Metastable Liquids
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Metastable Liquids
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Author : Pablo G. Debenedetti
language : en
Publisher: Princeton University Press
Release Date : 2020-06-16
Metastable Liquids written by Pablo G. Debenedetti and has been published by Princeton University Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-06-16 with Science categories.
Metastable Liquids provides a comprehensive treatment of the properties of liquids under conditions where the stable state is a vapor, a solid, or a liquid mixture of different composition. It examines the fundamental principles that govern the equilibrium properties, stability, relaxation mechanisms, and relaxation rates of metastable liquids. Building on the interplay of kinetics and thermodynamics that determines the thermophysical properties and structural relaxation of metastable liquids, it offers an in-depth treatment of thermodynamic stability theory, the statistical mechanics of metastability, nucleation, spinodal decomposition, supercooled liquids, and the glass transition. Both traditional topics--such as stability theory--and modern developments--including modern theories of nucleation and the properties of supercooled and glassy water--are treated in detail. An introductory chapter illustrates, with numerous examples, the importance and ubiquity of metastable liquids. Examples include the ascent of sap in plants, the strategies adopted by many living organisms to survive prolonged exposure to sub-freezing conditions, the behavior of proteins at low temperatures, metastability in mineral inclusions, ozone depletion, the preservation and storage of labile biochemicals, and the prevention of natural gas clathrate hydrate formation. All mathematical symbols are defined in the text and key equations are clearly explained. More complex mathematical explanations are available in the appendixes.
Metastable Liquids
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Author : Vladimir Pavlovich Skripov
language : en
Publisher:
Release Date : 1974
Metastable Liquids written by Vladimir Pavlovich Skripov and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1974 with High temperatures categories.
Teplofizicheskie Svo Stva Zhidkoste V Metastabil Nom Sosto Anii
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Author : Vladimir Pavlovich Skripov
language : en
Publisher: Gordon & Breach Science Pub
Release Date : 1988-01-01
Teplofizicheskie Svo Stva Zhidkoste V Metastabil Nom Sosto Anii written by Vladimir Pavlovich Skripov and has been published by Gordon & Breach Science Pub this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988-01-01 with Science categories.
Provides a systematic qualitative description of superheated liquids, formulates the basic concepts of the physics of metastable states and discusses various aspects of the problem, including the kinetics of nucleation and the question of thermodynamic stability to continuous changes. Inadequate index. Annotation copyrighted by Book News, Inc., Portland, OR
Metastable Systems Under Pressure
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Author : Sylwester Rzoska
language : en
Publisher: Springer
Release Date : 2009-11-16
Metastable Systems Under Pressure written by Sylwester Rzoska and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-11-16 with Science categories.
recently discovered advantages of amorphous forms of medicines/pharmaceutical products which focused a significant part of industry-related efforts on the GFA (Glass Forming Ability) and the glass temperature (T) versus pressure g dependences. 1 b ? 0 ? ? o ? P ? Pg P ? Pg 0 ? ? ? ? T (P ) = F (P )D (P ) =T 1 + exp ? g g ? 0 ? ? ? ? c + Pg ? ? ? ? 400 1 b 0 o ? ? ? ? P ? P P ? P g g 0 ? ? ? ? T (P ) = F (P )D (P ) =T 1 + exp ? g g 0 ? ? ? ? c ? + P max g ? ? ? ? T ~7 GPa g max P ~ 304 K Liquid g 300 1 HS glass 0 200 -1 mSG ?=0. 044 Liquid -2 100 -3 glass ?=0. 12 -1. 2 -0. 9 -0. 6 -0. 3 0. 0 log T 10 scaled -1 0 1 2 3 4 5 6 7 8 9 10 11 12 P (GPa) g 19 Figure 1. T he pressure evolution of the glass temperature in gl Th ye s cerol ol . id curve shows the parameterization of experimental data via the novel, modifie d Glat Sizm elon type equation, given in the Figure.
Metastable Systems Under Pressure
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Author : Sylwester Rzoska
language : en
Publisher: Springer Science & Business Media
Release Date : 2009-11-19
Metastable Systems Under Pressure written by Sylwester Rzoska and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-11-19 with Science categories.
recently discovered advantages of amorphous forms of medicines/pharmaceutical products which focused a significant part of industry-related efforts on the GFA (Glass Forming Ability) and the glass temperature (T) versus pressure g dependences. 1 b ? 0 ? ? o ? P ? Pg P ? Pg 0 ? ? ? ? T (P ) = F (P )D (P ) =T 1 + exp ? g g ? 0 ? ? ? ? c + Pg ? ? ? ? 400 1 b 0 o ? ? ? ? P ? P P ? P g g 0 ? ? ? ? T (P ) = F (P )D (P ) =T 1 + exp ? g g 0 ? ? ? ? c ? + P max g ? ? ? ? T ~7 GPa g max P ~ 304 K Liquid g 300 1 HS glass 0 200 -1 mSG ?=0. 044 Liquid -2 100 -3 glass ?=0. 12 -1. 2 -0. 9 -0. 6 -0. 3 0. 0 log T 10 scaled -1 0 1 2 3 4 5 6 7 8 9 10 11 12 P (GPa) g 19 Figure 1. T he pressure evolution of the glass temperature in gl Th ye s cerol ol . id curve shows the parameterization of experimental data via the novel, modifie d Glat Sizm elon type equation, given in the Figure.
Structural Glasses And Supercooled Liquids
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Author : Peter G. Wolynes
language : en
Publisher: John Wiley & Sons
Release Date : 2012-04-10
Structural Glasses And Supercooled Liquids written by Peter G. Wolynes and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-04-10 with Science categories.
With contributions from 24 global experts in diverse fields, and edited by world-recognized leaders in physical chemistry, chemical physics and biophysics, Structural Glasses and Supercooled Liquids: Theory, Experiment, and Applications presents a modern, complete survey of glassy phenomena in many systems based on firmly established characteristics of the underlying molecular motions as deduced by first principle theoretical calculations, or with direct/single-molecule experimental techniques. A well-rounded view of a variety of disordered systems where cooperative phenomena, which are epitomized by supercooled liquids, take place is provided. These systems include structural glasses and supercooled liquids, polymers, complex liquids, protein conformational dynamics, and strongly interacting electron systems with quenched/self-generated disorder. Detailed calculations and reasoned arguments closely corresponding with experimental data are included, making the book accessible to an educated non-expert reader.
Phase Transitions In Polymers The Role Of Metastable States
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Author : Stephen Z.D. Cheng
language : en
Publisher: Elsevier
Release Date : 2008-09-10
Phase Transitions In Polymers The Role Of Metastable States written by Stephen Z.D. Cheng and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-09-10 with Technology & Engineering categories.
A classical metastable state possesses a local free energy minimum at infinite sizes, but not a global one. This concept is phase size independent. We have studied a number of experimental results and proposed a new concept that there exists a wide range of metastable states in polymers on different length scales where their metastability is critically determined by the phase size and dimensionality. Metastable states are also observed in phase transformations that are kinetically impeded on the pathway to thermodynamic equilibrium. This was illustrated in structural and morphological investigations of crystallization and mesophase transitions, liquid-liquid phase separation, vitrification and gel formation, as well as combinations of these transformation processes. The phase behaviours in polymers are thus dominated by interlinks of metastable states on different length scales. This concept successfully explains many experimental observations and provides a new way to connect different aspects of polymer physics. * Written by a leading scholar and industry expert * Presents new and cutting edge material encouraging innovation and future research * Connects hot topics and leading research in one concise volume
Crystal Liquid Gas Phase Transitions And Thermodynamic Similarity
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Author : Vladimir P. Skripov
language : en
Publisher: John Wiley & Sons
Release Date : 2006-12-13
Crystal Liquid Gas Phase Transitions And Thermodynamic Similarity written by Vladimir P. Skripov and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-12-13 with Science categories.
Professor Skripov obtained worldwide recognition with his monograph "Metastable liquids", published in English by Wiley & Sons. Based upon this work and another monograph published only in Russia, this book investigates the behavior of melting line and the properties of the coexisting crystal and liquid phase of simple substances across a wide range of pressures, including metastable states of the coexisting phases. The authors derive new relations for the thermodynamic similarity for liquid-vapour phase transition, as well as describing solid-liquid, liquid-vapor and liquid-liquid phase transitions for binary systems employing the novel methodology of thermodynamic similarity.
Impulse Breakdown Of Liquids
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Author : Vasily Y. Ushakov
language : en
Publisher: Springer Science & Business Media
Release Date : 2007-09-21
Impulse Breakdown Of Liquids written by Vasily Y. Ushakov and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-09-21 with Technology & Engineering categories.
The book describes the main physical processes and phenomena in pulsed electric breakdown. The knowledge and the control of the electric breakdown of liquids is important not only for the insulation inside power systems but it is also used for the creation and information of high voltage and high current pulses. Such high-voltage micro- and nanosecond pulses find wide application in experimental physics, electro discharge technology, physics of dielectrics, radar detection and ranging, high-speed photography.
Multiparameter Equations Of State
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Author : Roland Span
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-06-29
Multiparameter Equations Of State written by Roland Span and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-06-29 with Science categories.
As a basis for printed property charts and tables, empirical multiparameter equa tions of state have been the most important source of accurate thermodynamic property data for more than 30 years now. However, due to increasing demands on the accuracy of thermodynamic property data in computerised calculations as well as the availability of appropriate software tools, and the ever increasing computer power, such formulations are nowadays becoming a valuable tool for everyday work. This development has substantially increased the number of scientists, engi neers, and students who are working with empirical multiparameter equations of state, and it continues to do so. Nevertheless, common knowledge on this kind of thermodynamic property models and on the ongoing progress in this scientific discipline is still very limited. Multiparameter equations of state do not belong to the topics which are taught intensively in thermodynamic courses in engineering and natural sciences and the books and articles where they are published mainly deal with the thermodynamic properties of certain substances rather than with the theoretical background of the used equations of state. In contrast to this, my concern mainly was to give a survey of the theoretical background of multiparameter equations of state both with regard to their application and their development.