandre Alexakis
language : en
Publisher: John Wiley & Sons
Release Date : 2013-12-30
Copper Catalyzed Asymmetric Synthesis written by Alexandre Alexakis and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-12-30 with Science categories.
This book reflects the increasing interest among the chemical synthetic community in the area of asymmetric copper-catalyzed reactions, and introduces readers to the latest, most significant developments in the field. The contents are organized according to reaction type and cover mechanistic and spectroscopic aspects as well as applications in the synthesis of natural products. A whole chapter is devoted to understanding how primary organometallics interact with copper to provide selective catalysts for allylic substitution and conjugate addition, both of which are treated in separate chapters. Another is devoted to the variety of substrates and experimental protocols, while an entire chapter covers the use on non-carbon nucleophiles. Other chapters deal with less-known reactions, such as carbometallation or the additions to imines and related systems, while the more established reactions cyclopropanation and aziridination as well as the use of copper (II) Lewis acids are warranted their own special chapters. Two further chapters concern the processes involved, as determined by mechanistic studies. Finally, a whole chapter is devoted to the synthetic applications. This is essential reading for researchers at academic institutions and professionals at pharmaceutical or agrochemical companies.
Lithium Compounds In Organic Synthesis
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Author : Renzo Luisi
language : en
Publisher: John Wiley & Sons
Release Date : 2014-03-11
Lithium Compounds In Organic Synthesis written by Renzo Luisi and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-03-11 with Science categories.
This unique book covers fundamentals of organolithium compounds and gives a comprehensive overview of the latest synthetic advances and developments in the field. Part I covers computational and spectroscopic aspects as well as structure-reactivity relationships of organolithiums, whereas Part II deals with new lithium-based synthetic methodologies as well as novel synthetic applications of functionalized lithium compounds. A useful resource for newcomers and active researchers involved in organic synthesis, whether working in academia or industry!
Boronic Acids
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Author : Dennis G. Hall
language : en
Publisher: John Wiley & Sons
Release Date : 2006-05-12
Boronic Acids written by Dennis G. Hall and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-05-12 with Science categories.
For the first time, the whole field of organoboronic acids is presented in one comprehensive handbook. Professor Dennis Hall, a rising star within the community, covers all aspects of this important substance class, including applications in chemistry, biology and medicine. Starting with an introduction to the structure, properties, and preparation of boronic acid derivatives, together with an overview of their reactions and applications, the book goes on to look at metal-catalyzed borylation of alkanes and arenas, coupling reactions and rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds. There follows chapters on copper-promoted C-O and C-N cross-coupling of boronic acids, recent applications in organic synthesis, as well as alpha-haloalkylboronic esters in asymmetric synthesis. Later sections deal with cycloadditions, organoboronic acids, oxazaborolidines as asymmetric inducers, and boronic acid based receptors and sensors. The whole is rounded off with experimental procedures, making this invaluable reading for organic, catalytic and medicinal chemists, as well as those working in organometallics.
Advanced Organic Chemistry
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Author : Francis A. Carey
language : en
Publisher: Springer Science & Business Media
Release Date : 2000
Advanced Organic Chemistry written by Francis A. Carey and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000 with Medical categories.
Concentrating on the most important reactions used for organic synthesis, this upper-level textbook presents the material by reaction type. The final chapter discusses the planning and execution of multi-step synthesis.