Metal Interactions With Boron Clusters
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Metal Interactions With Boron Clusters
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Author : Russell N. Grimes
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-11-11
Metal Interactions With Boron Clusters written by Russell N. Grimes and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-11 with Science categories.
Molecular clusters, in the broad sense that the term is commonly understood, today comprise an enormous class of species extending into virtually every important area of chemistry: "naked" metal clusters, transition metal carbonyl clusters, hydrocarbon cages such as cubane (C H ) and dodecahedrane (C H ), 8 8 20 20 organometallic cluster complexes, enzymes containing Fe S or MoFe S 4 4 3 4 cores, high polymers based on carborane units, and, of course, the many kinds of polyhedral borane species. So large is the area spanned by these diverse classes that any attempt to deal with them comprehensively in one volume would, to say the least, be ambitious-and also premature. We are presently at a stage where intriguing relationships between the various cluster families are becoming apparent (particularly in terms of bonding descriptions), and despite large dif ferences in their chemistry an underlying unity is gradually developing in the field. For example, structural changes occurring in Fe S cores as electrons are 4 4 pumped in and out, in some measure resemble those observed in boranes and carboranes. The cleavage of alkynes via incorporation into carborane cages and subsequent cage rearrangement, a sequence familiar to boron chemists, is a thermodynamically favored process which may be related to the behavior of unsaturated hydrocarbons on metal surfaces; analogies of this sort have drawn attention from theorists and experimentalists.
Metal Complexes Containing Boron Based Ligands
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Author : Gareth Owen
language : en
Publisher: MDPI
Release Date : 2019-10-30
Metal Complexes Containing Boron Based Ligands written by Gareth Owen and has been published by MDPI this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-10-30 with Science categories.
Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.
Molecular Clusters Of The Main Group Elements
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Author : Matthias Driess
language : en
Publisher: John Wiley & Sons
Release Date : 2008-11-21
Molecular Clusters Of The Main Group Elements written by Matthias Driess and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-11-21 with Science categories.
With more than 20 contributions from leading research groups, this book provides essential information for chemists and materials scientists working with molecular clusters. It treats both homonuclear and heteronuclear clusters, including: the theory and concepts in main-group cluster chemistry, * novel boranes and heteroboranes, * silicon/germanium/tin clusters, * alkali metal suboxides, * clusters in alloys with mercury, * chalkogen clusters * and numerous other compound classes. The whole is illustrated by examples of the great potential for technical applications such as electron storage, cancer therapy and in optoelectronic devices. Its systematic coverage of all relevant main group elements makes this the prime reference source in the field.
Boranes And Metalloboranes
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Author : Catherine E. Housecroft
language : en
Publisher: Ellis Horwood
Release Date : 1990
Boranes And Metalloboranes written by Catherine E. Housecroft and has been published by Ellis Horwood this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990 with Borane categories.
Carboranes
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Author : Russell N. Grimes
language : en
Publisher: Academic Press
Release Date : 2016-12-20
Carboranes written by Russell N. Grimes and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-12-20 with Science categories.
Carboranes, Third Edition, by Russell Grimes, is the definitive resource on the subject. Completely updated with a wealth of research and review articles published in this active field since the previous volume was released in 2011, the book provides a readable and concise introduction to the basic principles underlying the synthesis, structures, and reactions of carboranes, heterocarboranes, and metallacarboranes. Following the valuable foundational information, the book explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science. These disciplines include polymer science, catalysis, biomedicine, nanomaterials, and others. Includes over 2,000 molecular structure drawings throughout the text Features expanded coverage on applications of carboranes, particularly in biomedicine and nanomaterials, given the growth of research in these areas Presents extended and updated tables, listing thousands of compounds with key literature references, provided online via the book’s website Explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science
Boranes And Metallaboranes
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Author : Catherine E. Housecroft
language : en
Publisher:
Release Date : 1994
Boranes And Metallaboranes written by Catherine E. Housecroft and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994 with Science categories.
This concise introduction to boranes and metalloboranes employs an informal and straightforward style. The author establishes facts first, and rationalization and theories follow. Ideas of cluster bonding are presented, and the author surveys different approaches to the bonding in clusters, emphasizing the use of frontier molecule orbitals and the construction of clusters from fragments. The application of spectroscopic techniques to the elucidation of cluster structure is discussed, with an emphasis on multinuclear NMR spectroscopy. The second edition includes an update on structural data for boranes and their anions. Sections on spectroscopy and the reactivity of metalloboranes have been slightly expanded and references have been updated.
Cluster Chemistry
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Author : Guillermo Gonzalez-Moraga
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-11-09
Cluster Chemistry written by Guillermo Gonzalez-Moraga and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-09 with Science categories.
Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.
B Boron Compounds
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Author : Gert Heller
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-06-29
B Boron Compounds written by Gert Heller and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-06-29 with Science categories.
The 3rd supplement continues the updating of the original 20 volumes on boron compounds published between 1974 and 1979. The first supplement consisting of 3 volumes covered all the literature uniformly up to the end of 1977, whereas the two volumes of the 2nd supplement have extended the literature coverage of boron compounds to 1980 and the four volumes of the 3rd supplement to 1984. The present volume continues the description of boron compounds with halogens, presenting those with chlorine, bromine and iodine. The compounds with chalcogens are completed here along with those of boron with S, Se, Te and Po. The final chapter on carboranes contains the carboranes themselves, together with metallacarboranes, and in the last section a description of carborane-containing polymers, mostly derived from the three isomeric dicarbadodecarboranes. Volume 4 of the 3rd supplement brings this supplement series to an end. It will be supplemented by a separately appearing index volume, which contains all the boron compounds dealt with in volumes 1 - 4 of this supplement series.
Metal Complexes Containing Boron Based Ligands
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Author : Gareth Owen
language : en
Publisher:
Release Date : 2019
Metal Complexes Containing Boron Based Ligands written by Gareth Owen and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019 with Electronic books categories.
Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.
Introduction To Cluster Chemistry
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Author : D. M. P. Mingos
language : en
Publisher:
Release Date : 1990
Introduction To Cluster Chemistry written by D. M. P. Mingos and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990 with Science categories.