The Determination Of Ionization Constants
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The Determination Of Ionization Constants
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Author : Adrien Albert
language : en
Publisher:
Release Date : 1971
The Determination Of Ionization Constants written by Adrien Albert and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1971 with Science categories.
The Determination Of Ionization Constants
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Author : E. P. Serjeant
language : en
Publisher:
Release Date : 1962
The Determination Of Ionization Constants written by E. P. Serjeant and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1962 with categories.
The Determination Of Ionization Constants
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Author : Adrien Albert
language : en
Publisher:
Release Date : 1971
The Determination Of Ionization Constants written by Adrien Albert and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1971 with Ionization categories.
The Determination Of Ionization Constants
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Author : Adrien Albert
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
The Determination Of Ionization Constants written by Adrien Albert and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
This practical manual is devised for organic chemists and biochemists who, in the course of their researches and without previous experience, need to determine an ionization constant. We are gratified that earlier editions were much used for this purpose and that they also proved adequate for the in service training of technicians and technical officers to provide a Department with a pK service. The features of previous editions that gave this wide appeal have been retained, but the subject matter has been revised, extended, and brought up to date. We present two new chapters, one of which describes the determination of the stability constants of the complexes which organic ligands form with metal cations. The other describes the use of more recently introduced techniques for the determination of ionization constants, such as Raman and nuclear magnetic resonance spectroscopy, thermometric titrations, and paper electro phoresis. Chapter 1 gives enhanced help in choosing between alternative methods for determining ionization constants. The two chapters on potentiometric methods have been extensively revised in the light of newer understanding of electrode processes and of the present state of the art in instrumen tation.
Ionization Constants Of Acids And Bases
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Author : Adrien Albert
language : en
Publisher:
Release Date : 1962
Ionization Constants Of Acids And Bases written by Adrien Albert and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1962 with Acids categories.
A Precise Spectrophotometric Method For The Determination Of Ionization Constants
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Author : Irving Myron Klotz
language : en
Publisher:
Release Date : 1940
A Precise Spectrophotometric Method For The Determination Of Ionization Constants written by Irving Myron Klotz and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1940 with Ionization categories.
Pka Prediction For Organic Acids And Bases
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Author : D. Perrin
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-06-29
Pka Prediction For Organic Acids And Bases written by D. Perrin and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-06-29 with Science categories.
Many chemists and biochemists require to know the ionization constants of organic acids and bases. This is evident from the Science Citation Index which lists The Determination of Ionization Constants by A. Albert and E. P. Serjeant (1971) as one of the most widely quoted books in the chemical literature. Although, ultimately, there is no satisfactory alternative to experimental measurement, it is not always convenient or practicable to make the necessary measure ments and calculations. Moreover, the massive pK. compilations currently available provide values for only a small fraction of known or possible acids or bases. For example, the compilations listed in Section 1. 3 give pK. data for some 6 000--8 000 acids, whereas if the conservative estimate is made that there are one hundred different substituent groups available to substitute in the benzene ring of benzoic acid, approximately five million tri-substituted benzoic acids are theoretically possible. Thus we have long felt that it is useful to consider methods by which a pK. value might be predicted as an interim value to within several tenths of a pH unit using arguments based on linear free energy relationships, by analogy, by extrapolation, by interpolation from existing data, or in some other way. This degree of precision may be adequate for many purposes such as the recording of spectra of pure species (as anion, neutral molecule or cation), for selection of conditions favourable to solvent extraction, and for the interpretation of pH-profiles for organic reactions.
Ionization Constants Of Acids And Bases
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Author : Adrien Albert
language : en
Publisher:
Release Date : 1962
Ionization Constants Of Acids And Bases written by Adrien Albert and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1962 with Acids categories.
Buffers For Ph And Metal Ion Control
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Author : D. Perrin
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Buffers For Ph And Metal Ion Control written by D. Perrin and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
This book is intended as a practical manual for chemists, biologists and others whose work requires the use of pH or metal-ion buffers. Much information on buffers is scattered throughout the literature and it has been our endeavour to select data and instructions likely to be helpful in the choice of suitable buffer substances and for the preparation of appropriate solutions. For details of pH measurement and the preparation of standard acid and alkali solutions the reader is referred to a companion volume, A. Albert and E. P. Serjeant's The Determination of Ionization Constants (1971). Although the aims of the book are essentially practical, it also deals in some detail with those theoretical aspects considered most helpful to an understanding of buffer applications. We have cast our net widely to include pH buffers for particular purposes and for measurements in non-aqueous and mixed solvent systems. In recent years there has been a significant expansion in the range of available buffers, particularly for biological studies, largely in conse quence of the development of many zwiUerionic buffers by Good et al. (1966). These are described in Chapter 3.
Protein Purification
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Author : Robert K. Scopes
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-04-17
Protein Purification written by Robert K. Scopes and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-04-17 with Science categories.
New textbooks at alllevels of chemistry appear with great regularity. Some fields like basic biochemistry, organic reaction mechanisms, and chemical thermodynamics are weil represented by many excellent texts, and new or revised editions are published sufficiently often to keep up with progress in research. However, some areas of chemistry, especially many of those taught at the graduate level, suffer from a reallack ofup-to-date textbooks. The most serious needs occur in fields that are rapidly changing. Textbooks in these subjects usually have to be written by scientists actually involved in the research which is advancing the field. lt is not often easy to persuade such individuals to settime aside to help spread the knowledge they have accumu lated. Our goal, in this series, is to pinpoint areas of chemistry where recent progress has outpaced what is covered in any available textbooks, and then seek out and persuade experts in these fields to produce relatively concise but instructive introductions to their fields. These should serve the needs of one semester or one quarter graduate courses in chemistry and biochemistry. In some cases the availability of texts in active research areas should help stimulate the creation of new courses. NewYork CHARLES R. CANTOR Preface to the Second Edition The original plan for the first edition of this book was to title it Enzyme Purification: Princip/es and Practice.