Boranes And Metalloboranes
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Boranes And Metallaboranes
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Author : Catherine E. Housecroft
language : en
Publisher:
Release Date : 1994
Boranes And Metallaboranes written by Catherine E. Housecroft and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994 with Science categories.
This concise introduction to boranes and metalloboranes employs an informal and straightforward style. The author establishes facts first, and rationalization and theories follow. Ideas of cluster bonding are presented, and the author surveys different approaches to the bonding in clusters, emphasizing the use of frontier molecule orbitals and the construction of clusters from fragments. The application of spectroscopic techniques to the elucidation of cluster structure is discussed, with an emphasis on multinuclear NMR spectroscopy. The second edition includes an update on structural data for boranes and their anions. Sections on spectroscopy and the reactivity of metalloboranes have been slightly expanded and references have been updated.
Boranes And Metalloboranes
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Author : Catherine E. Housecroft
language : en
Publisher: Ellis Horwood
Release Date : 1990
Boranes And Metalloboranes written by Catherine E. Housecroft and has been published by Ellis Horwood this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990 with Borane categories.
Boron Metallo Boron Compounds And Boranes
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Author : Roy M. Adams
language : en
Publisher:
Release Date : 1964
Boron Metallo Boron Compounds And Boranes written by Roy M. Adams and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1964 with Borane categories.
Metal Interactions With Boron Clusters
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Author : Russell N. Grimes
language : en
Publisher: Modern Inorganic Chemistry
Release Date : 1982-12-31
Metal Interactions With Boron Clusters written by Russell N. Grimes and has been published by Modern Inorganic Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 1982-12-31 with Science categories.
Molecular clusters, in the broad sense that the term is commonly understood, today comprise an enormous class of species extending into virtually every important area of chemistry: "naked" metal clusters, transition metal carbonyl clusters, hydrocarbon cages such as cubane (C H ) and dodecahedrane (C H ), 8 8 20 20 organometallic cluster complexes, enzymes containing Fe S or MoFe S 4 4 3 4 cores, high polymers based on carborane units, and, of course, the many kinds of polyhedral borane species. So large is the area spanned by these diverse classes that any attempt to deal with them comprehensively in one volume would, to say the least, be ambitious-and also premature. We are presently at a stage where intriguing relationships between the various cluster families are becoming apparent (particularly in terms of bonding descriptions), and despite large dif ferences in their chemistry an underlying unity is gradually developing in the field. For example, structural changes occurring in Fe S cores as electrons are 4 4 pumped in and out, in some measure resemble those observed in boranes and carboranes. The cleavage of alkynes via incorporation into carborane cages and subsequent cage rearrangement, a sequence familiar to boron chemists, is a thermodynamically favored process which may be related to the behavior of unsaturated hydrocarbons on metal surfaces; analogies of this sort have drawn attention from theorists and experimentalists.
Nuclear Magnetic Resonance Spectroscopy Of Boron Compounds
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Author : Heinrich Nöth
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Nuclear Magnetic Resonance Spectroscopy Of Boron Compounds written by Heinrich Nöth and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
The revolutionary impetus of the NMR methods in organic chemistry has parallels in the field of boron chemistry. lIB NMR spectroscopy provided a basis for the elucida tion of structures and reactions of the boron hydrides. However, although many studies have been carried out with the higher boranes, carboranes, metalloboranes, etc. , and although certain patterns have emerged, the correlation between the observed chemical shift and the assigned structural unit is still not fully understood. Therefore, predictions in this area are still rather limited, and semiquantitative interpretations are not yet pos sible. Several years ago Eaton and Lipscomb sUpImarized the status in this field in their book "NMR Studies of Boron Hydrides and Related Compounds" and a plethora of new data has accumulated since then. The book also contained material on simple bo rane derivatives, but they were not discussed in any detail. On the other hand many systematic studies, both synthetic and spectroscopic, have been conducted on these simple boron materials in the last decade. Thus a large amount of NMR information is available, not only on lIB but also on 1 H, 1 3 C, and 14 N. However, this information is widely scattered in the literature, and often the data are not discussed at all. It see med appropriate, therefore, to collect these data and to present them in one volume.
Polyhedral Boranes
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Author : Earl L. Muetterties
language : en
Publisher: Hodder Education
Release Date : 1968
Polyhedral Boranes written by Earl L. Muetterties and has been published by Hodder Education this book supported file pdf, txt, epub, kindle and other format this book has been release on 1968 with Borane categories.
50th Anniversary Of Electron Counting Paradigms For Polyhedral Molecules
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Author : D. Michael P. Mingos
language : en
Publisher: Springer Nature
Release Date : 2022-01-01
50th Anniversary Of Electron Counting Paradigms For Polyhedral Molecules written by D. Michael P. Mingos and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-01-01 with Science categories.
The 50 Year Anniversary of the development of electron counting paradigms for polyhedral molecules is celebrated in two volumes of Structure and Bonding. Volume 1 covers the historical development, theoretical models and applications to boranes and metalloboranes.
Boron Chemistry 3
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Author : H. Nöth
language : en
Publisher: Elsevier
Release Date : 2013-10-22
Boron Chemistry 3 written by H. Nöth and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-22 with Science categories.
Boron Chemistry contains the selected lectures presented at the Third International Meeting on Boron Chemistry held at Munich & Ettal, FRG on July 5-9, 1976. Separating nine papers as chapters, this book discusses effects of orbital vacancies in boron compounds, the aminoboronation reaction, and the cyclic coordination of boron compounds. This text also explores the organoboranes in synthesis and analysis; the synthesis, structure, and chemical reactions of metalloboranes; and studies of the smaller boron hydrides and their derivatives.
Boron Hydride Chemistry
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Author : Earl L. Muetterties
language : en
Publisher:
Release Date : 1975
Boron Hydride Chemistry written by Earl L. Muetterties and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1975 with Science categories.
Boranes In Organic Chemistry
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Author : Herbert Charles Brown
language : en
Publisher:
Release Date : 1972
Boranes In Organic Chemistry written by Herbert Charles Brown and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1972 with Science categories.