Mechanisms Of Polymer Degradation And Stabilisation


Mechanisms Of Polymer Degradation And Stabilisation
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Mechanisms Of Polymer Degradation And Stabilisation


Mechanisms Of Polymer Degradation And Stabilisation
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Author : G. Scott
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Mechanisms Of Polymer Degradation And Stabilisation written by G. Scott and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Technology & Engineering categories.


The purpose of this publication is two-fold. In the first place it is intended to review progress in the development of practical stabilising systems for a wide range of polymers and applications. A complemen tary and ultimately more important objective is to accommodate these practical developments within the framework of antioxidant theory, since there can be little question that further major advances in the practice of stabilisation technology will only be possible on a firm mechanistic foundation. With the continual increase in the number of commercial anti oxidants and stabilisers, often functioning by mechanisms not even considered ten years ago, there is a need for a general theory which will allow the potential user to predict the performance of a particular antioxidant structure under specific practical conditions. Any such predictive tool must involve a simplified kinetic approach to inhibited oxidation and, in Chapter 1, Denisov outlines a possible mechanistic approach with the potential to predict the most useful antioxidant to use and the limits of its usefulness. In Chapter 2, Schwetlick reviews the current state of knowledge on the antioxidant mechanisms of the phosphite esters with particular emphasis on their catalytic peroxidolytic activity. Dithiophosphate v vi PREFACE derivatives show a similar behaviour but for quite different reasons and, in Chapter 3, AI-Malaika reviews information available from analytical studies, particularly using 31p_NMR spectroscopy, to elucid ate the complex chemistry that leads to the formation of the antioxidant -active agents.



Polymer Degradation And Stabilization


Polymer Degradation And Stabilization
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Author : W. L. Hawkins
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Polymer Degradation And Stabilization written by W. L. Hawkins and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Technology & Engineering categories.


The development of polymers as an important class of material was inhibited at the first by the premature failure of these versatile compounds in many applications. The deterioration of important properties of both natural and synthetic polymers is the result of irreversible changes in composition and structure of polymers molecules. As a result of these reactions, mechanical, electrical and/or aesthetic properties are degraded beyond acceptable limits. It is now generally recognized that stabilization against degradation is necessary if the useful life of polymers is to be extended sufficiently to meet design requirements for long-term applications. Polymers degrade by a wide variety of mechanisms, several of which affect all polymers through to varying degree. This monograph will concentrate on those degradation mechanisms which result from reactions of polymers with oxygen in its various forms and which are accelerated by heat and/or radiation. Those stabilization mechanisms are discussed which are based on an understanding of degradation reaction mechanisms that are reasonably well established. The stabilization of polymers is still undergoing a transition from an art to a science as mechanisms of degradation become more fully developed. A scientific approach to stabilization can only be approached when there is an understanding of the reactions that lead to degradation. Stabilization against biodegradation and burning will not be discussed since there is not a clear understanding of how polymers degrade under these conditions.



Polymer Degradation And Stabilisation


Polymer Degradation And Stabilisation
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Author : Norman Grassie
language : en
Publisher: CUP Archive
Release Date : 1988-04-14

Polymer Degradation And Stabilisation written by Norman Grassie and has been published by CUP Archive this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988-04-14 with Science categories.


The study of polymer degradation and stabilisation is of considerable practical importance as the industrial uses of polymeric materials continue to expand. In this book, the authors lucidly relate technological phenomena to the chemistry and physics of degradation and stabilisation processes. Degradation embraces a variety of technologically important phenomena ranging from relatively low temperature processes such as 'weathering' of plastics, 'fatigue' of rubbers through the processing of polymers in shearing mixers to very high temperature processes such as flammability and ablation. All these technological phenomena have in common certain basic chemical reactions. Thus 'weathering' has its roots in photo-oxidation, 'fatigue' and melt-degradation in mechano-oxidation and flammability, and ablation in ablation in pyrolysis and vapour phase oxidation.



Fundamentals Of Polymer Degradation And Stabilization


Fundamentals Of Polymer Degradation And Stabilization
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Author : N.S. Allen
language : en
Publisher: Springer Science & Business Media
Release Date : 1992-10-31

Fundamentals Of Polymer Degradation And Stabilization written by N.S. Allen and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992-10-31 with Technology & Engineering categories.


During the past decade, the field of polymer degradation and stabilization has become a subject of central importance in polymer science and technology. This book provides a fundamental source of information designed for those with only a basic understanding of the background of the field.



Polymer Degradation And Stabilization


Polymer Degradation And Stabilization
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Author : W. Lincoln Hawkins
language : en
Publisher:
Release Date : 1984

Polymer Degradation And Stabilization written by W. Lincoln Hawkins and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1984 with Polymerization categories.




Polymer Stabilisation Mechanisms And Applications


Polymer Stabilisation Mechanisms And Applications
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Author : N. C. Billingham
language : en
Publisher:
Release Date : 1991

Polymer Stabilisation Mechanisms And Applications written by N. C. Billingham and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1991 with Science categories.




Degradation And Stabilisation Of Polymers


Degradation And Stabilisation Of Polymers
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Author : G. Geuskens
language : en
Publisher:
Release Date : 1975

Degradation And Stabilisation Of Polymers written by G. Geuskens and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1975 with Polymerization categories.




Degradation And Stabilization Of Polymers


Degradation And Stabilization Of Polymers
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Author : Hans Helmut Gunter Jellinek
language : en
Publisher: Elsevier Publishing Company
Release Date : 1983

Degradation And Stabilization Of Polymers written by Hans Helmut Gunter Jellinek and has been published by Elsevier Publishing Company this book supported file pdf, txt, epub, kindle and other format this book has been release on 1983 with Science categories.




Thermal Degradation Of Polymeric Materials


Thermal Degradation Of Polymeric Materials
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Author : Krzysztof Pielichowski
language : en
Publisher: Elsevier
Release Date : 2022-11-05

Thermal Degradation Of Polymeric Materials written by Krzysztof Pielichowski and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-11-05 with Technology & Engineering categories.


Thermal Degradation of Polymeric Materials, Second Edition offers a wealth of information for polymer researchers and processors who require a thorough understanding of the implications of thermal degradation on materials and product performance. Sections cover thermal degradation mechanisms and kinetics, as well as various techniques, such as thermogravimetry in combination with mass spectroscopy and infrared spectrometry to investigate thermal decomposition routes. Other chapters focus on polymers and copolymers, including polyolefins, styrene polymers, polyvinyl chloride, polyamides, polyurethanes, polyesters, polyacrylates, natural polymers, inorganic polymers, high temperature-resistant and conducting polymers, blends, organic-inorganic hybrid materials, nanocomposites, and biocomposites. Finally, other key considerations such as recycling of polymers by thermal degradation, thermal degradation during processing, and modelling, are discussed in detail. Explains mechanisms of polymer degradation, making it possible to understand and predict material behavior at elevated temperatures Offers systematic coverage of each polymer group that is supported by data detailed explanations and critical analysis Investigates thermal decomposition routes in new materials, such as organic-inorganic hybrid materials and polymer nanocomposites



Stabilization Of Polymeric Materials


Stabilization Of Polymeric Materials
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Author : Hans Zweifel
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Stabilization Of Polymeric Materials written by Hans Zweifel and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


Plastics are used worldwide in everyday life, e.g. as food packaging, electronics, construction, automotive parts, and household appliances. To produce these products with the desired service lifetimes the use of suitable stabilizers is necessary. This book provides a concise and comprehensive overview of the basic mechanisms of plastic degradation processes caused by heat and light. At its core is a detailed description of the stabilization of different polymers, including an explanation of stabilization mechanisms and the influence of commonly used additives such as fillers, flame retardents and pigments on the stability of plastic. Every polymer scientist, material technologist, or application engineer dealing with the design of the properties of plastics will benefit from this new overview.